Surface improved agro-based material for the effective separation of toxic Ni(II) ions from aquatic environment.

In this present study, a novel and low cost surface improved material was prepared from the farm waste material (Borassus flabellifer male inflorescence) and its surface was enhanced by the sulphuric acid treatment to intensify the Ni(II) ions adsorption. The adsorption individualities such as availability of functional groups, essential elements and the exterior side and structural properties of the material were assessed by the FT-IR, EDX, SEM and XRD investigation. The impact of varied adsorption influencing parameters on Ni(II) ions adsorption was studied and optimized as pH - 6.0, biosorbent dosage - 1.5 g/L, contact time - 60 min and temperature - 303 K via batch adsorption examination. Modeling examinations were carried with varied adsorption isotherm (Langmuir, Freundlich, Fritz-Schlunder and Temkin) and kinetic models (Pseudo-first order, Pseudo-second order and Elovich kinetics). Thermodynamic studies were carried out at varied Ni(II) ions concentrations (25 mg/L - 150 mg/L) and temperatures (303 K-333 K) to explain the nature of Ni(II) ions adsorption on Borassus flabellifer male inflorescence. The prepared material has shown the most suitable Ni(II) ions adsorption results for the Langmuir isotherm (R2 = 0.9808) and Pseudo-first order kinetic models (R2 = 0.9735 for 25 mg/L). Thereby, the modeling study revealed that the prepared material has received the Ni(II) ions adsorption capacity (qm) value of 20.31 mg/g and the Ni(II) ions adsorption was physisorption. Thermodynamic results demonstrated that the Ni(II) ions adsorption was immediate, exothermic and favorable at low temperature.

A review on algal-bacterial symbiotic system for effective treatment of wastewater.

Industrialization, urbanization and other anthropogenic activities releases different organic and inorganic toxic chemicals into the environment which prompted the water contamination in the environment. Different physical and chemical techniques have been employed to treat the contaminated wastewater, among them biological wastewater treatment using algae has been studied extensively to overwhelm the constraints related to the usually utilized wastewater treatment techniques. The presence of bacterial biota in the wastewater will form a bond with algae and act as a natural water purification system. The removal efficiency of single algae systems was very low in contrast with that of algal-bacterial systems. Heterotrophic microorganisms separate natural organic matter that is discharged by algae as dissolved organic carbon (DOC) and discharges CO2 that the algae can take up for photosynthesis. Algae bacteria associations offer an exquisite answer for tertiary and scrape medicines because of the capacity of micro-algae to exploit inorganic compounds for their development. Furthermore, for their ability to evacuate noxious contaminants, in this way, it does not prompt optional contamination. The present review contribute the outline of algae-bacteria symbiotic relationship and their applications in the wastewater treatment. The role of algae and bacteria in the wastewater treatment have been elucidated in this review. Moreover, the efforts have been imparted the importance of alage-bacteria consortium and its applications for various pollutant removal from the environment.

Adsorption characteristics of magnetic nanoparticles coated mixed fungal biomass for toxic Cr(VI) ions in aquatic environment.

In this research, the adsorptive removal of Cr(VI) ions from the aquatic environment have been studied using newly synthesized magnetic nanoparticles coated mixed fungal biomass (MNP-FB). Two fungal biomass such as Aspergillus fumigatus and Aspergillus niger were isolated, screened, and utilized as a precursor for making an adsorbent. Molecular characterization of isolated fungal species was recognized using 18S rRNA sequencing. The characterization studies of the MNP-FB were evaluated using Fourier Transform Infrared Spectrophotometer (FTIR) and Scanning Electron Microscopy (SEM) and Energy Dispersive X-ray (EDX) analyses. Optimization studies were studied to check the effect of different operating variables such as pH (2.0-9.0), equilibrium time (10-90 min), MNP-FB dosage (0.1-1.0 g/L), temperature (30-60 °C) and concentration of Cr(VI) ions (50-500 mg/L). Additionally, Freundlich isotherm model fits well for the adsorption of Cr(VI) ion using MNP-FB. The adsorption kinetics was interpreted well by Pseudo-first order model. The thermodynamic study concluded that Cr(VI) ions removal by MNP-FB was exothermic and appreciative at low temperatures. The monolayer adsorption efficiency of MNP-FB for Cr(VI) ions was measured as 249.9 mg/g. The current results reveal that MNP-FB has considered being a proficient and economically suitable material for the Cr(VI) ions removal from the water environment.

A review on biosynthesis of metal nanoparticles and its environmental applications.

Nanotechnology has become one of the emerging multi-disciplinary fields receiving universal attention and playing a substantial role in agriculture, environment and pharmacology. In spite of various techniques employed for nanoparticle synthesis such as laser ablation, mechanical milling, spinning and chemical deposition, usage of hazardous chemicals and expensiveness of the process makes it unsuitable for the continuous production. Hence the necessity of sustainable, economic and environment friendly approach development have increased in recent years. Microbial synthesis of nanoparticles connecting microbiology and nanotechnology is one of the green techniques employed for sustainable production. Gold, silver and other metal nanoparticles like platinum, palladium, molybdenum nanoparticles biosynthesis by bacteria, fungi, yeast and algae have been reported in the present review. On account of microbial rich community, several microbes have been explored for the production of nanoparticles. Nanoparticles are also employed for environmental remediation processes such as pollutant removal and detection of contaminants. Lack of monodispersity and prolonged duration of synthesis are the limitations of bio-synthesis process which can be overcome by optimization of methods of microbial cultivation and its extraction techniques. The current review describes the different microbes involved in the synthesis of nanoparticles and its environmental applications.