What is the deal with the Green Deal: Will the new strategy help to improve European freshwater quality beyond the Water Framework Directive?

Agricultural land use covers almost half of the EU territory and reducing nutrient and pesticide losses to freshwaters is central to existing EU policy. However, the progress of improving freshwater quality and reducing eutrophication is slow and lags behind targets. The Green Deal is a key element of the EU plans to implement the United Nation's Sustainable Development Goals. Here, we discuss the opportunities that the Green Deal and associated strategies may provide for the achievement of the water quality goals of the Water Framework Directive in agricultural landscapes. We welcome Green Deal's aspirational stated goals. However, the reliance of mitigation of diffuse agricultural pollution on the reform of the Common Agricultural Policy represents grave risks for practical implementation and the achievement of the Green Deal objectives. We also argue that the new strategies should be targeted at tackling and understanding the sources of water quality problems along the full pollution continuum. To maximise the opportunities for tackling diffuse pollution from agricultural land use and achieving the delayed water quality targets, we stress that a range of targeted new instruments will be needed to close the gaps in the pollution continuum 'from source to impact'. These gaps include: (I) smart and standardised monitoring of the impacts of proposed eco-schemes and agri-environment-climate measures, (ii) active restoration of agricultural streams and ditches and their floodplains to reduce secondary pollution sources, (iii) options to draw down nutrient levels to or below the agronomic optimum that reduce legacy sources, (iv) integrating farm-scale and catchment-scale analysis of trade-offs in reducing different pollutants and their combined effects, and finally (v) accounting for emerging pressures to freshwater quality due to climate change. Incorporation of the pollution continuum framework into tackling diffuse agricultural pollution will ensure that the European water-related policy goals are achieved.

Tracing of particulate organic C sources across the terrestrial-aquatic continuum, a case study at the catchment scale (Carminowe Creek, southwest England).

Soils deliver crucial ecosystem services, such as climate regulation through carbon (C) storage and food security, both of which are threatened by climate and land use change. While soils are important stores of terrestrial C, anthropogenic impact on the lateral fluxes of C from land to water remains poorly quantified and not well represented in Earth system models. In this study, we tested a novel framework for tracing and quantifying lateral C fluxes from the terrestrial to the aquatic environment at a catchment scale. The combined use of conservative plant-derived geochemical biomarkers n-alkanes and bulk stable δ13C and δ15N isotopes of soils and sediments allowed us to distinguish between particulate organic C sources from different land uses (i.e. arable and temporary grassland vs. permanent grassland vs. riparian woodland vs. river bed sediments) (p<0.001), showing an enhanced ability to distinguish between land use sources as compared to using just n-alkanes alone. The terrestrial-aquatic proxy (TAR) ratio derived from n-alkane signatures indicated an increased input of terrestrial-derived organic matter (OM) to lake sediments over the past 60years, with an increasing contribution of woody vegetation shown by the C27/C31 ratio. This may be related to agricultural intensification, leading to enhanced soil erosion, but also an increase in riparian woodland that may disconnect OM inputs from arable land uses in the upper parts of the study catchment. Spatial variability of geochemical proxies showed a close coupling between OM provenance and riparian land use, supporting the new conceptualization of river corridors (active river channel and riparian zone) as critical zones linking the terrestrial and aquatic C fluxes. Further testing of this novel tracing technique shows promise in terms of quantification of lateral C fluxes as well as targeting of effective land management measures to reduce soil erosion and promote OM conservation in river catchments.

Accelerated export of sediment and carbon from a landscape under intensive agriculture.

The export of total organic carbon (particulate and dissolved) from terrestrial to aquatic ecosystems has important implications for water quality and the global carbon cycle. However, most research to date has focused on DOC losses from either forested or peaty catchments, with only limited studies examining the controls and rates of total fluvial carbon losses from agricultural catchments, particularly during storm events. This study examined the controls and fluxes of total suspended sediment (SS), total particulate (TPC) and dissolved organic carbon (DOC) from two adjacent catchments with contrasting intensive agricultural and semi-natural land-use. Data from 35 individual storm events showed that the agricultural catchment exported significantly higher SS concentrations on a storm-by-storm basis than the semi-natural catchment, with peak discharge exerting a greater control over SS, TPC and DOC concentrations. Baseflow DOC concentrations in the agricultural catchment were significantly higher. DOC quality monitored during one simultaneous rainfall event differed between the two study catchments, with more humic, higher molecular weight compounds prevailing in the agricultural catchment and lower molecular weight compounds prevailing in the semi-natural catchment. During an eight month period for which a comparable continuous turbidity record was available, the estimated SS yields from the agricultural catchment were higher than from the semi-natural catchment. Further, the agricultural catchment exported proportionally more TPC and a comparable amount of DOC, despite a lower total soil carbon pool. These results suggest that altered hydrological and biogeochemical processes within the agricultural catchment, including accelerated soil erosion and soil organic matter turnover, contributed to an enhanced fluvial SS and carbon export. Thus, we argue that enhancing semi-natural vegetation within intensively farmed catchments could reduce sediment and carbon losses from these areas and increase their resilience to more extreme hydrological events, anticipated as a result of climate change.