1.
Angew Chem Int Ed Engl
; 57(42): 13780-13783, 2018 Oct 15.
Artigo
em Inglês
| MEDLINE
| ID: mdl-30160076
RESUMO
A new mesoporous metal-organic framework (MOF; DUT-60) was conceptually designed in silico using Zn4 O6+ nodes, ditopic and tritopic linkers to explore the stability limits of framework architectures with ultrahigh porosity. The robust ith-d topology of DUT-60 provides an average bulk and shear modulus (4.97â GPa and 0.50â GPa, respectively) for this ultra-porous framework, a key prerequisite to suppress pore collapse during desolvation. Subsequently, a cluster precursor approach, resulting in minimal side product formation in the solvothermal synthesis, was used to produce DUT-60, a new crystalline framework with the highest recorded accessible pore volume (5.02â cm3 g-1 ) surpassing all known crystalline framework materials.