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1.
Heliyon ; 10(4): e26165, 2024 Feb 29.
Artigo em Inglês | MEDLINE | ID: mdl-38420471

RESUMO

Parabolic dish concentrators have demonstrated the highest thermal and optical efficiencies among the available concentrator options. This paper proposes a novel design approach for fabricating large parabolic dish concentrators by employing compliant petals optimized through Particle Swarm Optimization-Genetic Algorithm (PSO-GA). The design concept involves using cables to pull the outer corners of the petals towards the center, resulting in the creation of finely formed dish mirrors. These mirrors are constructed from thin, optimal-shaped metal petals with highly reflective surfaces. In addition, an analytical model is presented to optimize the bending stiffness of the petals by strategically arranging punched holes using PSO-GA. The proposed design concept is validated through the application of Finite Element Analysis and ray tracing software, specifically LightTools, as well as laboratory experiments. Based on the demonstration with a 1m-diameter parabolic dish, it was observed that a receiver surface with a radius of 3.5 cm could achieve an impressive sunlight collection efficiency of up to 98%. This innovative design approach offers several advantages, including simplified fabrication and transportation of flat mirror elements to field sites, which can potentially lead to cost reductions and highly efficient solar energy solutions.

2.
Opt Express ; 23(21): 27618-26, 2015 Oct 19.
Artigo em Inglês | MEDLINE | ID: mdl-26480422

RESUMO

We report on a novel technology for high-speed inter-satellites optical communication by bidirectional beam tracking. By establishing the relation between the compensation effect and the parameters of response time and overshoot situation, the stability can be well compensated simply by the control system. Thus the relation between compensation effect and maintain time can be predicted from ground tests, and the certain evaluation standard could be established to meet the requirements of system. The other critical factors, such as signal-to-noise ratio and pointing angle error, have also been considered to improve the stability. The general approach can provide us a powerful path to overcome the performance limitation of bidirectional beam tracking, which can be expected to be widely applied in Free Space optics communications in future.

3.
Anal Chem ; 87(10): 5263-9, 2015 May 19.
Artigo em Inglês | MEDLINE | ID: mdl-25860874

RESUMO

We report on self-assembled nanocube-based plasmene nanosheets as new surface-enhanced Raman scattering (SERS) substrates toward direct identification of a trace amount of drugs sitting on topologically complex real-world surfaces. The uniform nanocube arrays (superlattices) led to low spatial SERS signal variances (∼2%). Unlike conventional SERS substrates which are based on rigid nanostructured metals, our plasmene nanosheets are mechanically soft and optically semitransparent, enabling conformal attachment to real-world solid surfaces such as banknotes for direct SERS identification of drugs. Our plasmene nanosheets were able to detect benzocaine overdose down to a parts-per-billion (ppb) level with an excellent linear relationship (R(2) > 0.99) between characteristic peak intensity and concentration. On banknote surfaces, a detection limit of ∼0.9 × 10(-6) g/cm(2) benzocaine could be achieved. Furthermore, a few other drugs could also be identified, even in their binary mixtures with our plasmene nanosheets. Our experimental results clearly show that our plasmene sheets represent a new class of unique SERS substrates, potentially serving as a versatile platform for real-world forensic drug identification.


Assuntos
Anestésicos Locais/análise , Benzocaína/análise , Ouro/química , Nanoestruturas/química , Prata/química , Análise Espectral Raman/métodos , Acetaminofen/análise , Analgésicos não Narcóticos/análise , Anti-Inflamatórios não Esteroides/análise , Aspirina/análise , Ibuprofeno/análise , Limite de Detecção , Nanoestruturas/ultraestrutura , Análise Espectral Raman/instrumentação , Propriedades de Superfície
4.
Nanoscale ; 7(7): 2862-8, 2015 Feb 21.
Artigo em Inglês | MEDLINE | ID: mdl-25599516

RESUMO

We systematically investigated the size- and shape-dependent SERS activities of plasmonic core-shell nanoparticles towards detection of the pesticide thiram. Monodisperse Au@Ag nanocubes (NCs) and Au@Ag nanocuboids (NBs) were synthesized and their Ag shell thickness was precisely adjusted from ∼1 nm to ∼16 nm. All these nanoparticles were used as SERS substrates for thiram detection, and the Raman intensities with three different lasers (514 nm, 633 nm and 782 nm) were recorded and compared. Our results clearly show that: (1) the excitation wavelength discriminated particle shapes regardless of particle sizes, and the maximized Raman enhancement was observed when the excitation wavelength approaches the SERS peak (provided there is significant local electric field confinement on the plasmonic nanostructures at that wavelength); (2) at the optimized laser wavelength, the maximum Raman enhancement was achieved at a certain threshold of particle size (or silver coating thickness). By exciting particles at their optimized sizes with the corresponding optimized laser wavelengths, we achieved a detection limit of roughly around 100 pM and 80 pM for NCs and NBs, respectively.


Assuntos
Nanopartículas Metálicas/química , Nanotecnologia/métodos , Praguicidas/química , Prata/química , Análise Espectral Raman , Tiram/química , Ouro/química , Lasers , Limite de Detecção , Microscopia Eletrônica de Transmissão , Modelos Teóricos , Tamanho da Partícula , Espectrofotometria Ultravioleta , Ressonância de Plasmônio de Superfície
5.
ACS Nano ; 8(11): 11086-93, 2014 Nov 25.
Artigo em Inglês | MEDLINE | ID: mdl-25265019

RESUMO

We introduce Plasmene- in analogy to graphene-as free-standing, one-particle-thick, superlattice sheets of nanoparticles ("meta-atoms") from the "plasmonic periodic table", which has implications in many important research disciplines. Here, we report on a general bottom-up self-assembly approach to fabricate giant plasmene nanosheets (i.e., plasmene with nanoscale thickness but with macroscopic lateral dimensions) as thin as ∼40 nm and as wide as ∼3 mm, corresponding to an aspect ratio of ∼75,000. In conjunction with top-down lithography, such robust giant nanosheets could be milled into one-dimensional nanoribbons and folded into three-dimensional origami. Both experimental and theoretical studies reveal that our giant plasmene nanosheets are analogues of graphene from the plasmonic nanoparticle family, simultaneously possessing unique structural features and plasmon propagation functionalities.

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