Green dispersants for oil spill response: A comprehensive review of recent advances.

Green dispersants are so-called "green" because they are renewable (from bio-based sources), non-volatile (from ionic liquids), or are from naturally available solvents (vegetable oils). In this review, the effectiveness of different types of green dispersants, namely, protein isolates and hydrolysates from fish and marine wastes, biosurfactants from bacterial and fungal strains, vegetable-based oils such as soybean lecithin and castor oils, as well as green solvents like ionic liquids are reviewed. The challenges and opportunities offered by these green dispersants are also elucidated. The effectiveness of these dispersants varies widely and depends on oil type, dispersant hydrophilicity/hydrophobicity, and seawater conditions. However, their advantages lie in their relatively low toxicity and desirable physico-chemical properties, which make them potentially ecofriendly and effective dispersants for future oil spill response.

Updated review on microplastics in water, their occurrence, detection, measurement, environmental pollution, and the need for regulatory standards.

The gravity of the impending threats posed by microplastics (MPs) pollution in the environment cannot be over-emphasized. Several research studies continue to stress how important it is to curb the proliferation of these small plastic particles with different physical and chemical properties, especially in aquatic environments. While several works on how to monitor, detect and remove MPs from the aquatic environment have been published, there is still a lack of explicit regulatory framework for mitigation of MPs globally. A critical review that summarizes recent advances in MPs research and emphasizes the need for regulatory frameworks devoted to MPs is presented in this paper. These frameworks suggested in this paper may be useful for reducing the proliferation of MPs in the environment. Based on all reviewed studies related to MPs research, we discussed the occurrence of MPs by identifying the major types and sources of MPs in water bodies; examined the recent ways of detecting, monitoring, and measuring MPs routinely to minimize projected risks; and proposed recommendations for consensus regulatory actions that will be effective for MPs mitigation.

Sorption and removal of crude oil spills from seawater using peat-derived biochar: An optimization study.

Bio-based sorbents are preferred over chemical-based methods for the clean-up of crude oil spills in marine environments because bio-based sorbents are more environmentally friendly. This study evaluates the use of peat-derived biochar (PB) as a bio-sorbent for the sorption and removal of crude oil spills from synthetic seawater. Experiments were designed to determine the effect of four operating factors (PB/crude oil contact time, PB dosage, oil dosage, and temperature) on two performance indicators (crude oil sorption capacity of PB, S, and oil removal efficiency, R%). Regression models containing linear, quadratic, and two-way interaction terms were developed to predict S and R% from the four factors. Response surface methodology (RSM) was employed to identify the optimum conditions for the sorption and removal of crude oil from seawater. The performance indicators were predicted with a high degree of accuracy, i.e. with coefficient of determination (R2) values exceeding 90%. The optimum values of S and R% were estimated to be 32.5 g of crude oil/g of sorbent and 91.2% respectively. These optimum values were attained after 70 min of PB/crude oil contact time and at a temperature of 45 °C. The spent sorbent maintained its performance after three cycles of regeneration and reuse, suggesting that the material is reusable.

Pyrolysis of date palm waste to biochar using concentrated solar thermal energy: Economic and sustainability implications.

A system of concentrated solar energy for pyrolysis of date palm waste to biochar is designed and simulated using SuperPro Designer v8.5. Both economic and environmental sustainability implications are evaluated by bench-marking with the conventional process (electric heating-based pyrolysis). Economic analysis shows that this process is more economically viable than the conventional process, with payback time (PBT) of 4 years and 132 days, internal rate of return (IRR) of 14.8%, return on investment (ROI) of 22.9% and gross margin of 35.5%. Environmental impact assessment shows that CO2 emissions from concentrated solar energy-based pyrolysis accounts for only 38% of that of the conventional pyrolysis, indicating that concentrated solar energy pyrolysis is more environmentally friendly. Sensitivity analysis shows that PBT is more sensitive to changes in biochar selling price than changes in the cost of acquiring date palm waste. This process presents sustainable opportunities for biochar production while reducing life cycle emissions and costs.

Membrane bioreactors and electrochemical processes for treatment of wastewaters containing heavy metal ions, organics, micropollutants and dyes: Recent developments.

Research and development activities on standalone systems of membrane bioreactors and electrochemical reactors for wastewater treatment have been intensified recently. However, several challenges are still being faced during the operation of these reactors. The current challenges associated with the operation of standalone MBR and electrochemical reactors include: membrane fouling in MBR, set-backs from operational errors and conditions, energy consumption in electrochemical systems, high cost requirement, and the need for simplified models. The advantage of this review is to present the most critical challenges and opportunities. These challenges have necessitated the design of MBR derivatives such as anaerobic MBR (AnMBR), osmotic MBR (OMBR), biofilm MBR (BF-MBR), membrane aerated biofilm reactor (MABR), and magnetically-enhanced systems. Likewise, electrochemical reactors with different configurations such as parallel, cylindrical, rotating impeller-electrode, packed bed, and moving particle configurations have emerged. One of the most effective approaches towards reducing energy consumption and membrane fouling rate is the integration of MBR with low-voltage electrochemical processes in an electrically-enhanced membrane bioreactor (eMBR). Meanwhile, research on eMBR modeling and sludge reuse is limited. Future trends should focus on novel/fresh concepts such as electrically-enhanced AnMBRs, electrically-enhanced OMBRs, and coupled systems with microbial fuel cells to further improve energy efficiency and effluent quality.

Comparative cradle-to-grave life cycle assessment of biogas production from marine algae and cattle manure biorefineries.

The environmental impacts resulting from the cradle-to-grave life cycles of Enteromorpha prolifera macroalgae and cattle manure biorefineries are assessed and compared. Sensitivity analysis is carried out to evaluate the response of the impacts to changes in biogas application by using Simapro 7.3.3. Three scenarios are considered in the biorefineries. In the first and second scenarios, the biogas produced is considered to be used for electricity production and transportation, respectively. In the third scenario, the biogas is considered to be recycled back to the systems. Process energy requirements and transportation of inputs contribute the largest share of the overall impacts. The cattle manure biorefinery is slightly more eco-friendly than the macroalgae biorefinery in Scenarios 1 and 2 because it requires more eco-friendly inputs. However, the macroalgae biorefinery becomes more eco-friendly than the cattle manure biorefinery in Scenario 3 because macroalgae require less energy and water for biogas production.

Recent improvements in oily wastewater treatment: Progress, challenges, and future opportunities.

Oily wastewater poses significant threats to the soil, water, air and human beings because of the hazardous nature of its oil contents. The objective of this review paper is to highlight the current and recently developed methods for oily wastewater treatment through which contaminants such as oil, fats, grease, and inorganics can be removed for safe applications. These include electrochemical treatment, membrane filtration, biological treatment, hybrid technologies, use of biosurfactants, treatment via vacuum ultraviolet radiation, and destabilization of emulsions through the use of zeolites and other natural minerals. This review encompasses innovative and novel approaches to oily wastewater treatment and provides scientific background for future work that will be aimed at reducing the adverse impact of the discharge of oily wastewater into the environment. The current challenges affecting the optimal performance of oily wastewater treatment methods and opportunities for future research development in this field are also discussed.

Numerical modeling of an electrically enhanced membrane bioreactor (MBER) treating medium-strength wastewater.

In this paper, a numerical model of an electrically enhanced membrane bioreactor (MBER) was developed. MBER is a reactor that combines biological decomposition, membrane filtration and electrocoagulation of wastewater pollutants in a hybrid unit. To assess its design, the final contents and removal efficiencies of organics, nutrients, and metals were carried out using varying influent compositions. In a 60-day test of a laboratory-scale MBER, experimental results were used to calibrate and validate the model. The modeling results were in agreement with the experimental data and showed that the MBER can remove 99% of total phosphorus (TP), 99.9% of chemical oxygen demand (COD), 91% of total nitrogen (TN), 79% of nickel (Ni), 89% of iron (Fe), and 80% of chromium (Cr), using a current density of 15 A/m(2) intermittently supplied in a cycle of 5 min ON and 15 min OFF.

Enhanced sludge properties and distribution study of sludge components in electrically-enhanced membrane bioreactor.

This study investigated the impact of electric field on the physicochemical and biological characteristics of sludge wasted from an electrically-enhanced membrane bioreactor treating medium-strength raw wastewater. This method offers a chemical-free electrokinetic technique to enhance sludge properties and remove heavy metals. For example, sludge volume index (SVI), time-to-filter (TTF), mean sludge particle diameter (PSD), viscosity, and oxidation-reduction potential (ORP) of 21.7 mL/g, 7 min, 40.2 µm, 3.22 mPa s, and -4.9 mV were reported, respectively. Also, X-ray fluorescence (XRF) and X-ray diffraction (XRD) analyses provided mechanisms for heavy metal removal so as to establish relevant pathways for nutrient recovery. Furthermore, variations in dissolved oxygen (DO), conductivity, viscosity, ORP, total suspended solids (MLSS), and volatile suspended solids (MLVSS) were interrelated to evaluate the quality of wasted sludge. A pathway study on the transport and chemical distribution of nutrients and metals in sludge showed great potential for metal removal and nutrient recovery.