A critical review on mechanochemical processing of fly ash and fly ash-derived materials.

Fly ash (FA) is a solid, fine powder that constitutes a by-product obtained when coal, biomass, municipal solid waste or a mixture of these are combusted. This review article focuses on the mechanochemistry of coal fly ash (CFA), as well as highlights the issue of fly ash from municipal solid waste (MSW). In general, FA is regarded as a waste of public concern (since it contains hazardous components), which is primarily consumed in the construction industry, as well as in chemical synthesis and environmental engineering. However, the actual amount of FA recycled is still less than the amount produced, with the reuse rate of only up to 30 %. Due to its relatively low reactivity and heterogeneity, FA is commonly landfilled in huge quantities. Nevertheless, the physical and chemical properties of FA can be tailored, for example, by mechanical forces, ultimately leading to a higher value-added product. Currently, mechanochemistry (MC) is drawing attention in chemical synthesis, pollution remediation and waste management, especially as a possible solution for various drawbacks of conventional syntheses and processes. Mechanochemical processing of FA can be considered eco-friendly, inexpensive and efficient, in particular for processing tons of readily available fly ash already stored in ponds or landfills. With the aim of highlighting the hidden potential and facilitating the favorable use of FA, this article deals with FA as an environmentally challenging material, FA reactivity and recycling through mechanochemical processing, mechanochemical stabilization of heavy metals in FA, as well as up-to-date challenges for life cycle assessment (LCA) in evaluating FA-derived materials. Furthermore, all these full-potential aspects of FA mechanochemistry have not been addressed before, which is a valuable contribution to the existing literature.

A Critical Review on Modification Methods of Cement Composites with Nanocellulose and Reaction Conditions during Nanocellulose Production.

Nanocellulose (NC) is a natural polymer that has driven significant progress in recent years in the study of the mechanical properties of composites, including cement composites. Impressive mechanical properties, ability to compact the cement matrix, low density, biodegradability, and hydrophilicity of the surface of nanocellulose particles (which improves cement hydration) are some of the many benefits of using NCs in composite materials. The authors briefly presented a description of the types of NCs (including the latest, little-known shapes), showing the latest developments in their manufacture and modification. Moreover, NC challenges and opportunities are discussed to reveal its hidden potential, as well as the use of spherical and square/rectangular nanocellulose to modify cement composites. Intending to emphasize the beneficial use of NC in cementitious composites, this article discusses NC as an eco-friendly, low-cost, and efficient material, particularly for recycling readily available cellulosic waste. In view of the constantly growing interest in using renewable and waste materials in a wide range of applications, the authors hope to provide progress in using nanocellulose (NC) as a modifier for cement composites. Furthermore, this review highlights a gap in research regarding the preparation of new types of NCs, their application, and their impact on the properties of cementitious composites. Finally, the authors summarize and critically evaluate the type, dosage, and application method of NC, as well as the effects of these variables on the final properties of NC-derived cement composites. Nevertheless, this review article stresses up-to-date challenges for NC-based materials as well as future remarks in light of dwindling natural resources (including building materials), and the principles of a circular economy.

Mechanochemically Assisted Coal Fly Ash Conversion into Zeolite.

Mechanically treated fly ash (FA) was utilised to provide Al and Si atoms for zeolite synthesis. A combination of mechanical fly ash activation and classical hydrothermal synthesis led to favourable dissolution of activated fly ash and improved crystallization of zeolites. The milling activation step induced structural changes in FA to promote its reactivity in alkaline solution. The conversion of milled FA into zeolite materials was finally completed in the second step, during hydrothermal synthesis. The effect of such factors as crystallization temperature, milling time, and solution conditioning were systematically studied. The physicochemical properties characterising the obtained zeolite materials were determined via particle size distribution (PSD), nitrogen adsorption-desorption, X-ray fluorescence spectroscopy (XRF), scanning electron microscopy (SEM), and powder X-ray diffraction (XRD). As a result, the best samples achieved a high degree of crystallinity and an extensive specific surface area of 292 m2/g, 87.4 m2/g, 41.9 m2/g for Na-X, Na-P1, and Na-A, respectively. The obtained results provide new and useful data for utilising fly ash resources and synthesising other practical zeolites through an innovative, mechanochemically assisted, and template-free approach.