Bioethanol production from agricultural residues as lignocellulosic biomass feedstock's waste valorization approach: A comprehensive review.

Bioenergy is becoming very popular, drawing attention as a renewable energy source that may assist in managing growing energy costs, besides possibly affording revenue to underprivileged farmers and rural populations worldwide. Bioethanol made from agricultural residual-biomass provides irreplaceable environmental, socioeconomic, and strategic benefits and can be considered as a safe and cleaner liquid fuel alternative to traditional fossil fuels. There is a significant advancement made at the bench scale towards fuel ethanol production from agricultural lignocellulosic materials (ALCM). These process technologies include pretreatment of ALCM biomass employment of cellulolytic enzymes for depolymerizing carbohydrate polymers into fermentable sugars to effectively achieve it by applying healthy fermentative microbes for bioethanol generation. Amongst all the available process methods, weak acid hydrolysis followed by enzymatic hydrolysis process technique. Recovering higher proficient celluloses is more attractive in terms of economic benefits and long-term environmental effects. Besides, the state of ALCM biomass based bioethanol production methods is discussed in detail, which could make it easier for the scientific and industrial communities to utilize agricultural leftovers properly.

Green synthesis, characterization, and application of metal oxide nanoparticles for mercury removal from aqueous solution.

In this work, a novel surface-modified, green-based wheat straw-supported magnetite nanoparticles (Fe3O4-NPs) were synthesized via the green synthesis method, and the adsorption of mercury (Hg(II)) ion from aqueous solutions was methodically investigated. The synthesized wheat straw-supported magnetite (Fe3O4-WSS) NPs were characterized using X-ray diffraction (XRD), Fourier transform-infrared spectroscopy (FT-IR), thermogravimetric analysis (TGA), and scanning electron microscopic (SEM) methods. FT-IR and TGA confirmed that the surface of Fe3O4-NPs was functionalized well. The XRD analysis revealed the existence of magnetite in the synthesized wheat straw-supported Fe3O4-NPs of 19.83 nm average crystalline size. SEM analysis showed Fe3O4-NPs were almost spherical, with an average particle size of 22.48 nm. Adsorption studies were carried out to investigate the adsorption of Hg(II) ions onto Fe3O4-WSS NPs and the effect of various adsorption parameters such as pH, time, adsorbent dosage, and Hg(II) ion concentration. The optimum adsorption conditions were obtained: pH of 6, contact time of 45 min, adsorbate of 40 mg/L, and adsorbent of 1 g. A maximum of 98.04% Hg(II) ion removal efficiency was obtained at these optimum conditions. FT-IR analysis also indicated that surface functional groups such as C = C,-OH, and C-C of the newly produced Fe3O4-NPs led to the more efficient removal of Hg(II) from aqueous solution. The synthesized nano-adsorbent showed an excellent adsorption capability of 101.01 mg/g. Hg(II) ions adsorption onto Fe3O4-WSS NPs fitted well with the Langmuir adsorption isotherm model. Therefore, these reasonable findings reveal that Fe3O4-WSS NPs are an efficient and promising adsorbent for Hg(II) removal from aqueous water environments.