Nature-inspired adhesive systems.

Many organisms in nature thrive in intricate habitats through their unique bio-adhesive surfaces, facilitating tasks such as capturing prey and reproduction. It's important to note that the remarkable adhesion properties found in these natural biological surfaces primarily arise from their distinct micro- and nanostructures and/or chemical compositions. To create artificial surfaces with superior adhesion capabilities, researchers delve deeper into the underlying mechanisms of these captivating adhesion phenomena to draw inspiration. This article provides a systematic overview of various biological surfaces with different adhesion mechanisms, focusing on surface micro- and nanostructures and/or chemistry, offering design principles for their artificial counterparts. Here, the basic interactions and adhesion models of natural biological surfaces are introduced first. This will be followed by an exploration of research advancements in natural and artificial adhesive surfaces including both dry adhesive surfaces and wet/underwater adhesive surfaces, along with relevant adhesion characterization techniques. Special attention is paid to stimulus-responsive smart artificial adhesive surfaces with tunable adhesive properties. The goal is to spotlight recent advancements, identify common themes, and explore fundamental distinctions to pinpoint the present challenges and prospects in this field.

Self-Sorting in Diastereomeric Mixtures of Functionalized Dipeptides.

Self-sorting in functionalized dipeptide systems can be driven by the chirality of a single amino acid, both at a high pH in the micellar state and at a low pH in the gel state. The structures formed are affected to some degree by the relative concentrations of each component showing the complexity of such an approach. The structures underpinning the gel network are predefined by the micellar structures at a high pH. Here, we describe the systems prepared from two dipeptide-based gelators that differ only by the chirality of one of the amino acids. We provide firm evidence for self-sorting in the micellar and gel phases using small-angle neutron scattering and cryo-transmission electron microscopy (cryo-TEM), showing that complete self-sorting occurs across a range of relative concentrations.

Robust Underwater Oil-Repellent Biomimetic Ceramic Surfaces: Combining the Stability and Reproducibility of Functional Structures.

Robust underwater oil-repellent materials combining high mechanical strength and durability with superwettability and low oil adhesion are needed to build oil-repellent devices able to work in water, to manipulate droplet behavior, etc. However, combining all of these properties within a single, durable material remains a challenge. Herein, we fabricate a robust underwater oil-resistant material (Al2O3) with all of the above properties by gel casting. The micro/nanoceramic particles distributed on the surface endow the material with excellent underwater superoleophobicity (∼160°) and low oil adhesion (<4 µN). In addition, the substrate exhibits typical ceramic characteristics such as good antiacid/alkali properties, high salt resistance, and high load tolerance. These excellent properties make the material not only applicable to various liquid environments but also resistant to the impact of particles and other physical damage. More importantly, the substrate could still exhibit underwater superoleophobicity after being worn under specific conditions, as wear will create new surfaces with similar particle size distribution. This approach is easily scalable for mass production, which could open a pathway for the fabrication of practical underwater long-lasting functional interfacial materials.

A Tough Reversible Biomimetic Transparent Adhesive Tape with Pressure-Sensitive and Wet-Cleaning Properties.

Dry adhesives that combine strong adhesion, high transparency, and reusability are needed to support developments in emerging fields such as medical electrodes and the bonding of electronic optical devices. However, achieving all of these features in a single material remains challenging. Herein, we propose a pressure-responsive polyurethane (PU) adhesive inspired by the octopus sucker. This adhesive not only showcases reversible adhesion to both solid materials and biological tissues but also exhibits robust stability and high transparency (>90%). As the adhesive strength of the PU adhesive corresponds to the application force, adhesion could be adjusted by the preloading force and/or pressure. The adhesive exhibits high static adhesion (∼120 kPa) and 180° peeling force (∼500 N/m), which is far stronger than those of most existing artificial dry adhesives. Moreover, the adhesion strength is effectively maintained even after 100 bonding-peeling cycles. Because the adhesive tape relies on the combination of negative pressure and intermolecular forces, it overcomes the underlying problems caused by glue residue like that left by traditional glue tapes after removal. In addition, the PU adhesive also shows wet-cleaning performance; the contaminated tape can recover 90-95% of the lost adhesion strength after being cleaned with water. The results show that an adhesive with a microstructure designed to increase the contribution of negative pressure can combine high reversible adhesion and long fatigue life.

Stimuli-responsive surfaces for switchable wettability and adhesion.

Diverse unique surfaces exist in nature, e.g. lotus leaf, rose petal and rice leaf. They show similar contact angles but different adhesion properties. According to the different wettability and adhesion characteristics, this review reclassifies different contact states of droplets on surfaces. Inspired by the biological surfaces, smart artificial surfaces have been developed which respond to external stimuli and consequently switch between different states. Responsive surfaces driven by various stimuli, e.g. stretching, magnetic, photo, electric, temperature, humidity and pH, are discussed. Studies reporting on either atmospheric or underwater environments are discussed. The application of tailoring surface wettability and adhesion includes microfluidics/droplet manipulation, liquid transport and harvesting, water energy harvesting and flexible smart devices. Particular attention is placed on the horizontal comparison of smart surfaces with the same stimuli. Finally, the current challenges and future prospects in this field are also identified.

Highly fluorescent Ti3C2 MXene quantum dots for macrophage labeling and Cu2+ ion sensing.

Quantum dots, derived from two-dimensional (2D) materials, have shown promise in bioimaging, sensing and photothermal applications, and in white light emitting devices (WLEDs). Herein, nitrogen and phosphorus functionalized Ti3C2 MXene based quantum dots (N,P-MQDs) were successfully prepared through a top-bottom hydrothermal method. This type of photoluminescent quantum dots has realized green fluorescence for the first time at around 560 nm with a photoluminescence quantum yield (PLQY) of 20.1%, the highest ever reported; meanwhile, it also exhibits excellent photostability and pH resistance capacities. Comprehensive characterization and well-resolved density functional theory (DFT) calculation were implemented to determine the mechanism of fluorescence shift and enhancement. Furthermore, the N,P-MQDs have been proved to efficiently act as fluorescent probes for macrophage labeling. In addition, the high sensitivity of the N,P-MQDs toward Cu2+ ions made them a low cost, sensitive, environment-friendly, and label-free fluorescence platform for Cu2+ detection. The outstanding performance of Ti3C2 MXene based quantum dots has demonstrated their great potential to be used as promising fluorescent probes in the fields of biological imaging, optical sensing, photoelectric conversion, etc.

Multi-color carbon dots for white light-emitting diodes.

Heteroatom doped carbon dots (CDs) with color adjustable properties have attracted extensive attention. The doping of elements can effectively tune the surface chemical properties of CDs, thus resulting in its multi-functional applications such as in bio-imaging, photocatalysis, and photothermal conversion. The facile preparation of single metal-doped CDs with color-tunable properties has been rarely reported yet. Herein, we report a one-step solvothermal method to synthesize CDs with different fluorescent emission varying from red to purple to blue. The luminescence characteristic of CDs can be tuned by simply controlling the ratio of precursors, with the emission wavelength correspondingly adjusted from 610 nm to 390 nm. XPS investigation further demonstrated that the color variation is mainly due to the doping of zinc, which will increase the degree of surface oxidation in the as-prepared CDs. For blue emission CDs, the content of graphitic carbon gradually decreases with the rising of zinc chloride addition, while oxygen content remains around 20%, compared with red emission CDs of which the oxygen content is only 4.42%. We also demonstrated with theoretical simulations that the Zn dopant and the functional groups including -C[double bond, length as m-dash]O, -C-OH, -NH2, and pyrrolic N, play an important role in color change. Furthermore, the synthesized CDs have been successfully used into the fabrication of white LEDs. More than that, we produced a sensitive sensor from the prepared CDs for the effective detection of a variety of colorless transparent organic solvents utilizing the robust fluorescence properties of CDs, showing their great potential as fluorescent probes for chemical sensing.