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J Nanosci Nanotechnol ; 6(2): 345-51, 2006 Feb.
Artigo em Inglês | MEDLINE | ID: mdl-16573031

RESUMO

Hybrid resins composed of vinylester (VE) and aliphatic amine (Al-Am)-cured cycloaliphatic epoxy (Cal-EP) were produced and their morphology and properties (toughness, water uptake) determined. According to atomic force microscopy (AFM) results achieved on physically etched (ion eroded) specimens the hybrid resins possessed a nanoscaled interpenetrating network (IPN) structure, the characteristics of which depended on the VE/EP ratio. Characteristics of the IPN morphology, viz strand width and mean roughness data increase with increasing amount of the EP component. The fracture mechanical data (K(Q) and G(Q)) pass a maximum as a function of the VE/EP ratio, similar to that of the phase segregation term (alpha). The latter was deduced from dynamic-mechanical thermal analysis (DMTA) traces. The water sorption and diffusion behavior of the interpenetrated VE/EP hybrids were controlled by the relative amount of the EP (Cal-EP+Al-Am) used.


Assuntos
Nanotecnologia , Difusão , Teste de Materiais , Microscopia de Força Atômica , Água
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