Contamination Assessment and Temporal Evolution of Nitrates in the Shallow Aquifer of the Metauro River Plain (Adriatic Sea, Italy) after Remediation Actions.

Over the last decades, groundwater resources at global level have suffered a significant deterioration due to nitrate pollution, mainly related to the input of agricultural fertilizers, manure, sewage, and untreated urban and industrial effluents. The most impacted waters are those forming surface and shallow reservoirs, which usually play a key role in supplying waters to civil, agricultural, and industrial activities. The terminal portion of the Metauro River plain, located in central Italy along the Adriatic Sea coastline, hosts a strategic phreatic aquifer that, along with the surface water of the Metauro River, supplies water to the local population (i.e., about 60,000 people). This shallow coastal aquifer experiences a long-lasting story of nitrate contamination since the 1970s when the increase in the use of agricultural fertilizers contributed to very high levels of pollution (NO3- > 100 mg/L). This fact prompted the local authorities to carry out remediation actions that involve a pumping system to inject the NO3--poor waters from the Metauro River course directly into the shallow aquifer. The present work was aimed at defining the contamination of nitrates in this important water resource. The main geochemical characteristics and the temporal evolution of NO3- concentrations (between 2009 and 2020), in the shallow coastal aquifer of the Metauro River plain, were analyzed by means of classical geochemical analyses and multivariate methods accounting for the compositional nature of the data, to assess the efficiency of the in-situ remediation over time.

Evaluation of the biochemical methane potential of residual organic fraction and mechanically-biologically treated organic outputs intended for landfilling.

Mechanical biological treatment (MBT) approaches are being adopted to manage residual municipal waste (RMW) to promote the prevention or reduction of potential environmental impacts of landfilling. From this perspective, the present study aimed to increase the knowledge of the biological (anaerobic) stability of different MBT organic outputs and, conversely, initial methane generation from residual organic waste. Biochemical methane potential (BMP) tests, along with initial and final characterisations of substrates and digestates, were conducted on: a mechanically separated organic fraction from RMW (ms-OFRMW); a first MBT organic output represented by a biostabilised organic fraction from RMW (bios-OFRMW); and a different MBT organic output represented by a biodried fine fraction from RMW (biod-FFRMW). The ms-OFRMW had a BMP of 445.6 Nml CH4 g VS-1, which was comparable or even higher than those from separately collected and source-sorted organic fractions. The fibre and liquor fractions of the digestate from ms-OFRMW with inoculum showed potential profiles of P-rich amendment and N-rich fluid phase, respectively, even satisfying environmental limits (with the exclusion only of Cu and Zn contents in fibre fraction that, however, remained within typical ranges for agricultural digestates). The BMPs for bios-OFRMW and biod-FFRMW were 143.4 and 261.0 Nml CH4 g VS-1, respectively, indicating that these streams may still contribute to landfill methane generation. The BMPs for bios-OFRMW, biod-FFRMW, and ms-OFRMW were positively associated with the degrees of conversion of the substrates (17, 32, and 55%, respectively) and the potential dynamic respiration indexes (955, 3126, and 6062 mg O2 kg VS-1 h-1, respectively).