RESUMO
For the design of a new chiroptically active host-guest system, a bent amphiphilic compound was synthesized using cyclic monoterpenes as key biorelated chiral frameworks. In water, the bent amphiphiles form a terpene-based micellar capsule with a core diameter of â¼2 nm in a spontaneous and quantitative fashion. The resultant chiral capsule shows wide-ranging uptake abilities toward achiral fluorescent dyes in water. Notably, relatively strong CD bands are generated from the resultant host-guest composites, e.g., possessing AIE-active tetraphenylethene and sterically demanding BODIPY dyes, through efficient host-to-guest chirality transfer. The composites also display CPL, with moderate to high emission asymmetry factors (|glum| = up to 3.3 × 10-3).
RESUMO
Mechanochromic luminescence (MCL) is an intrinsic phenomenon in the solid state and thus has been hardly observed in solution so far. Here we report that arylethynyl Pt(ii)-complexes with an NCN-pincer ligand are efficiently encapsulated by micellar aromatic capsules in water, through a simple grinding protocol with bent amphiphiles. When a bent pentamethylbenzene-based amphiphile is employed as an optimized capsule component, the resultant host-guest composite, with an average diameter of â¼4 nm, is obtained in water at room temperature. Notably, the nanocomposite displays strong red emission (Φ = 33%, λmax = 700 nm) derived from MCL via intermolecular Pt(ii)â¯Pt(ii) interactions even under aerobic aqueous conditions, in sharp contrast to the free Pt(ii)-complex with weak green emission (Φ = 4%, λmax = 500 nm) in CH2Cl2. Moreover, enhancement of the solution-state MCL (up to Φ = 48%) can be achieved by coencapsulation of the Pt(ii)-complexes with carbazole derivatives by the capsule in water. This study provides the first example of "solution-state" mechanochromic luminescence, capable of facilely tuning its intensity and wavelength, among the intensive studies of various solid-state MCL reported previously.
