1.
Acta Crystallogr Sect E Struct Rep Online
; 68(Pt 2): m187, 2012 Feb 01.
Artigo
em Inglês
| MEDLINE
| ID: mdl-22346858
RESUMO
The water-coordinated Ni(2+) cation in the title compound, [Ni(C(10)H(5)N(3)O(4))(H(2)O)](n), assumes an octa-hedral NiN(3)O(3) coord-ination mode and is N,O-chelated by two deprotonated 2-(pyridin-4-yl)-1H-imidazole-4,5-dicarb-oxy-lic acid (HPyImDC(2-)) ligands, forming a layer structure extending in the bc plane. The chains are arranged along the b-axis direction, forming a layer structure extending in the bc plane. O-Hâ¯O hydrogen bonding between the layers results in the formation of a three-dimensional supra-molecular framework. The structure is isotypic with the Zn analogue [Li et al. (2009). Cryst. Growth Des.6, 3423-3431].