Composition Analysis of the Solid Electrolyte Interface of NaK Anodes in Na-Ion Batteries.

Sodium-ion batteries have emerged as a promising alternative to Li-ion batteries due to the abundance of sodium. However, anodes in Na-ion batteries face challenges such as dendrite formation and an unstable solid electrolyte interface layer. To address these challenges, NaK liquid metal alloy anodes have been proposed as an alternative because they do not form dendrites. In our study, we demonstrate that the NaK alloy anode interacts with the commonly used ethylene carbonate and dimethyl carbonate electrolyte, leading to a continuously growing unstable SEI layer, evidenced by cycling failures under 100 cycles and an increasing charge transfer resistance in electrochemical impedance spectroscopy studies. In situ surface-enhanced Raman spectroscopy and X-ray photoelectron spectroscopy reveal that over the course of cycling the surface of the NaK anode becomes increasingly sodium-rich. After 30 cycles, XPS analysis detects only trace amounts of potassium on the NaK anode surface. When the electrolyte is analyzed postcycling using inductively coupled plasma optical emission spectroscopy, there is a noticeable increase in potassium levels, suggesting that potassium metal dissolves into the electrolyte. The introduction of a 10 wt % fluoroethylene carbonate additive can mitigate this problem to some extent, enabling an enhanced cycling performance of up to 800 cycles at 1C. Nevertheless, the dissolution of K metal is still evident in the XPS results, albeit to a lesser degree. These discoveries provide valuable insights for designing a more robust SEI layer for the NaK anode.

Enabling Acidic Oxygen Reduction Reaction in a Zinc-Air Battery with Bipolar Membrane.

Zinc-air batteries are a promising alternative to lithium ion batteries due to their large energy density, safety, and low production cost. However, the stability of the zinc-air battery is often low due to the formation of dendrite which causes short circuiting and the CO2 adsorption from the air which causes carbonate formation on the air electrode. In this work, we demonstrate a zinc-air battery design with acidic oxygen reduction reaction for the first time via the incorporation of a bipolar membrane. The bipolar membrane creates a locally acidic environment in the air cathode which could lead to a higher oxygen reduction reaction activity and a better 4-electron selectivity toward water instead of the 2-electron pathway toward peroxide. Locally acidic air cathode is also effective at improving the cell's durability by preventing carbonate formation. Gas chromatography confirms that CO2 adsorption is 7 times lower in the bipolar membrane compared to a conventional battery separator. A stable cycling of 300+ hours is achieved at 5 mA/cm2. Dendrite formation is also mitigated due to the mechanical strength of the membrane. The insights from this work could be leveraged to develop a better zinc-air battery design for long-term energy storage applications.

Ductile cooling phase change material.

Cooling represents a considerable fraction of energy consumption. However, it is indispensable to develop eco-friendly, biocompatible, and ductile cooling materials for personal applications. In this study, we demonstrate the ductile cooling ability with phase change of thermally passivated hydrogel composite materials with additive manufacturing ability. Thermal evaluation of such water-based composites indicates a superior cold retention capacity with a cooling comfort over 6 hours, while the composite displays a full recovery when strained up to 80% in uniaxial compression tests as a result of the intertwining between covalent and ionic bonds. A three-layered rectangular model was utilized to simulate the problem in a steady-state thermal analysis to study the cooling effect. Our findings indicate the potential of hydrogel as a cooling phase-change medium and its contribution towards ductile cooling applications.