PbS Quantum Dots-Decorated BiVO4 Photoanodes for Highly Efficient Photoelectrochemical Hydrogen Production.

While metal oxides such as TiO2, Fe2O3, WO3, and BiVO4 have been previously studied for their potential as photoanodes in photoelectrochemical (PEC) hydrogen production, their relatively wide band-gap limits their photocurrent, making them unsuitable for the efficient utilization of incident visible light. To overcome this limitation, we propose a new approach for highly efficient PEC hydrogen production based on a novel photoanode composed of BiVO4/PbS quantum dots (QDs). Crystallized monoclinic BiVO4 films were prepared via a typical electrodeposition process, followed by the deposition of PbS QDs using a successive ionic layer adsorption and reaction (SILAR) method to form a p-n heterojunction. This is the first time that narrow band-gap QDs were applied to sensitize a BiVO4 photoelectrode. The PbS QDs were uniformly coated on the surface of nanoporous BiVO4, and their optical band-gap was reduced by increasing the number of SILAR cycles. However, this did not affect the crystal structure and optical properties of the BiVO4. By decorating the surface of BiVO4 with PbS QDs, the photocurrent was increased from 2.92 to 4.88 mA/cm2 (at 1.23 VRHE) for PEC hydrogen production, resulting from the enhanced light-harvesting capability arising from the narrow band-gap of the PbS QDs. Moreover, the introduction of a ZnS overlayer on the BiVO4/PbS QDs further improved the photocurrent to 5.19 mA/cm2, attributed to the reduction in interfacial charge recombination.

Influence of Antagonistic Tensions on Distributed Friction Forces of Multisegment Tendon-Driven Continuum Manipulators With Irregular Geometry.

In this paper, we thoroughly analyze the effect of single-tendon and antagonistic tendons actuation on tension loss of multi-segment tendon-driven continuum manipulators (TD-CMs) with irregular geometry. To this end, we propose a generic analytical modeling approach and iterative algorithm that can solve the unknown correlation between distributed friction force, tendons' tension transmission loss, and planar deformation behavior of TD-CMs during tendons' pulling and releasing phases. The proposed generic model solely relies on known input tendons' tensions and does not require a priori knowledge of the manipulator's shape and/or other experimental conditions. To investigate the influence of actuation type on tension loss and deformation behavior of TD-CMs, we fabricated two different TD-CMs and performed various simulation and experimental studies with single-tendon and antagonistic tensions actuations. The obtained results indicate the importance of considering the effect of distributed friction force and actuation type on tension(s) loss of multi-segment TD-CMs. Moreover, it clearly demonstrates the efficacy and accuracy of the proposed model in providing insights and understanding of tension transmission process in various types of actuations in multi-segment TD-CMs with irregular geometry.