Geoenvironmental properties of a Cr(VI)-contaminated soil treated by alkali-activated GGBS under freeze-thaw cycles: Insights into Cr species transformation and microscopic mechanism.

Stabilization/solidification is the most frequently used method for treating soils contaminated by heavy metals; however, degradation of the treatment will occur under freeze-thaw (F-T) cycles. In this paper, a low-carbon emission by-product, ground granulated blast furnace slag (GGBS), was adopted as a binder to treat Cr(VI)-contaminated soil after alkali excitation. Built on the usage scenarios of subgrade materials, the impact of F-T cycles and initial water content on the geoenvironmental properties of the treated soils, including leaching toxicity, unconfined compressive strength (UCS), pH, Eh, and permeability, were discussed. To investigate the mechanisms of the changing properties, this study analyzed the chemical morphology of Cr, the micromorphology of the reaction products, and the pore characteristics. The results demonstrated that negative impact of F-T cycles on treatment effectiveness was low at the optimal water content. After 28 F-T cycles, the Cr(VI) component increased by 6.4 %, and the leached Cr concentration showed a significant increase, especially for specimens with low water content. A new solid phase with mixed valence Mn(III/IV), mainly composed of birnessite and manganite, was observed via microscopic analysis. During the first 3 F-T cycles, the content of hydration gel increased by 0.18 %, and the cumulative pore volume decreased such that the UCS increased by an average of 1.2 MPa. This study demonstrated that a few F-T cycles would result in a secondary alkali-activated GGBS reaction, enhancing the treatment effect. However, additional F-T cycles would create an oxidizing environment under which the initially precipitated Cr(III) would react with manganese oxide, resulting in more Cr(VI) released. The degree of reoxidation was closely related to the initial water content of the solidified soil.

Influence of humic acid and bovine serum albumin on colloid-associated heavy metal transport in saturated porous media.

Colloid-facilitated contaminant transport in porous media has been widely observed in laboratory and field studies. In this study, the influence of two dissolved organic matters (DOMs), humic acid (HA) and bovine serum albumin (BSA), on the colloid-associated heavy metal transport, was investigated. Soil colloids with particle sizes <2 µm were prepared from bentonite. Glass bead was used as porous media for the column tests. The influence of DOM on the adsorption of Pb2+ and Cu2+ onto colloids was tested. Colloid mobility and colloid-metal co-transport in the presence/absence of DOMs were investigated by breakthrough tests. The test results showed that DOMs facilitated colloid mobility. The measured ζ-potentials showed that DOMs enhanced the electrostatic repulsion between colloids and glass beads and reduced colloid deposition. These findings were further confirmed by calculating the interaction energy using the DLVO theory. Batch tests showed the strong adsorption of Pb2+ and Cu2+ on the colloid, and the adsorption was enhanced by DOMs. The colloid-metal co-transport tests showed that colloids can significantly facilitate the transport of Pb2+ and Cu2+ and that the facilitation was further enhanced by DOMs. By heavy metals, the colloid mobility was retarded, mainly due to the increased deposition. The transport of Cu2+ facilitated by DOM was more obvious than that of Pb2+. Compared to BSA, the effect of HA on enhancing colloid mobility, increasing colloid adsorption to heavy metals, and hence on the facilitation of colloid-associated heavy metals transport was more prominent.

Reduction, stabilization, and solidification of Cr(VI) in contaminated soils with a sustainable by-product-based binder.

This study evaluated the use of a sustainable GFD binder for the stabilization/solidification (S/S) of chromium VI (Cr(VI))-contaminated soil. The GFD binder was composed of ground granulated blast furnace slag (GGBFS), fly ash and desulfurization ash, named after the initials of the three materials. The effects of curing time and binder dosage on soil unconfined compressive strength (UCS), Cr leachability, soil pH, and reduction ratio of Cr (VI) were tested. The immobilization mechanisms of Cr(VI) in contaminated soil were further explored using X-ray diffraction (XRD), scanning electron microscopy (SEM), and sequential extraction procedure (SEP). The results showed that the UCS and pH of the soil increased substantially after the GFD binder was added. After 28 days of curing with a 20% binder dosage, the leached total Cr concentration decreased from 34.4 mg/L in the contaminated soil to 1.44 mg/L in the treated soil, and the leached Cr(VI) concentration decreased from 28.0 mg/L to 0.45 mg/L. A Cr(VI) reduction ratio of 96.2% was achieved, indicating the strong reducibility of GGBFS. XRD revealed that the main hydration products of the GFD binder were hydrated calcium silicate (C-S-H) and ettringite. SEM results showed that the formation of hydration products and Cr-bearing precipitates filled the soil pores, resulting in a dense soil structure. The SEP results demonstrated that the levels of the unstable fraction F1 decreased considerably, and that the levels of the stable fractions F3 and F5 increased after treatment. Encapsulation by C-S-H, reduction by sulfides, adsorption of C-S-H, and precipitation of Cr-bearing hydroxides were the main mechanisms involved in Cr immobilization using the GFD binder.