Chronopotentiometric Evaluation of Ionization Degree and Dissociation Constant of Imidazolium-Based Ionic Liquid [C6Meim][NTf2] in Polymeric Plasticized Membranes.

Ionic liquids (ILs) have a wide variety of applications in modern electrochemistry due to their unique electrolytic properties. In particular, they are promising candidates as dopants for polymeric membranes in potentiometric sensors and liquid-junction free reference electrodes. However, the effective use of ILs requires a comprehensive understanding of their electrolytic behavior in the polymeric phase. We report here the exploration of the electrolytic and diffusion properties of IL 1-hexyl-3-methyl-1H-imidazol-3-ium bis[(trifluoromethyl)sulfonyl]amide ([C6Meim][NTf2]) in a poly(vinyl chloride) matrix. Chronopotentiometry is utilized to determine the concentration of charge carriers, ionic diffusion coefficients and apparent dissociation constant of [C6Meim][NTf2] in PVC membranes plasticized with a mixture of [C6Meim][NTf2] and bis(2-ethylhexyl) sebacate (DOS) over a wide range of IL concentrations. The diffusion properties of [C6Meim][NTf2] are confirmed by NMR-diffusometry. The non-monotonic electrolytic behavior of the IL in PVC-DOS matrix is described for the first time. A maximum ionization degree and diffusion coefficient is observed at 30 wt.% of IL in the plasticizing mixture. Thus, it is shown that by varying the flexible parameter of the IL to plasticizer ratio in the polymeric phase one can tune the electrolytic and transport properties of sensing PVC membranes.

Simple and Cost-Efficient Classification of Ballpoint Pen Inks Using Digital Color Analysis.

We report here a simple and cost-effective technique for classification of the samples of writing inks based on their digital color analysis (DCA). The dynamics of artificial aging of writing inks under UV irradiation was studied by means of DCA for the first time. The color of ballpoint pen marks was recorded over time using an ordinary consumer DSLR camera. The inks were classified according to the parameters of their color degradation curves with precision superior to conventional Raman scattering method, which serves as a proof-of-concept of the proposed approach. The reported approach has broad prospects for implementation by criminalists for document investigation when document forgery is suspected. The proposed technique can be of interest not only in the field of forensic science but also for those who deal with dyes and dye-containing materials and their degradation over time as well as for the study of any processes, the evolution of which is reflected in a color change.