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1.
Environ Anal Health Toxicol ; 38(4): e2023029-0, 2023 Dec.
Artigo em Inglês | MEDLINE | ID: mdl-38298048

RESUMO

The industrial sector stands out as a significant contributor to environmental pollution. Those who reside in close proximity to industrial areas commonly harbor concerns about potential health and environmental hazards. This study aimed to find out the perception of risk and self-reported health impacts among individuals living near industries in Godawari Municipality, Lalitpur, Nepal. Conducted as a community-based cross-sectional study, it involved 270 households. Face-to-face interviews were employed, utilizing a pretested structured questionnaire. The study zone encompassed the communities of Godawari Municipality within a 3-kilometer radius of industrial sites. Specifically, stone mines, stone crushers, and brick kilns were purposefully selected, while study participants were randomly sampled using a random table. Data analysis was performed using IBM SPSS, incorporating both univariate and bivariate techniques. Among those residing near industrial zones, a mere 9.6 % reported experiencing wheezing or whistling in the past 12 months. A substantial 36.3% consistently felt stressed due to industrial activities in their vicinity. Approximately half (51.9 %) of the participants indicated that the contaminated air in the area had adverse effects on human health. Furthermore, a palpable perception of elevated risk was associated with the proximity of industries (p<0.001). Over half of the participants perceived a notable risk stemming from the presence of industries near their homes, largely due to pollutants. These individuals also disclosed various health repercussions and expressed significant apprehension regarding their future well-being in the area. The implications of these findings are substantial, particularly for local-level planning and the development of industrial sites. Addressing the concerns surrounding people's heightened perception of risk from nearby industries is pivotal in fostering harmonious coexistence and informed decision-making.

2.
Nanoscale ; 10(34): 15956-15966, 2018 Aug 30.
Artigo em Inglês | MEDLINE | ID: mdl-30132491

RESUMO

It has been a challenge to use transition metal oxides as anode materials in Li-ion batteries due to their low electronic conductivity, poor rate capability and large volume change during charge/discharge processes. Here, we present the first demonstration of a unique self-recovery of capacity in transition metal oxide anodes. This was achieved by reducing tungsten trioxide (WO3) via the incorporation of urea, followed by annealing in a nitrogen environment. The reduced WO3 successfully self-retained the Li-ion cell capacity after undergoing a sharp decrease upon cycling. Significantly, the reduced WO3 also exhibited excellent rate capability. The reduced WO3 exhibited an interesting cycling phenomenon where the capacity was significantly self-recovered after an initial sharp decrease. The quick self-recoveries of 193.21%, 179.19% and 166.38% for the reduced WO3 were observed at the 15th (521.59/457.41 mA h g-1), 36th (538.49/536.61 mA h g-1) and 45th (555.39/555.39 mA h g-1) cycles respectively compared to their respective preceding discharge capacity. This unique self-recovery phenomenon can be attributed to the lithium plating and conversion reaction which might be due to the activation of oxygen vacancies that act as defects which make the WO3 electrode more electrochemically reactive with cycling. The reduced WO3 exhibited a superior electrochemical performance with 959.1/638.9 mA h g-1 (1st cycle) and 558.68/550.23 mA h g-1 (100th cycle) vs. pristine WO3 with 670.16/403.79 mA h g-1 (1st cycle) and 236.53/234.39 mA h g-1 (100th cycle) at a current density of 100 mA g-1.

3.
ACS Appl Mater Interfaces ; 10(21): 17883-17895, 2018 May 30.
Artigo em Inglês | MEDLINE | ID: mdl-29741353

RESUMO

The core plays a crucial role in achieving high performance of linear hole transport materials (HTMs) toward the perovskite solar cells (PSCs). Most studies focused on the development of fused heterocycles as cores for HTMs. Nevertheless, nonfused heterocycles deserve to be studied since they can be easily synthesized. In this work, we reported a series of low-cost triphenylamine HTMs (M101-M106) with different nonfused cores. Results concluded that the introduced core has a significant influence on conductivity, hole mobility, energy level, and solubility of linear HTMs. M103 and M104 with nonfused oligothiophene cores are superior to other HTMs in terms of conductivity, hole mobility, and surface morphology. PSCs based on M104 exhibited the highest power conversion efficiency of 16.50% under AM 1.5 sun, which is comparable to that of spiro-OMeTAD (16.67%) under the same conditions. Importantly, the employment of M104 is highly economical in terms of the cost of synthesis as compared to that of spiro-OMeTAD. This work demonstrated that nonfused heterocycles, such as oligothiophene, are promising cores for high performance of linear HTMs toward PSCs.

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