Anisotropic gypsum scaling of corrugated polyvinylidene fluoride hydrophobic membrane in direct contact membrane distillation.

Membrane distillation (MD) technology has gained a lot of attention for treatment of geothermal brine, high salinity waste streams. However, mineral scaling remains a major challenge when treating complex high-salt brines. The development of surface-patterned superhydrophobic membranes is one of the core strategies to solve this problem. We prepared flat sheet membranes (F-PVDF) and hydrophobic membranes with micron-scale corrugated pattern (C-PVDF) using a phase separation method. Their scaling behavior was systematically evaluated using calcium sulfate solutions and the impact of the feed flow was innovatively investigated. Although C-PVDF shows higher contact angle and lower sliding angle than F-PVDF, the scaling resistance of C-PVDF in the perpendicular flow direction has worst scaling resistance. Although the nucleation barrier of the corrugated membrane is the same at both parallel and perpendicular flow directions based on the traditional thermodynamic nucleation theory, experimental observations show that the C-PVDF has the best scaling resistance in the parallel flow direction. A 3D computational fluid dynamics (CFD) model was used and the hydrodynamic state of the pattern membranes was assessed as a determinant of the scaling resistance. The corrugated membrane with parallel flow mode (flow direction in parallel to the corrugation ridge) induces higher fluid velocity within the channel, which mitigated the deposition of crystals. While in the perpendicular flow mode (flow direction in perpendicular to the corrugation ridge), the solutions confined in the corrugated grooves due to vortex shielding, which aggravates the scaling. These results shed light on the mechanism of scaling resistance of corrugated membranes from a hydrodynamic perspective and reveal the mechanism of anisotropy exhibited by corrugated membranes in MD.

Microstructure Reconstruction and Multiphysics Dynamic Distribution Simulation of the Catalyst Layer in PEMFC.

Due to the complexity of both material composition and the structure of the catalyst layer (CL) used in the proton-exchange membrane fuel cell (PEMFC), conjugated heat and mass transfer as well as electrochemical processes simultaneously occur through the CL. In this study, a microstructure model of CL was first reconstructed using images acquired by Nano-computed tomography (Nano-CT) of a real sample of CL. Then, the multiphysics dynamic distribution (MPDD) simulation, which is inherently a multiscale approach made of a combination of pore-scale and homogeneous models, was conducted on the reconstructed microstructure model to compute the corresponded heat and mass transport, electrochemical reactions, and water phase-change processes. Considering a computational domain with the size of 4 um and cube shape, this model consisting of mass and heat transport as well as electrochemical reactions reached a stable solution within 3 s as the convergence time. In the presence of sufficient oxygen, proton conduction was identified as the dominant factor determining the strength of the electrochemical reaction. Additionally, it was concluded that current density, temperature, and the distribution of water all exhibit similar distribution trends, which decrease from the interface between CL and the proton-exchange membrane to the interface between CL and the gas-diffusion layer. The present study not only provides an in-depth understanding of the mass and heat transport and electrochemical reaction in the CL microstructure, but it also guides the optimal design and fabrication of CL components and structures, such as improving the local structure to reduce the number of dead pores and large agglomerates, etc.