Evaluation of physical and chemical characteristics of wastewater and sludge of Zahedan urban wastewater treatment plant for reuse.

Following the water shortage in the world, the use of wastewater as a sustainable resource has been considered in large volume. The study conducted to evaluate the physical and chemical characteristics of the wastewater and sludge of the Zahedan urban wastewater treatment plant showed that the wastewater and sludge treatment system of the treatment plant has high efficiency and effectiveness in removing the investigated parameters. The investigated parameters in the effluent included Chemical oxygen demand (COD), Biochemical oxygen demand (BOD), and Total suspended solids (TSS), turbidity, temperature, nitrate, nitrite, phosphate, pH, zinc, cobalt, lead and copper. Also, the investigated parameters in the sludge included Mixed liquor suspended solids (MLSS), Mixed liquor volatile suspended solids (MLVSS), pH, electrical conductivity and heavy metals. The results showed that the average concentration of metals in the treated effluent is Zn > Mn > Cu > Pb > Ni > Cr > Cd ،and Chemical oxygen demand and Biochemical oxygen demand in the effluent of this treatment plant are on average 171 and 44.4 mg/L, respectively, and its discharge in surface water is limited, but it can be applied for agriculture. Also, the purified sludge had the necessary standards and could be used as soil or household fertilizer and compost for agricultural land.

Degradation of reactive red 198 dye from aqueous solutions by combined technology advanced sonofenton with zero valent iron: Characteristics/ effect of parameters/kinetic studies.

Dyes are one of the most common contaminants in industrial effluents, whose continuous release into the environment has become an increasing global concern. In this work, nanoparticles of zero-valent iron (NZVI) were synthesized using the chemical regeneration method ،and were utilized for the first time as a catalyst in the advanced Sono-Nano-Fenton hybrid method for the decomposition of Reactive Red 198 (RR198). The properties of zero-valent iron nanoparticles were analyzed using SEM and XRD. The effect of pH, initial dye concentration, nanoparticle dosage, zero-valent iron and H2O2 concentration on the decomposition efficiency of Red Reactive 198 was investigated. Comparing the efficiency of Reactivate 198 dye degradation in Sonolysis, Sono-NZVI, Sono-H2O2 and Sono-Nano Fenton processes showed that 97 % efficiency was achieved by the Sono-Nano Fenton process in 60 min. The kinetics of the removal process showed that this process follows pseudo-first-order kinetics and the Langmuir-Hinshelwood model. The results indicate that the effectiveness of the ultrasonic process in removing resistant organic pollutants such as dyes increases tremendously with the synergy of the Fenton process.

Incidence and exposure to microplastics in table salt present in the Iran market.

Plastics and microplastics (MPs) are toxic, pervasive and threatening the biotic and abiotic components of the earth, and they threaten food safety and food security by moving in the food chain. In this study, the amounts and characteristics of 40 table salt samples with different brands, including sea salt (No = 13), rock (No = 13), bulk (No = 8) and non-standard (No = 6), were investigated with a combination of sieving, filtration, observation and FTIR, Micro-Raman and SEM techniques. The results showed that all the salts were contaminated with MPs. In general, the abundance range of detected particles was 700-5470 MPs/kg. The abundance of MPs was higher in counterfeit and non-standard salts (1825 ± 1808 MPs/kg). Investigating the relationship between the effect of the purification process (Kruskal-Wallis Test, P = 0.841), the type of packaging (Kruskal-Wallis Test, P = 0.609), and the type of salt (Kruskal-Wallis Test, P = 0.942), on the abundance of MPs using a comparison test Kruskal-Wallis was not significant. However, the numerical difference was recognizable. The most identified polymer in the salts was cellulose acetate, which probably causes by unmanaged plastic litter in the environment (especially cigarette butts). The dominant form of particles was fragment-shaped, which is the most abundant form of identified MPs in the environment. Both environmental pollution and secondary pollution (during production and packaging), respectively, contribute to the contamination of salts with MPs. The estimated human dietary intake (EDI) and the amount of estimated annual intake (EAI) for different ages in Iran were obtained EDI = 5-59 MPs/capita/day and EAI = 1967-21563 MPs/capita/year. The surface morphology of the particles showed that the MPs were affected by continuous weathering, mechanical fracture and oxidation. MPs are a threat to human health due to the absorption and transmission of dangerous pollutants and their inherent toxicity. Therefore, a solution must be thought of to prevent the contamination of the food chain through salts by MPs, (with protective measures at the salt source, and by improving its production processes.

Tracking microplastics contamination in drinking water in Zahedan, Iran: From source to consumption taps.

Microplastics (MPs) that pollute drinking water are inherently toxic, act as an adsorbent of hazardous pollutants, and threaten human health. So, the fate of microplastics in drinking water from the source to consumption taps (CTs) was assessed in spring and winter in Zahedan city in Iran. Sampling was performed from 4 reservoirs (raw water), before and after two water treatment plants (WTPs), and 10 CTs. The reservoirs were sampled using a plankton net (pore size = 100 µm), and the remaining samples were taken using a sampling device (containing a stainless steel membrane as a filter with pore size = 5 µm). The combination of density separation techniques, digestion, observation, Micro-Raman and FTIR, and SEM analysis was performed to recognize MPs. The average number of MPs in raw water varied between 15.4 and 44.7 MP/m3 (winter) and 22-51.8 MP/m3 (spring). The results before and after the treatment plant showed that about 64 % and 75 % of particles were eliminated in WTP1 and WTP2, respectively. The average number of MPs in CTs was more than treatment water (CTa = 85-390 MP/m3 and CTb = 75-400 MP/m3), which is a probable confirmation of secondary contamination (abrasion from pipes, installations, and sealing materials). The dominant type of polymer detected in raw water, treated water, and consumption taps were PS. The estimated daily intake for children and adults was about 0.16-15 MP/kg/bw/year and 0.07-5.7 MP/kg/bw/year, respectively. The surface morphology of MPs showed that the particles were affected by continuous weathering, mechanical breakage, and oxidation. MPs threaten the environment and human health due to the adsorption and transport of hazardous pollution and their intrinsic toxicity, so a solution must be thought of to prevent the pollution of drinking water by MPs.

Abundance and distribution of microplastics in the sediments of the estuary of seventeen rivers: Caspian southern coasts.

Given the increase in plastic production, persistence, and toxicity in the environment, understanding the probability of microplastics (MPs) accumulation in the sediments of the rivers' estuary is urgently needed. In this study, sediments of the estuary of 17 rivers, ending to the Caspian Sea, were evaluated at two depths (0-5 cm and 5-15 cm). Plastic particles were categorized into two groups in terms of size: small MPs and large MPs. The combination of observational techniques, FTIR, and SEM analysis was applied to identify MPs. The mean of MPs in 17 rivers was obtained at a depth of 0 to 15 cm of sediments 350.6 ± 232.6 MP/kg. The fiber was identified as the predominant particles in sediments, and foam-shaped particles were the least amount in the sediment. In terms of polymer structure, polyethylene (PE) (20%) and polyvinyl chloride (PVC) (2%) showed the highest and lowest prevalence, respectively. In the current study, the number of MPs was higher than the average of MPs in sediments of recreational-tourist areas and non-tourist areas of the southern Caspian coast. Results from this study indicate that sediments of the rivers' estuary are a hotspot of plastic particle pollution. Therefore, plastic management in the path of the Caspian catchment area of Iran, and cleaning rivers coast and rivers mouth from plastic is recommended.

Contamination of the Caspian Sea Southern coast sediments with microplastics: A marine environmental problem.

Marine ecosystem pollution with microplastics (MPs) is a global problem. The current study aimed to assess the occurrence of MPs in the sediments of the Caspian Sea southern coasts. For sampling, two distinct areas were selected including recreational-tourism areas (No = 24), and non-tourist areas (No = 24). MPs were studied in 5 and 5-15 cm from the top sediment surface. All 96 samples were taken and analyzed according to the methodology provided by the US national oceanic and atmospheric administration (NOAA). The combination of observational techniques, FTIR, and SEM analysis was applied to identify MPs. MPs were classified into two categories in terms of size: small MPs and large MPs. The average, maximum, and minimum abundance of MPs (based on dry weight) in sediments of the southern coast of the Caspian Sea was 183.5 ± 154.4 MP/kg, 542 MP/kg, and 13 MP/kg, respectively. On the basis of morphology, fragment-shaped (30.3%) MPs showed the highest prevalence, while film-shaped (18.7%) MPs were the least contributory. Polyethylene (PE) and polyethylene terephthalate (PET), each of them with a 20% share, were the most common MPs found in the studied samples. The distribution of MPs on the southern coasts of the Caspian Sea revealed a sporadic and irregular spatial pattern. Correspondingly, it can be concluded that probably environmental factors (the current of the sea surface water from west to east), enclosed environment of the Caspian Sea, anthropogenic activities (e.g., industrialization and urbanization, improper waste management, fishing, and tourism activity, residential wastewater), and also discharging of rivers (which can carry plastics) into the sea, have all influenced the abundance and polymer diversity of MPs in the sediments of the southern coast of the sea. More attention should be paid to the health and environmental effects of MPs and to the protection of this sensitive marine ecosystem through implementing proper waste management system by all surrounding littoral countries.

Estimation of plastic waste inputs from land into the Persian Gulf and the Gulf of Oman: An environmental disaster, scientific and social concerns.

It has been reported that, the huge amount of plastic waste is present in marine environments. This study evaluated solid waste generation, management, disposal approaches, and the amount of plastic waste entered into the Persian Gulf and the Gulf of Oman in 2016. The findings showed that waste in the Persian Gulf and the Gulf of Oman regions has been mismanaged by 65% and 81%, respectively. According to our estimates, about 1634.9 k-tons (Kt) and 204.6 Kt of plastic waste have been, respectively, generated by the Persian Gulf and the Gulf of Oman littoral states in 2016. Most likely, the mass of plastic waste entering the Persian Gulf and the Gulf of Oman in 2016 was ranged from 155 to 413.4 Kt and 29.2-77.9 Kt, respectively. Without implementation of effective waste management strategies, it is estimated that by 2030, the mass of plastic waste entering the Persian Gulf will increase to 199.4-531.6 Kt, while in the Gulf of Oman it would be about 40.4-107.7 Kt. The entry of plastic waste into the Persian Gulf and the Gulf of Oman has been expected to increase by 29% and 38% in 2030, respectively. As a result, the related cumulative environmental and health effects can be more intensive. It can be emphasized that all countries located in the coastal areas of the Persian Gulf and the Gulf of Oman need to modify their solid waste management, plastic waste in particular, policies to conserve sensitive marine ecosystems.

Estimation of plastic waste inputs from land into the Caspian Sea: A significant unseen marine pollution.

It has been proven that there is an extensive bulk of plastic debris in marine ecosystems. The present study analyzed solid waste generation, its management and final disposal methods in Caspian Sea coastal countries, and the amount of plastic waste entering the Caspian Sea. The results showed that, on average, more than 90% of waste in the Caspian Sea coastal countries is mismanaged. According to our estimates, 425 kilotons (Kt) of plastic waste was generated by Caspian Sea coastal countries in 2016, of which, with high probability, 58-155 Kt find their way to the Caspian Sea. It is estimated that without improved waste management infrastructures, the amount of plastic waste entering the Caspian Sea will increase to 68-182 Kt by 2030, an increase of about 15%. Accordingly, the related cumulative environmental and health problems could be more severe. All countries located in the coastal areas of the Caspian Sea should revise their solid waste and plastic waste management programs to protect that sensitive marine ecosystem.

Data for efficiency comparison of raw pumice and manganese-modified pumice for removal phenol from aqueous environments-Application of response surface methodology.

Present deadest collection was aimed to evaluate the efficiency of raw pumice (RWP) and Mn-modified pumice (MMP). Response surface methodology (RSM) based on the central composite designs (CCD) was applied to evaluate the effects of independent variables including pH, adsorbents dosage, contact time and adsorbate concentration on the response function and the best response values were predicted. The Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD) and scanning electron microscopy (SEM) were used to characterize the adsorbents. Based on acquired data, the maximum efficiency removal of phenol was obtained 89.14% and 100% for raw and Mn-modified pumice respectively. The obtained data showed pH was effective parameter on phenol removal among the different variables. Evaluation of data using isotherms and kinetics models showed the fitted with Langmuir isotherm and pseudo second order kinetic for both adsorbents. According to obtained data was observed that modification of pumice can improve the efficiency removal of phenol to meet the effluent standards.