Soft ionization mechanisms in flexible µ-tube plasma-from FµTP to closed µ-tube plasma.

In order to find an explanation for the mechanism in a plasma operated with an alternating voltage, or rather a square wave voltage, such a plasma was investigated. It was found that Penning ionization, charge transfer, and photoionization played a minor or even no role in the soft ionization mechanism of a FµTP. If the collision of plasma gases with air does not contribute to soft ionization, it should also be possible to use a separated plasma for soft ionization. Preliminary investigations show that it is possible to ignite a diagnosis gas with a plasma gas even when there is a barrier such as glass between those gases. A temporally and locally limited potential must be produced at the outer surface to achieve this. This potential should be sufficient to ionize the environment softly and to be able to use this so-called closed µ-tube plasma as a new ionization source.

Setting the Separation Factor α for Ketone Monomers and Dimers by the Use of Different Drift Gases.

This study investigates the influence of different drift gases on ion mobility in ion mobility spectrometry (IMS) using ketones as model substances within a custom-built drift tube spectrometer. Different binary mixtures of nitrogen, helium, and argon were used as drift gases to investigate the influence of mobility on the monomers and dimers of the different ketones. Experimental results reveal shifts in ion drift times and separation factors (α) with varying gas compositions, in accordance with Blanc's Law. Furthermore, the study underscores the device-independent nature of α and the device-dependent resolution, emphasizing the importance of comparative analyses. Employing 2-hexanone and 2-decanone in the same sample but with different drift gases is used to show the impact of different drift gases. By changing the drift gas composition, total alignment of drift times and therefore no possible resolution or baseline resolution could be achieved. Through different experiments and analyses, this research provides insights into the interactions between gas composition and ion mobility, offering implications for diverse analytical applications from environmental monitoring to chemical detection.

Non-Invasive Manipulation of Two-Phase Liquid-Liquid Slug Flow Parameters Using Magnetofluidics.

Liquid-liquid slug flow in a microcapillary, with its improved heat and mass transfer properties and narrow residence time, plays a vital role in process intensification. Knowledge of the flow properties in microchannels along variables' controllability (e.g., phase ratio, slug length along with classical variables, such as pressure, temperature, and flow velocity) during operation is crucial. This work aids in this by using magnetofluidics to manipulate these parameters. A ferrofluid with reproducible properties is produced and, together with another phase, stable slug flow is generated. Micro-gear pumps and syringe pumps, with their traditional mechanical components, result in parts degrading over time due to fatigue caused by pressure differentials and corrosive chemicals. The microflow is also disturbed by the invasive nature of these pumps. A considerably energy-efficient, non-invasive alternative, with reduced mechanical interfacing is suggested in this work. It uses magnetic gradients to manipulate two-phase flow, one of which is a magnetically active phase. Conveying concepts using permanent magnets in the immediate vicinity of the flow are investigated. To operate this pump continuously and to be able to regulate the phase ratio, an electromagnetic non-invasive valve is developed. Phase separation is also carried out with an existing decanter design, modified using electromagnetism to work without a selective membrane, usually necessary for phase separation at this scale. This pump is then compared with similar pumps developed in the past.