The coupling coordination and spatiotemporal evolution of industrial water-energy-CO2 in the Yellow River Basin.

The Yellow River Basin (YRB) is an important energy, chemical, raw material, and basic industrial base in China. With economic growth, water and energy consumption in industrial industries increasing dramatically, huge pressure for CO2 emission reduction has generated. This paper constructed an industrial water-energy-CO2 (WEC) evaluation index system, analyzed the comprehensive evaluation level, coupling status and coupling coordination status, by using the comprehensive evaluation method, coupling degree model and coupling coordination degree model and used the spatial autocorrelation analysis to study the spatiotemporal evolution from 1999 to 2019 in the YRB. The results demonstrated that the integrated development level of the basin's industrial WEC system and subsystems had been improving. The basin was at a high coupling and the level of coupling had been increasing as a whole, and the industrial energy-CO2 coupling degree was bigger than the industrial water-energy and industrial water-CO2 coupling degrees in the YRB. The coupling coordination status had transitioned from forced coordination to good coordination. Spatially, the coupling coordination didn't appear a significant correlation and showed a random distribution. Accordingly, the suggestions were made to improve the level of industrial development in the basin, strengthen integrated resource management, and enhance intra-basin cooperation.

Water-Adaptive Microcapsules with a Brittle-Ductile-Brittle Transition Based on an O/W/O Emulsion for the Self-Healing of Cementitious Materials.

Cementitious materials inevitably develop cracks, posing a serious threat to the long-term security of infrastructure, especially in the complex underground environment of cementing engineering. Microcapsules are facing the problem of encapsulated structure damage during the mixing and breaking difficultly during self-healing when applied in cementitious materials, resulting in the decline of self-healing efficiency. Herein, the calcium alginate water-adaptive microcapsules (CaAlg-NS/E-51) were prepared via an O/W/O emulsion, and the water adaptability of the shell was applied to achieve a rapid brittle-ductile transition by absorbing water. The water adaptability of the microcapsule is conducive to resisting shear stress during stirring due to the decreased elastic modulus and the increased ductility of the shell when it absorbs water. Meanwhile, the water-bearing shell loses water and becomes brittle during dry curing, making it prone to fracture when self-healing. In the self-healing measurement, the self-healing efficiency of cementitious specimens with microcapsules absorbing water for 10 min improved by 234.9 and 60.0% at 1 and 7 days, respectively, compared with those containing dry microcapsules, owing to the water adaptability of the shell.

Ecological security evaluation and early warning in the water source area of the Middle Route of South-to-North Water Diversion Project.

Ecological security has important influence on regional sustainable development. The ecological security of Nanyang, the water source area of the Middle Route of South-to-North Water Diversion Project, was threatened because of surface water pollution. The existing studies had not been able to comprehensively assess the ecological security and future trend of water source area. In order to promote the high-quality development of the follow-up projects of the South-to-North Water Diversion project, it is very important to probe into the current situation and predict the future trend of ecological security in the water source area. Therefore, this paper constructed an ecological security evaluation index system based on the Driving force, Pressure, State, Impact and Response (DPSIR) model, used the combination of Analytic Hierarchy Process and- entropy weighting method to evaluate the ecological security of each district and county in Nanyang from 2000 to 2020, and used the auto regressive integrated moving average (ARIMA) model to predict the ecological security of the water source area from 2021 to 2030. The results demonstrated that: (1) The ecological security of Nanyang had changed from a moderate warning to a general safety, and the ecological security index had improved. The ecological security level of Nanyang would improve continuously from 2021 to 2030. (2) The northwest area and the central area of Nanyang had better ecological security states, while the southeast area wasn't so. Based on the results, the countermeasures for improving ecological security were proposed.