Assessment of a simple and replicable procedure for selective phosphorus recovery from sewage sludge ashes by wet chemical extraction and precipitation.

The selective phosphorus recovery by wet chemical extraction and precipitation was assessed at the laboratory scale aiming at identifying a simple and replicable procedure that could be effectively applied to different types of sewage sludge ashes. The experimental work was performed on five samples of sewage sludge ashes, of which three were obtained from muffle-furnace incineration and two from full-scale mono-incineration plants. A single-step extraction procedure has been investigated by applying different operating conditions (type of leaching acid, liquid-to-solid ratio, contact time). Experimental results indicated that phosphorus recovery efficiency varied between 54 and 92% with limited co-dissolution of metals and metalloids, except for arsenic. Operating conditions, sewage sludge ashes characteristics and phosphorus removal processes in the wastewater treatment plant were the main factors affecting phosphorus recovery efficiency. The application of optimal operating conditions (0.2 M sulfuric acid, liquid-to-solid ratio of 20 and contact time of 2 h) resulted in phosphorus recovery from 76 to 92% on four samples. Subsequently, precipitation of phosphorus from acidic leachate was carried out by lime dosing. After filtering and drying, the recovered products presented a P2O5 content between 11.5 and 36.7% dry weight, with a fraction of soluble phosphorus between 75 and 91%, a good percentage for application as fertilizer or animal feed. Since few undesired elements (i.e., As, Cu and Zn) exceeded the limits for fertilizer application (exception was represented by Ni and Pb, which were present at low concentration), an additional purification step may be required. Overall, experimental results highlighted the influence of process parameters on phosphorus recovery.

Electro-dewatering treatment of sludge: Assessment of the influence on relevant indicators for disposal in agriculture.

Waste activated sludge requires effective dewatering, high biological stability and retention of nutrients prior to disposal for agricultural application. The study was conducted to evaluate the impact of pressure-driven electro-dewatering (EDW) on improving sludge characteristics related to disposal in agriculture, including biological stability, pathogen availability, heavy metals concentrations and nutrients content. Thickened conditioned and mechanically dewatered sludge samples were collected from two wastewater treatment plants (WWTPs), characterized by different stabilization processes, and treated by a lab-scale device at 5, 15 and 25 V. EDW increased significantly the dry solid (DS) content, up to 43-45%, starting from 2 to 3% of raw sludge. The endogenous value of specific oxygen uptake rate (SOUR), monitored as indicator of biological stability, increased up to 56% and 39% after EDW tests for sludge from two WWTPs. On the other hand, the exogenous SOUR decreased, indicating a significant drop in the active bacterial population. Likewise, a 1-2 log unit reduction was observed for E. coli after EDW tests at 15 and 25 V. However, no remarkable removal of heavy metals, namely chromium, nickel, lead, copper and zinc, was achieved. Finally, the concentration of nutrients for soil, such as carbon, nitrogen, phosphorus and sulfur, was not affected by the EDW process. In conclusion, EDW exerts considerable effects on the biological characteristics of sludge, which should be considered in a proper design of sludge management to ensure safe and sustainable resource recovery.