Passenger comfort and ozone pollution exposure in an air-conditioned bus microenvironment.

Ground-level ozone is the primary source of air pollution in China, particularly during the warmer months. In this study, we investigated the exposure status of ozone pollution and the temperature distribution in an air-conditioned bus in Jinan during the evening peak period based on field measurements obtained with a handheld portable particle counter and indigo disulfonate spectrophotometry. Statistical analysis showed that the passengers experienced poor air quality within the confines of the bus due to the poor air quality outside. Furthermore, the level of passenger comfort was dissatisfactory because of the high temperature, thereby highlighting the urgent need to improve the current situation. Numerical simulations were conducted using FLUENT software to explore the impacts of the air supply angle, the opening and closing of the bus door, and the chemical reaction between ozone and its precursors on the diffusion and distribution of ozone, the temperature, and the airflow field. The results indicated that high concentrations of ozone were present in the middle and front regions of the bus. Pollution can be reduced by keeping the bus door open for no longer than 20 s when waiting for other passengers, and the best optimization effect in relation to the temperature and passenger comfort was determined as an air supply angle of 30°. In addition, the average individual daily intake of ozone was combined with other relevant parameters to assess the exposure level. It is recommended that the elderly and children should avoid peak time travel to reduce their exposure to ozone (inhalation dose values > 60 µg/m3 and > 56 µg/m3 according to simulations, respectively). These findings are expected to effectively improve the air quality and passenger comfort levels in busses, thereby protecting the health of passengers and reducing carbon usage.

Synergistic effect of N- and F-codoping on the structure and photocatalytic performance of TiO2.

Three types of TiO2 nanostructures were synthesized via a facile hydrolysis method at 195°C. Effects of the preparation method and doping with N and F on the crystal structure and photocatalytic performance of TiO2 were investigated. The nanomaterials were characterized by X-ray diffraction, transmission electron microscopy, X-ray photoelectron spectroscopy, Brunauer-Emmett-Teller porosimetry, ultraviolet-visible diffuse reflectance spectroscopy and fluorescent emission spectra. Their photo-catalytic activity was examined by the photodegradation of methylene blue in aqueous solution under both ultra-violet and visible light irradiation. The results show that nitrogen and fluorine co-doped anatase TiO2 had the characteristics of a smaller crystalline size, broader light absorption spectrum and lower charge recombination than pure TiO2. Most importantly, more efficient photocatalytic activity under both ultra-violet and visible light was observed. The obtained N-F-TiO2 nanomaterial shows considerable potential for water treatment under sunlight irradiation.