1.
Org Lett
; 5(3): 337-9, 2003 Feb 06.
Artigo
em Inglês
| MEDLINE
| ID: mdl-12556186
RESUMO
[reaction: see text] A new route, of potential strategic importance, to a difluorosugar analogue has been developed. Key steps included a Stille coupling and a highly regio- and enantioselective dihydroxylation of a highly substituted diene. Protecting groups were chosen to enhance the reactivity of the disubstituted allylic fragment in the AD reaction and allow deprotection under orthogonal conditions.