1.
Angew Chem Int Ed Engl
; 59(29): 11769-11773, 2020 Jul 13.
Artigo
em Inglês
| MEDLINE
| ID: mdl-32240563
RESUMO
Advances in the field of phosphorus chemistry are documented, by revealing the synthetic utility of previously underutilized quaternary phosphiranium salts (QPrS) as three-chain-atom electrophilic building blocks. Notably, control of their challenging C-centered electrophilicity is disclosed with an expedient synthesis of tertiary ß-anilino phosphines as a proof-of-concept.