Self-Standing Nanomembranes of Super-Tough Plastics.

Nanomembranes are effective coating materials for protecting substrates from external stimuli; however, they are generally not self-standing owing to their low mechanical toughness. Self-standing nanomembranes would be an innovative development in the field of nanotechnology including miniaturized devices. In this study, self-standing nanomembranes were developed by spin-casting supertough polyamides over dimethylformamide solution. The polyamides were synthesized by the polycondensation of two derivatives of 4,4'-diamino-α-truxillic acid (4ATA) with slightly bent diphenylcyclobutane in the core. Mechanical evaluation of the 4ATA polyamides having an appropriate composition of aliphatic diacids revealed a high strain-energy density of 231 MJ m-3 at its maximum, which is significantly tougher than spider silk. The nanocoats with a thickness of several hundred nanometers showing interference fringes were able to be peeled off the glass substrate without breaking, owing to its ultrahigh toughness. The self-standing nanomembrane would be applied to flexible devices in the future.

High-temperature resistant water-soluble polymers derived from exotic amino acids.

High-performance water-soluble polymers have a wide range of applications from engineering materials to biomedical plastics. However, existing materials are either natural polymers that lack high thermostability or rigid synthetic polymers. Therefore, we design an amino acid-derived building block, 4,4'-diamino-α-truxillate dianion (4ATA2-), that induces water solubility in high-performance polymers. Polyimides containing 4ATA2- units are intrinsically water-soluble and are processed into films cast from an aqueous solution. The resulting polyimide films exhibit exceptional transparency and extremely high thermal stability. In addition, the films can be made insoluble in water by simple post-treatment using weak acid or multivalent metal ions such as calcium. The synthesized polyimide's derived from bio-based resources are useful for yielding waterborne polymeric high-performance applications.