Formation kinetics of SVOC organic films and their impact on child exposure in indoor environments.

We conducted an SVOC mass transfer and child-exposure modeling analysis considering the combined sorption of multiple SVOCs containing DnBP, BBP, DEHP, DINP and DINCH in indoor environments. A mechanistic model was applied to describe the organic film formation, and a partition-coefficient-prediction model was originally developed for the realistic organic films. The characteristics of film formation on impermeable surfaces were examined based on three different assumptions: the widely-used constant Kns,im assumption, Koa assumption, and the proposed Kom assumption (predicted specifically for the realistic organic films in this study). After long-term SVOC sorption, the organic film reached increasing equilibrium gradually under constant Kns,im assumption. While under Koa and Kom assumption, organic films exhibited nearly linear increases on surfaces, the trends of which agreed well with field studies. However, the film thicknesses calculated under Kom assumption with larger film partition coefficients were approximately twice larger than those under Koa assumption. Meanwhile, Horizontal surfaces with higher deposition rates of particle-phase SVOCs exhibited larger velocities of film growth compared to vertical surfaces. Under the Kom assumption, exposures of hazardous SVOCs for a 3-year-old child increased by 87.5 %-198.7 % even with the weekly cleaning of indoor impermeable surfaces, carpet and cloth. This study is anticipated to provide valuable insights into the film-forming characteristics of multiple SVOCs and the accompanying significant health risks to human beings in indoor environments.

Electrostatic Polydopamine-Interface-Mediated (e-PIM) filters with tuned surface topography and electrical properties for efficient particle capture and ozone removal.

Ambient particulate matter (PM) poses severe environmental health risks to the public globally, and efficient filtration technologies are urgently needed for air ventilation. In this contribution, to overcome the efficiency-resistance trade-off for fibrous filtration, we introduced an electrostatic polydopamine-interface-mediated (e-PIM) filter utilizing a combined effect of particle pre-charging and filter polarizing. After delineating the PM-fiber interactions in electrostatic filtration, we designed a composite fiber structure and fabricated the filters by a two-step dip-coating. The surface topography and electrical potential of the polyester (PET) coarse substrates were regulated by successively coating polydopamine (PDA) layers and manganese oxide clusters. By this means, an 8-mm-thick Mn-P @ P-100 filter possessed improved efficiency of 96.05%, 97.60%, and 99.14% for 0.3-0.5 µm, 0.5-1 µm, and 1-3 µm particles, the ultralow air resistance of 10.4 Pa at a filtration velocity of 0.5 m/s, and steady ozone removal property. Compared with the pristine PET substrates, the efficiency for 0.3-0.5 µm particles expanded 12 times. Compared with the pristine PET substrates, the efficiency for 0.3-0.5 µm particles expanded 12 times. We expect e-PIM filters and the filtration prototype will be potential candidates as effective and low-cost air cleaning devices for a sustainable and healthy environment.

[Distribution Characteristics of Soil Phosphorus Forms and Phosphatase Activity at Different Altitudes in the Soil of Water-Level-Fluctuation Zone in Pengxi River, Three Gorges Reservoir].

Phosphatases play important roles in converting organic phosphorus into inorganic phosphorus in soil. However, studies from this perspective on the water-level-fluctuation zone (WLFZ) of the Three Gorges Reservoir are limited. In this study, phosphatase activity and the forms of phosphorus were analyzed. Soil samples were collected in the river basin of the Penxi River in the WLFZ during a drying period. The correlation between phosphatase activity and phosphorus forms and the impacts of phosphatase activity on the phosphorus forms were analyzed. The results showed that the contents of H2O-Pi, NaHCO3-Pi, and NaOH-Pi in the soils of the WLFZ were higher than those in the soils by the river. In addition, a higher altitude resulted in higher contents of bio-enzymatically hydrolysable phosphorus and NaOH-Po. Furthermore, redundancy analysis (RDA) showed that the contents of organic matter and amorphous Fe and Mn were the main factors affecting soil organic phosphorus forms. The average activities of acid phosphomonoesterase (ACP), alkaline phosphomonoesterase (ALP), phosphodiesterase (PDE) (all in p-NP), and phytase (PAE) (in P) in the soils of the WLFZ were 1.40, 2.60, 0.44, and 11.43 µmol·(g·h)-1, respectively. Moreover, the activities of different phosphatases increased with altitude. Soil plant biomass and microbial biomass were important reasons for the difference in spatial distribution of phosphatase activity in the soil of the WLFZ. Phosphatase activities were significantly positively correlated with the contents of organic phosphorus forms but negatively correlated with the content of bioavailable phosphorus. A higher soil phosphatase activity and a lower content of bioavailable phosphorus were usually detected in soil samples taken at a higher altitude. In the early stage of flooding, phosphatase converted organic phosphorus into inorganic phosphorus at a relatively high rate, and the risk of phosphorus release to the overlying water body was also high. This study contributed to a comprehensive understanding of the geochemical cycle of soil phosphorus in the soil of the WLFZ.

Ultralow Resistance Two-Stage Electrostatically Assisted Air Filtration by Polydopamine Coated PET Coarse Filter.

Airborne particulate matters (PM) pose serious health threats to the population, and efficient filtration is needed for indoor and vehicular environments. However, there is an intrinsic conflict between filtration efficiency, air resistance, and service life. In this study, a two-stage electrostatically assisted air (EAA) filtration device is designed and the efficiency-air resistance-filter life envelope is significantly improved by a thin coating of polydopamine (PDA) on the polyethylene terephthalate (PET) coarse filter by in situ dopamine polymerization. The 8 mm thick EAA PDA-140@PET filter has a high filtration efficiency of 99.48% for 0.3 µm particles, low air resistance of 9.5 Pa at a filtration velocity of 0.4 m s-1 , and steady performance up to 30 d. Compared with the bare PET filter, the penetration rate for 0.3 µm particles is lowered by 20×. The coated PDA is of submicron thickness, 10-3  × the gap distance between filter fibers, so low air resistance could be maintained. The filter shows steadily high filtration efficiency and an acceptable increase of air resistance and holds nearly as many particles as its own weight in a 30 day long-term test. The working mechanism of the EAA coarse filter is investigated, and the materials design criteria are proposed.