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1.
Phys Rev E ; 94(4-1): 042609, 2016 Oct.
Artigo em Inglês | MEDLINE | ID: mdl-27841649

RESUMO

In an attempt to quantify the role of polydispersity in colloidal suspensions, we present an efficient implementation of the renormalized jellium model for a mixture of spherical charged colloids. The different species may have different size, charge, and density. Advantage is taken from the fact that the electric potential pertaining to a given species obeys a Poisson's equation that is species independent; only boundary conditions do change from one species to the next. All species are coupled through the renormalized background (jellium) density, that is determined self-consistently. The corresponding predictions are compared to the results of Monte Carlo simulations of binary mixtures, where Coulombic interactions are accounted for exactly, at the primitive model level (structureless solvent with fixed dielectric permittivity). An excellent agreement is found.

2.
Artigo em Inglês | MEDLINE | ID: mdl-23496499

RESUMO

We study the dynamics of a granular gas heated by a stochastic thermostat. From a Boltzmann description, we derive the hydrodynamic equations for small perturbations around the stationary state that is reached in the long time limit. Transport coefficients are identified as Green-Kubo formulas obtaining explicit expressions as a function of the inelasticity and the spatial dimension.


Assuntos
Coloides/química , Gases/química , Modelos Químicos , Modelos Moleculares , Simulação por Computador , Hidrodinâmica , Modelos Lineares
3.
Phys Rev E Stat Nonlin Soft Matter Phys ; 85(5 Pt 1): 051301, 2012 May.
Artigo em Inglês | MEDLINE | ID: mdl-23004744

RESUMO

We study the dynamics of a homogeneous granular gas heated by a stochastic thermostat, in the low density limit. It is found that, before reaching the stationary regime, the system quickly "forgets" the initial condition and then evolves through a universal state that does not only depend on the dimensionless velocity, but also on the instantaneous temperature, suitably renormalized by its steady state value. We find excellent agreement between the theoretical predictions at the Boltzmann equation level for the one-particle distribution function and the direct Monte Carlo simulations. We conclude that at variance with the homogeneous cooling phenomenology, the velocity statistics should not be envisioned as a single-parameter, but as a two-parameter scaling form, keeping track of the distance to stationarity.

4.
Phys Rev E Stat Nonlin Soft Matter Phys ; 77(5 Pt 1): 051127, 2008 May.
Artigo em Inglês | MEDLINE | ID: mdl-18643046

RESUMO

We study the nonequilibrium statistical mechanics of a system of freely moving particles, in which binary encounters lead either to an elastic collision or to the disappearance of the pair. Such a system of ballistic annihilation therefore constantly loses particles. The dynamics of perturbations around the free decay regime is investigated using the spectral properties of the linearized Boltzmann operator, which characterize linear excitations on all time scales. The linearized Boltzmann equation is solved in the hydrodynamic limit by a projection technique, which yields the evolution equations for the relevant coarse-grained fields and expressions for the transport coefficients. We finally present the results of molecular dynamics simulations that validate the theoretical predictions.

5.
Phys Rev E Stat Nonlin Soft Matter Phys ; 77(5 Pt 1): 051128, 2008 May.
Artigo em Inglês | MEDLINE | ID: mdl-18643047

RESUMO

We develop a theory for fluctuations and correlations in a gas evolving under ballistic annihilation dynamics. Starting from the hierarchy of equations governing the evolution of microscopic densities in phase space, we subsequently restrict our attention to a regime of spatial homogeneity, and obtain explicit predictions for the fluctuations and time correlation of the total number of particles, total linear momentum, and total kinetic energy. Cross correlations between these quantities are worked out as well. These predictions are successfully tested against molecular dynamics and Monte Carlo simulations. This provides strong support for the theoretical approach developed, including the hydrodynamic treatment of the spectrum of the linearized Boltzmann operator. This paper makes use of the spectral analysis reported in the preceding paper [Phys. Rev. E 77, 051127 (2008)].

6.
Phys Rev E Stat Nonlin Soft Matter Phys ; 78(6 Pt 1): 061110, 2008 Dec.
Artigo em Inglês | MEDLINE | ID: mdl-19256805

RESUMO

The behavior of a heavy tagged intruder immersed in a bath of particles evolving under ballistic annihilation dynamics is investigated. The Fokker-Planck equation for this system is derived and the peculiarities of the corresponding diffusive behavior are worked out. In the long time limit, the intruder velocity distribution function approaches a Gaussian form, but with a different temperature from its bath counterpart. As a consequence of the continuous decay of particles in the bath, the mean-squared displacement increases exponentially in the collision per particle time scale. Analytical results are finally successfully tested against Monte Carlo numerical simulations.

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