RESUMO
This work presents a comprehensive study of the combustion performance of an industrial furnace in an olefin plant using computational fluid dynamics (CFD) simulations. The focus was on analyzing the heat release pattern of bottom burners to optimize the furnace efficiency in steam-cracking processes. The study developed an accurate computational fluid dynamics (CFD) model for predicting combustion behavior in a cracking furnace. The computational model was validated by comparing the simulation results with industrial data and was used to investigate the impact of burner clogging and the importance of small holes in the body of burners in the furnace. The results also provided insights into the influence of excess air, temperature distribution, fluid behavior, composition of combustion products, and thermal efficiency of the furnace. The presented results contributed to a better understanding of parameters controlling combustion performance in steam-cracking furnaces.
RESUMO
The contamination of the aquatic environment with antibiotics is among the major and developing problems worldwide. The present study investigates the potential of adsorbent magnetite-chitosan nanoparticles (Fe3O4/CS NPs) for removing trimethoprim (TMP) and sulfamethoxazole (SMX). For this purpose, Fe3O4/CS NPs were synthesized by the co-precipitation method, and the adsorbent characteristics were investigated using XRD, SEM, TEM, pHzpc, FTIR, and VSM. The effect of independent variables (pH, sonication time, adsorbent amount, and analyte concentration) on removal performance was modeled and evaluated by Box-Behnken design (BBD). The SEM image of the Fe3O4/CS adsorbent showed that the adsorbent had a rough and irregular surface. The size of Fe3O4/CS crystals was about 70 nm. XRD analysis confirmed the purity and absence of impurities in the adsorbent. TEM image analysis showed that the adsorbent had a porous structure, and the particle size was in the range of nanometers. In VSM, the saturation magnetization of Fe3O4/CS adsorbent was 25 emu g-1 and the magnet could easily separate the adsorbent from the solution. The results revealed that the optimum condition was achieved at a concentration of 22 mg L-1, a sonication time of 15 min, an adsorbent amount of 0.13 g/100 mL, and a pH of 6. Among different solvents (i.e., ethanol, acetone, nitric acid, and acetonitrile), significant desorption of TMP and SMX was achieved using ethanol. Also, results confirmed that Fe3O4/CS NPs can be used for up to six adsorption/desorption cycles. In addition, applying the Fe3O4/CS NPs on real water samples revealed that Fe3O4/CS NPs could remove TMP and SMX in the 91.23-95.95% range with RSD (n = 3) < 4. Overall, the Fe3O4/CS NPs exhibit great potential for removing TMP and SMX antibiotics from real water samples.
