1.
Org Biomol Chem
; 12(46): 9345-9, 2014 Dec 14.
Artigo
em Inglês
| MEDLINE
| ID: mdl-25338766
RESUMO
The first total synthesis of ganglioside DSG-A (1) is achieved via chemoselective glycosylation and a [1 + 1 + 2] synthetic strategy. We have also developed an efficient method that can be handled on large scale (50 g) for the synthesis of the phytosphingosine.