Large-Area Printed Oxide Film Sensors Enabling Ultrasensitive and Dual Electrical/Colorimetric Detection of Hydrogen at Room Temperature.

Commercial hydrogen (H2) sensors operate at high temperatures, which increases power consumption and poses a safety risk owing to the flammable nature of H2. Here, a polymer-noble metal-metal oxide film is fabricated using the spin-coating and printing methods to realize a highly sensitive, low-voltage operation, wide-operating-concentration, and near-monoselective H2 sensor at room temperature. The H2 sensors with an optimized thickness of Pd nanoparticles and SnO2 showed an extremely high response of 16,623 with a response time of 6 s and a recovery time of 5 s at room temperature and 2% H2. At the same time, printed flexible sensors demonstrate excellent sensitivity, with a response of 2300 at 2% H2. The excellent sensing performance at room temperature is due to the optimal SnO2 thickness, corresponding to the Debye length and the oxygen and H2 spillover caused by the optimized coverage of the Pd catalyst. Furthermore, multistructures of WO3 and SnO2 films are used to fabricate a new type of dual-signal sensor, which demonstrated simultaneous conductance and transmittance, i.e., color change. This work provides an effective strategy to develop robust, flexible, transparent, and long-lasting H2 sensors through large-area printing processes based on polymer-metal-metal oxide nanostructures.

Dual Responsive Dependent Background Color Based on Thermochromic 1D Photonic Crystal Multilayer Films.

In this paper, we present dual responsive one-dimensional (1D) photonic crystal (PC) multilayer films that utilize a high-humidity environment and temperature. Dual responsive 1D PC multilayer films are fabricated on precoated thermochromic film by sequential alternate layer deposition of photo-crosslinkable poly(2-vinylnaphthalene-co-benzophenone acrylate) (P(2VN-co-BPA)) as a high refractive index polymer, and poly(4-vinylpyrollidone-co-benzophenone acrylate) P(4VP-co-BPA) as a low refractive index polymer. The thermochromic film shows a vivid color transition from black to white at 28 °C. Three different colors of thermochromic 1D PC multilayer films are prepared by thickness modulation of P(4VP-co-BPA) layers, and the films on a black background exhibit visible spectrum color only in a high-humidity environment (over 90% relative humidity (RH)). For the three films placed on a hands display, three different composite colors are synthesized by the reflection of light, including yellow, magenta, and cyan, due to the changing of backgrounds from black to white with temperature. Additionally, the films show remarkable color transitions with reliable reversibility. The films can be applied as anti-counterfeiting labels and can be used for smart decoration films. To the best of our knowledge, this is the first report of dual response colorimetric films that change color in various ways depending on temperature and humidity changes, and we believe that it can be applied to various applications.

Polymer-based flexible NOx sensors with ppb-level detection at room temperature using breath-figure molding.

A strategically designed polymer semiconductor thin film morphology with both high responsivity to the specific gas analyte and high signal transport efficiency is reported to realize high-performance flexible NOx gas sensors. Breath-figure (BF) molding of polymer semiconductors enables a finely defined degree of nano-porosity in polymer films with high reproducibility while maintaining high charge carrier mobility characteristics of organic field effect transistors (OFETs). The optimized BF-OFET with a donor-acceptor copolymer exhibits a maximum responsivity of over 104%, sensitivity of 774% ppm-1, and limit of detection (LOD) of 110 ppb against NO at room temperature. When tested across at NO concentrations of 0.2-10 ppm, the BF-OFET gas sensor exhibits a response time of 100-300 s, which is suitable for safety purposes in practical applications. Furthermore, BF-OFETs show a high reproducibility as confirmed by statistical analysis on 64 independently fabricated devices. The selectivity of NOx analytes is tested by comparing the sensing ability of BF-OFETs with those of other reducing gases and volatile organic compounds; the BF-OFET gas sensor platform monitors specific gas analytes based on their polarity and magnitude of sensitivity. Finally, flexible BF-OFETs conjugated with plastic substrates are demonstrated and they exhibit a sensitivity of 500% ppm-1 and a LOD of 215 ppb, with a responsivity degradation of only 14.2% after 10 000 bending cycles at 1% strain.