Paper Thermoelectrics by a Solvent-Free Drawing Method of All Carbon-Based Materials.

As practical interest in the flexible or wearable thermoelectric generators (TEGs) has increased, the demand for the high-performance TEGs based on ecofriendly, mechanically resilient, and economically viable TEGs as alternatives to the brittle inorganic materials is growing. Organic or hybrid thermoelectric (TE) materials have been employed in flexible TEGs; however, their fabrication is normally carried out using wet processing such as spin-coating or screen printing. These techniques require materials dissolved or dispersed in solvents; thus, they limit the substrate choice. Herein, we have rationally designed solvent-free, all carbon-based TEGs dry-drawn on a regular office paper using few-layered graphene (FLG). This technique showed very good TE parameters, yielding a power factor of 97 µW m-1 K-2 at low temperatures. The p-type only device exhibited an output power of up to ∼19.48 nW. As a proof of concept, all carbon-based p-n TEGs were created on paper with the addition of HB pencil traces. The HB pencil exhibited low Seebeck coefficients (-7 µV K-1), and the traces were highly resistive compared to FLG traces, which resulted in significantly lower output power compared to the p-type only TEG. The demonstration of all carbon-based TEGs drawn on paper highlights the potential for future low-cost, flexible, and almost instantaneously created TEGs for low-power applications.

Lightweight and Bulk Organic Thermoelectric Generators Employing Novel P-Type Few-Layered Graphene Nanoflakes.

Graphene exhibits both high electrical conductivity and large elastic modulus, which makes it an ideal material candidate for many electronic devices. At present not much work has been conducted on using graphene to construct thermoelectric devices, particularly due to its high thermal conductivity and lack of bulk fabrication. Films of graphene-based materials, however, and their nanocomposites have been shown to be promising candidates for thermoelectric energy generation. Exploring methods to enhance the thermoelectric performance of graphene and produce bulk samples can significantly widen its application in thermoelectrics. Realization of bulk organic materials in the thermoelectric community is highly desired to develop cheap, Earth-abundant, light, and nontoxic thermoelectric generators. In this context, this work reports a new approach using pressed pellets bars of few-layered graphene (FLG) nanoflakes employed in thermoelectric generators (TEGs). First, FLG nanoflakes were produced by a novel dry physical grinding technique followed by graphene nanoflake liberation using plasma treatment. The resultant material is highly pure with very low defects, possessing 3 to 5-layer stacks as proved by Raman spectroscopy, X-ray diffraction measurement, and scanning electron microscopy. The thermal and electronic properties confirm the anisotropy of the material and hence the varied performance characteristics parallel to and perpendicular to the pressing direction of the pellets. The full thermoelectric properties were characterized both parallel and perpendicular to the pressing direction, and the proof-of-concept thermoelectric generators were fabricated with variable amounts of legs.