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Hydrogen and helium saturate the 1D pore systems of the high-silica (Si/Al>30) zeolites Theta-One (TON), and Mobile-Twelve (MTW) at high pressure based on x-ray diffraction, Raman spectroscopy and Monte Carlo simulations. In TON, a strong 22 % volume increase occurs above 5â GPa with a transition from the collapsed P21 to a symmetrical, swelled Cmc21 form linked to an increase in H2 content from 12 H2/unit cell in the pores to 35 H2/unit cell in the pores and in the framework of the material. No transition and continuous collapse of TON is observed in helium indicating that the mechanism of H2 insertion is distinct from other fluids. The insertion of hydrogen in the larger pores of MTW results in a strong 11 % volume increase at 4.3â GPa with partial symmetrization followed by a second volume increase of 4.5 % at 7.5â GPa, corresponding to increases in hydrogen content from 43 to 67 and then to 93 H2/unit cell. Flexible 1D siliceous zeolites have a very high H2 capacity (1.5 and 1.7 H2/SiO2 unit for TON and MTW, respectively) due to H2 insertion in the pores and the framework, in contrast to other atoms and molecules, thereby providing a mechanism for strong swelling.
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Barium-cobaltate-based perovskite (BaCoO3-δ) and barium-cobaltate-based nanocomposites have been intensively studied in energy storage and conversion devices mainly due to flexible oxygen stoichiometry and tunable nonprecious transition metal oxidation states. Although a rich and complex family of structural polymorphs has already been reported for these perovskites in the literature, the potential structural evolution that may occur during the oxygen reduction reaction and the oxygen evolution reaction has not been investigated so far. In this study, we synthesized and characterized the lowest Co-oxidation state possible in the compound, BaCoO2, which exhibits a quartz-derived, trigonal structure with a helicoidally corner-sharing, CoO4-tetrahedral-framework as already proposed by Spitsbergen et al. Oxygen can reversibly be inserted in such a crystal structure to form BaCoO3-δ, i.e., with 0 ≤ δ ≤ 1, based on the results of an in situ coupled thermogravimetric - neutron diffraction study and which presents therefore giant oxygen capacity storage due to the extreme tunability of the electronic configuration of the cobalt cations which defines the fundamental origins of the materials performance. The reversible conversion of BaCoO2 to BaCoO3-δ associated with a similar electronic conductivity above 900 K permits to clarify the high potential of BaCoO3-δ-based energy storage and conversion devices.
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Pressure induced amorphization provides a distinct route to prepare novel amorphous materials. Single crystals of the porous aluminophosphate AlPO4-17 directly transform to an amorphous state beginning at 0.6 GPa, without fragmentation into polycrystalline material. Apart from a reduction in dimensions, the amorphous material retains the form of the initial single crystal. Remnant crystalline domains in the amorphous material also preserve the initial orientation of the single crystal. X-ray diffraction indicates the compression of the structure around the empty pores in the xy plane and such an amorphization mechanism is consistent with a direct structural relationship between the single crystal and amorphous forms. The collapse of the initial pore volume is almost complete at 2.5 GPa. A memory effect is observed in the amorphous form, which strongly expands on decompression. The present process opens the way for the synthesis of topologically ordered amorphous materials approaching "perfect glasses" with improved mechanical properties.
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The topology of amorphous materials can be affected by mechanical forces during compression or milling, which can induce material densification. Here, we show that densified amorphous silica (SiO2) fabricated by cold compression of siliceous zeolite (SZ) is permanently densified, unlike densified glassy SiO2 (GS) fabricated by cold compression although the X-ray diffraction data and density of the former are identical to those of the latter. Moreover, the topology of the densified amorphous SiO2 fabricated from SZ retains that of crystalline SZ, whereas the densified GS relaxes to pristine GS after thermal annealing. These results indicate that it is possible to design new functional amorphous materials by tuning the topology of the initial zeolitic crystalline phases.
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The porous aluminophosphate AlPO4-17 with a hexagonal erionite structure, exhibiting very strong negative thermal expansion, anomalous compressibility, and pressure-induced amorphization, was studied at high pressure by single-crystal and powder X-ray diffraction in the penetrating pressure transmitting media N2, O2, and Ar. Under pressure, these guest species were confirmed to enter the pores of AlPO4-17, thus completely modifying its behavior. Pressure-induced collapse in the xy plane of AlPO4-17 no longer occurred, and this plane exhibited close to zero area compressibility. Pressure-induced amorphization was also suppressed as the elastic instability in the xy plane was removed. Crystal structure refinements at a pressure of 5.5 GPa indicate that up to 28 guest molecules are inserted per unit cell and that this insertion is responsible for the reduced compressibility observed at high pressure. A phase transition to a new hexagonal structure with cell doubling along the a direction was observed above 4.4 GPa in fluid O2.
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Low-dimensional boron nitride (BN) chains were prepared in the one-dimensional pores of the siliceous zeolites theta-one (TON) and Mobil-twelve (MTW) by the infiltration, followed by the dehydrocoupling and pyrolysis of ammonia borane under high-pressure, high-temperature conditions. High-pressure X-ray diffraction in a diamond anvil cell and in a large-volume device was used to follow in situ these different steps in order to determine the optimal conditions for this process. Based on these results, millimeter-sized samples of BN/TON and BN/MTW were synthesized. Characteristic B-N stretching vibrations of low-dimensional BN were observed by infrared and Raman spectroscopies. The crystal structures were determined using a combination of X-ray diffraction and density functional theory with one and two one-dimensional zig-zag (BN)x chains per pore in BN/TON and BN/MTW, respectively. These 1-D BN chains potentially have interesting photoluminescence properties in the far ultraviolet region of the electromagnetic spectrum.
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The very strong negative thermal expansion in the porous aluminophosphate AlPO4-17 with a hexagonal erionite structure was tuned by the insertion of oxygen molecules at high pressure. The structure of the oxygen-filled material was determined in situ at high pressure by synchrotron, single-crystal X-ray diffraction. The thermal expansion of this material was measured precisely at 0.38 GPa by synchrotron X-ray powder diffraction. Whereas the overall volume thermal expansion only exhibits a small change with respect to empty AlPO4-17 at ambient pressure, the expansion along the a direction decreases almost to zero and the expansion along c increases by a factor of 7. Such highly anisotropic thermal expansion properties are of great interest for mechanical and optical applications as in two directions the dimensions of the material are extremely stable, whereas a very strong linear negative thermal expansion of -2.2 × 10-5 K-1 is observed in the perpendicular direction. Guest insertion is thus a very powerful tool for tuning the thermal expansion properties of porous materials.
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Until recently, saturated carbon nanothreads were the missing tile in the world of low-dimension carbon nanomaterials. These one-dimensional fully saturated polymers possess superior mechanical properties by combining high tensile strength with flexibility and resilience. They can be obtained by compressing aromatic and heteroaromatic crystals above 15 GPa exploiting the anisotropic stress that can be achieved by the diamond anvil cell technique. Recently, double-core nanothreads were synthesized by compressing azobenzene crystals, achieving the remarkable result of preserving the azo group as a linker of the resulting double thread. Herein, we demonstrate the generality of these findings through the synthesis of double carbon nanothreads from trans stilbene and azobenzene-stilbene mixed crystals. Employment of Fourier transform infrared spectroscopy and synchrotron X-ray diffraction enabled a comprehensive characterization of the reactivity identifying threshold conditions, kinetics and structure-reaction relationship. In particular, the reaction is anticipated by a phase transition characterized by a sudden increase of the monoclinic angle and a collapse along the b axis direction. Large bidimensional crystalline areas extending several tens of nanometers are evidenced by transmission electron microscopy also confirming the monoclinic unit cell derived from X-ray diffraction data in which threads possessing the polymer 1 structure, as suggested by density functional theory calculations, are packed. The most exciting result of this study is the demonstration of viable synthesis of double nanothreads where the number and the nature of chromophoric groups linking the threads can be tuned by preparing starting crystals of desired composition, thanks to the isomorphism typical of the pseudo-stilbene molecules. This is extremely important in tailoring nanothreads with tunable optical properties and an adjustable band gap, also exploiting the possibility of introducing substituents in the phenyl groups.
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Recently, filling zeolites with gaseous hydrocarbons at high pressures in diamond anvil cells has been carried out to synthesize novel polymer-guest/zeolite-host nanocomposites with potential, intriguing applications, although the small amount of materials, 10-7 cm3, severely limited true technological exploitation. Here, liquid phenylacetylene, a much more practical reactant, was polymerized in the 12 Å channels of the aluminophosphate Virginia Polytechnic Institute-Five (VFI) at about 0.8 GPa and 140 °C, with large volumes in the order of 0.6 cm3. The resulting polymer/VFI composite was investigated by synchrotron X-ray diffraction and optical and 1H, 13C, and 27Al nuclear magnetic resonance spectroscopy. The materials, consisting of disordered π-conjugated polyphenylacetylene chains in the pores of VFI, were deposited on quartz crystal microbalances and tested as gas sensors. We obtained promising sensing performances to water and butanol vapors, attributed to the finely tuned nanostructure of the composites. High-pressure synthesis is used here to obtain an otherwise unattainable true technological material.
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High-pressure X-ray diffraction and Raman spectroscopy in a diamond anvil cell were used to study the insertion of the chemical hydrogen storage material, ammonia borane, in the one-dimensional pores of the zeolite theta-1 TON. Heating of this material up to 300 °C under pressures up to 5 GPa resulted in the release of a significant amount of hydrogen due to the conversion of ammonia borane confined in the channels of TON and outside the zeolite to polyaminoborane and then polyiminoborane chains. The filling of TON with hydrogen resulted in a much greater increase in unit cell volume than that corresponding to thermal expansion of normal compact inorganic solids. This process at high temperature is accompanied by a phase transition from the collapsed high-pressure Pbn21 form to the more symmetric Cmc21 phase with expanded pores. This material has a high capacity for hydrogen adsorption under high-temperature, high-pressure conditions.
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Our combined high-pressure synchrotron X-ray diffraction and Monte Carlo modeling studies show super-filling of the zeolite, and computational results suggest an occupancy by a maximum of nearly two inserted H2 molecules per framework unit, which is about twice that observed in gas hydrates. Super-filling prevents amorphization of the host material up to at least 60 GPa, which is a record pressure for zeolites and also for any group IV element being in full 4-fold coordination, except for carbon. We find that the inserted H2 forms an exotic topologically constrained glassy-like form, otherwise unattainable in pure hydrogen. Raman spectroscopy on confined H2 shows that the microporosity of the zeolite is retained over the entire investigated pressure range (up to 80 GPa) and that intermolecular interactions share common aspects with bulk hydrogen, while they are also affected by the zeolite framework.
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The negative thermal expansion material potassium cadmium dicyanoargentate, KCd[Ag(CN)2]3, is studied at high pressure using a combination of X-ray single-crystal diffraction, X-ray powder diffraction, infrared and Raman spectroscopy, and density functional theory calculations. In common with the isostructural manganese analogue, KMn[Ag(CN)2]3, this material is shown to exhibit very strong negative linear compressibility (NLC) in the crystallographic c direction due to structure hinging. We find increased structural flexibility results in enhanced NLC and NTE properties, but this also leads to two pressure-induced phase transitions-to very large unit cells involving octahedral tilting and shearing of the structure-below 2 GPa. The presence of potassium cations has an important effect on the mechanical and thermodynamic properties of this family, while the chemical versatility demonstrated here is of considerable interest to tune unusual mechanical properties for application.
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The incorporation of guest species in zeolites has been found to strongly modify their mechanical behavior and their stability with respect to amorphization at high pressure (HP). Here we report the strong effect of H2O on the pressure-induced amorphization (PIA) in hydrated AlPO4-17. The material was investigated in-situ at HP by synchrotron X-ray powder diffraction in diamond anvil cells by using non- and penetrating pressure transmitting media (PTM), respectively, silicone oil and H2O. Surprisingly, in non-penetrating PTM, its structural response to pressure was similar to its anhydrous phase at lower pressures up to ~1.4 GPa, when the amorphization was observed to start. Compression of the structure of AlPO4-17 is reduced by an order of magnitude when the material is compressed in H2O, in which amorphization begins in a similar pressure range as in non-penetrating PTM. The complete and irreversible amorphization was observed at ~9.0 and ~18.7 GPa, respectively, in non- and penetrating PTM. The present results show that the insertion of guest species can be used to strongly modify the stability of microporous material with respect to PIA, by up to an order of magnitude.
Assuntos
Alumínio/química , Fosfatos/química , Pressão , Água/química , Transição de Fase , Difração de Raios XRESUMO
SnO_{2} powders and single crystal have been studied under high pressure using Raman spectroscopy and ab initio simulations. The pressure-induced changes are shown to drastically depend on the form of the samples. The single crystal exhibits phase transitions as reported in the literature, whereas powder samples show a disordering of the oxygen sublattice in the first steps of compression. This behavior is proposed to be related to the defect density, an interpretation supported by ab initio simulations. The link between the defect density and an amorphouslike Raman signal is discussed in terms of the invasive percolation of the anionic sublattice. The resistance of the cationic sublattice to the disorder propagation is discussed in terms of cation close packing. This result on SnO_{2} may be extended to other systems and questions a "traditional" crystallographic description based on polyhedra packing, as a decoupling between both sublattices is observed.
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Molecular nitrogen is a benchmark system for condensed matter and, in particular, for looking at universal properties of strongly confined dense systems. We conducted Raman and X-ray diffraction measurements on a dense and disordered form of molecular nitrogen subnanoconfined in a noncatalytic pure SiO2 zeolite under pressure, up to 50 GPa. In this form, N2-N2 interactions and, consequently, distances are found to be very close to those of bulk N2 and intramolecular interactions progressively weaken upon increasing pressure. Surprisingly, the filled zeolite is still crystalline at 50 GPa with silicon in tetrahedral coordination by oxygen, which is a record pressure for this type of coordination among all the known forms of silica. We have thus found a rationale for the polymerization of a number molecules occurring in the microchannels of noncatalytic zeolites under pressure, where the pressure threshold is found to be very similar to that observed in bulk samples.
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A series of thermally stable Hofmann-type clathrate structures with the general formula M(pz)[M'(CN)4], where M and M' are bivalent metal ions M(II) = Ni(II), Co(II), M(II)' = Ni(II), Pd(II), Pt(II), and pz is the pyrazine bidentate ligand, was synthesized and investigated for the efficient entrapment of iodine (I2) in solution and in the gas phase. Iodine-containing clathrates thus prepared were analysed to determine the saturation capacity, thermal stability, guest-induced structural changes of the clathrate's lattice and the nature of the confined iodine according to the chemical composition of the host structure. An efficient confinement of about 1 I2 per unit cell is observed for the series of clathrates with the Ni(II) and Pd(II) ions in the square planar position whatever the bivalent metal ion in the octahedral position. Specific responses in the lattice adjustment are detected for Co(II) in the octahedral and Pd(II) in the square planar positions.
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The insertion of H2O in AlPO4-54·xH2O at high pressure was investigated by single-crystal X-ray diffraction and Monte Carlo molecular simulation. H2O molecules are concentrated, in particular, near the pore walls. Upon insertion, the additional water is highly disordered. Insertion of H2O (superhydration) is found to impede pore collapse in the material, thereby strongly modifying its mechanical behavior. However, instead of stabilizing the structure with respect to amorphization, the results provide evidence for the early stages of chemical bond formation between H2O molecules and tetrahedrally coordinated aluminum, which is at the origin of the amorphization/reaction process.
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Multifunctional molecular ferroelectrics are exciting materials synthesized using molecular chemistry concepts, which may combine a spontaneous electrical polarization, switched upon applying an electric field, with another physical property. A high-temperature ferroelectric material is presented that is based on a chiral Zn(2+) /Dy(3+) complex exhibiting Dy(3+) luminescence, optical activity, and magnetism. We investigate the correlations between the electric polarization and the crystal structure as well as between the low-temperature magnetic slow relaxation and the optical properties.