Dynamics of droplet motion over hydrophobic surfaces with functionalized and non-functionalized ferro particles.

Dynamically manipulating droplet motion on hydrophobic surfaces is crucial in various fields, including biomedical, sensing, actuation, and oil-water separation applications. Ferrofluid droplets can be manipulated and controlled using external magnetic forces. The creation of ferrofluids involves multiple procedures that can affect the functionality and stability of droplet manipulation, limiting their use in sustainable applications. This study investigates the dynamics of droplet motion over functionalized and non-functionalized ferroparticles, considering different droplet volumes, ferroparticle layer widths, and wt% concentrations. The translational and sliding velocities of the droplets are measured using high-speed camera recording with a tracker application. The finding revealed the transformation of a droplet sliding motion into a rolling motion with propulsion under the magnetic influence. The sliding velocity increases for the droplets moving over the ordinary ferroparticles on the hydrophobic surface. However, the droplet motion is dominated by rolling in the case of hydrophobic ferro particles. The droplet sliding velocity rises sharply at high concentrations (or layer width) of ferroparticle as the magnetic bond number rises sharply to 3. A newborn droplet adheres to the magnet surface during droplet rolling and sliding motion.

Dust mitigation by a water droplet in between movable and modified wetting states surfaces.

A novel approach for mitigating environmental dust from hydrophobic surfaces using a water droplet is presented. A sessile droplet is sandwiched between two parallel plates, one of which is moveable and hydrophilic while the other is stationary and hydrophobic. Investigations are conducted into how plate spacing affects the dust mitigation rate and the droplet's level motion. The high-speed camera analyzes the droplet motion for various plate spacing, dusty regions, and droplet sizes. In a controlled laboratory setting, the movement of fluid and dust particles inside a droplet is simulated. The results showed that when a droplet is still, it effectively reduces dust. The droplet meniscus expands by decreasing the gap between the droplet and the surface, increasing the dust removal rate. While the Magdeburg force and surface tension influence the droplet's adhesion to a hydrophobic surface, surface tension remains the primary factor affecting droplet pinning on a hydrophilic plate, more so than pinning on a dusty hydrophobic surface. When compressing, a current is created in the droplet fluid, greatly accelerating the rate at which dust is removed from the hydrophobic surface. We also move a dangling droplet over a dirty surface to evaluate its cleaning effectiveness and find that a 60 µL droplet has a 97% cleaning effectiveness and can remove dust from up to 450 mm2 of surface area. Our study provides insight into the unique method of removing dust from active surfaces and sheds light on droplet pinning forces generated by the Magdeburg effect in nano-cavities during vertical and horizontal movement.

Water droplet behavior in between hydrophilic and hydrophobic surfaces and dust mitigation.

An innovative method is introduced for environmental dust mitigation from a hydrophobic surface by a sessile water droplet. The sessile water droplet is located between two parallel plates having hydrophilic (at the top) and hydrophobic (at the bottom) states. The water droplet is located at the top hydrophilic plate, and the effect of the plate spacing on dust mitigation rate is examined. The droplet behavior is analyzed for different plate spacings and various droplet sizes using a high-speed camera. The fluid and the particle motions are simulated inside the droplet while adopting the experimental conditions. The findings demonstrate that the sessile droplet can effectively mitigate dust. Reducing the plate spacing increases the droplet meniscus diameter and enhances the dust removal rate. The surface tension force on the hydrophilic surface remains greater than that of the pinning force on the dusty hydrophobic surface even though the Magdeburg and surface tension forces contribute to the droplet pinning force on the hydrophobic dusty surface. Flow current is developed in the droplet fluid during the squeezing period, which considerably enhances the dust removal rate from the hydrophobic surface. The cleaned area increases with the droplet volume and plate spacing. Stria patterns are observed on the circumference of the dust-removed area. The present study provides a detailed analysis of a new method of dust removal from surfaces for self-cleaning applications.

Sliding and Rolling Motion of a Ferro-Liquid Droplet on the Hydrophobic Surface under Magnetic Influence.

The ferro-liquid droplet manipulation on hydrophobic surfaces remains vital for various applications in biomedicine, sensors and actuators, and oil-water separation. The magnetic influence of ferro-liquid droplets on the hydrophobic surface is elucidated. The mechanisms of a newborn droplet formation under the magnetic force are explored. The sliding and rolling dynamics of the ferro-liquid droplets are assessed for the various concentrations wt % of ferro-particles. High-speed recording and a tracker program are used to evaluate the droplet sliding and translational velocities. It is demonstrated that the mode of droplet motion changes from sliding to rolling as the magnetic Bond number increases, in which case, the droplet position becomes close to the magnet surface. The translational velocity of the droplet under rolling mode increases as the ferro-particle concentration in the droplet fluid increases. A further increase of the magnetic Bond number results in the creation of a newborn droplet attached to the magnet surface.

Water droplet can mitigate dust from hydrophobized micro-post array surfaces.

Water droplet rolling motion over the hydrophobized and optically transparent micro-post array surfaces is examined towards dust removal pertinent to self-cleaning applications. Micro-post arrays are replicated over the optically transparent polydimethylsiloxane (PDMS) surfaces. The influence of micro-post array spacing on droplet rolling dynamics is explored for clean and dusty surfaces. The droplet motions over clean and dusty micro-post array surfaces are monitored and quantified. Flow inside the rolling droplet is simulated adopting the experimental conditions. Findings reveal that micro-post gap spacing significantly influences droplet velocity on clean and dusty hydrophobized surfaces. Air trapped within the micro-post gaps acts like a cushion reducing the three-phase contact line and interfacial contact area of the rolling droplet. This gives rise to increased droplet velocity over the micro-post array surface. Droplet kinetic energy dissipation remains large for plain and micro-post arrays with small gap spacings. A Rolling droplet can pick up dust particles from micro-post array gaps; however, few dust residues are observed for large gap spacings. Nevertheless, dust residues are small in quantity over hydrophobized micro-post array surfaces.

On the Mechanism of Human Saliva Interaction with Environmental Dust in Relation to Spreading of Viruses.

Environmental effects such as dust mitigation can amplify the spread of viruses via inhaling infected dust particles. Infusion and the spreading rate of human saliva over the dust particles can play a critical role in contiguous virus spread. In the present study, mechanical and chemical interactions of human saliva with environmental dust particles are considered. The saliva droplet impact on dust particles is examined while mimicking saliva droplet spreading during coughing in a dusty ambience. The mechanisms of saliva infusion and cloaking on the dust particles are explored. The characteristics of saliva droplet normal and oblique impacts on a dust particle are examined experimentally and numerically to evaluate the amount of saliva residues on the impacted particle surface. The findings reveal that the saliva liquid infuses and cloaks the dust particle surfaces. The saliva droplet impact on the dust particles leaves a considerable amount of saliva residues on the impacted surfaces, which remain undried for a prolonged period in indoor environments. Weak adhesion of the saliva-infected dust particles on surfaces, such as glass surfaces, enables saliva-infected dust particles to rejoin neighboring ambient air while possessing a high potential for virus spreading.

Sliding Water Droplet on Oil Impregnated Surface and Dust Particle Mitigation.

Self-cleaning of surfaces becomes challenging for energy harvesting devices because of the requirements of high optical transmittance of device surfaces. Surface texturing towards hydrophobizing can improve the self-cleaning ability of surfaces, yet lowers the optical transmittance. Introducing optical matching fluid, such as silicon oil, over the hydrophobized surface improves the optical transmittance. However, self-cleaning ability, such as dust mitigation, of the oil-impregnated hydrophobic surfaces needs to be investigated. Hence, solution crystallization of the polycarbonate surface towards creating hydrophobic texture is considered and silicon oil impregnation of the crystallized surface is explored for improved optical transmittance and self-cleaning ability. The condition for silicon oil spreading over the solution treated surface is assessed and silicon oil and water infusions on the dust particles are evaluated. The movement of the water droplet over the silicon oil-impregnated sample is examined utilizing the high-speed facility and the tracker program. The effect of oil film thickness and the tilting angle of the surface on the sliding droplet velocity is estimated for two droplet volumes. The mechanism for the dust particle mitigation from the oil film surface by the sliding water droplet is analyzed. The findings reveal that silicon oil impregnation of the crystallized sample surface improves the optical transmittance significantly. The sliding velocity of the water droplet over the thick film (~700 µm) remains higher than that of the small thickness oil film (~50 µm), which is attributed to the large interfacial resistance created between the moving droplet and the oil on the crystallized surface. The environmental dust particles can be mitigated from the oil film surface by the sliding water droplet. The droplet fluid infusion over the dust particle enables to reorient the particle inside the droplet fluid. As the dust particle settles at the trailing edge of the droplet, the sliding velocity decays on the oil-impregnated sample.

Avalanche effect for chemically modified dust mitigation from surfaces.

Cost effective dust mitigation from surfaces is one of the challenges in various sectors. The reduction of dust adhesion on surfaces plays a vital role for dust mitigation from surfaces under the gravitational influence. Creating an avalanche effect on dusty surfaces improves the dust mitigation rate and provides an effective cleaning process. Hence, solution treatment of dust by low concentration hydrofluoric acid is considered towards reducing dust adhesion on glass surfaces. To increase the rate of dust mitigation, the avalanche influence is created by the higher density and larger size particles (5300 kg/m3 and ~ 50 µm) than the average size dust particles (2800 kg/m3 and 1.2 µm) via locating them in the top region of the dusty glass surfaces. Mitigation velocity of the dust particles is evaluated using a high-speed recording system and the tracker program. Findings revealed that solution treatment (curing) of the dust particles results in the formation of fluorine compounds, such as CaF2 and MgF2, on dust surfaces, which suppress dust adhesion on surfaces. OSHA Globally Harmonized System lists the fluorine compounds formed as environmentally non-harmful. Avalanche's influence results in dust mitigation at a smaller tilt angle of the glass surface (~ 52°) than that of the case with none-avalanche influence (63°). Area cleaned on the glass surface, via dust mitigation, is larger as the avalanche is introduced, which becomes more apparent for the solution treated dust particles. Dust mitigation under avalanche influence improves optical transmittance of the dusty glass samples by a factor of 98%.

A water droplet-cleaning of a dusty hydrophobic surface: influence of dust layer thickness on droplet dynamics.

Water droplet cleaning of a dusty hydrophobic surface is examined. Environmental dust are used in the experiments and cloaking velocity of a dust layer by a droplet fluid is measured and hemi-wicking conditions for the dust layer are analyzed adopting the pores media wick structure approach. A droplet motion on dusty and inclined hydrophobic surface is analyzed using a high speed digital imaging system. Influences of dust layer thickness, droplet volume, and surface inclination angle on the mechanisms of dust removal by a rolling droplet are evaluated. The findings revealed that dust cloaking velocity decreases exponentially with time. The droplet fluid can cloak the dust layer during its transition on the dusty surface. The transition period of droplet wetted length on the dusty surface remains longer than the cloaking time of the dust layer by the droplet fluid. Translational velocity of rolling droplet is affected by the dust layer thickness, which becomes apparent for small volume droplets. Small volume droplet (20 µL) terminates on the thick dust layer (150 µm) at low surface inclination angle (1°). The quantity of dust picked up by the rolling droplet increases as the surface inclination angle increases. The amount of dust residues remaining on the rolling droplet path is relatively larger for the thick dust layer (150 µm) as compared to its counterpart of thin dust layer (50 µm).

Carbonated Water Droplet Can Ease Dust Mitigation from Hydrophobic Surfaces.

Carbonated water droplets can ease the difficulties faced by distilled water droplets mitigating dust particles from hydrophobic surfaces. Rising of CO2 bubbles in carbonated water droplets and their interaction with the flow structure, created by Marangoni and buoyancy possessions, in droplets are investigated. Spreading and infusion (cloaking) of carbonated water on dust surfaces are analyzed, and the rate at which bubbles formed inside the carbonated water droplet, as placed on a dusty hydrophobic surface, is examined. Flow structures formed inside the carbonated water droplet are simulated, and findings are compared to those corresponding to the distilled water droplet. Dust mitigation from the hydrophobic surface toward droplet liquid inside is evaluated using the high-speed recording system, and the results are compared with those of predictions. It is found that carbonated water spreads and infuses onto dust particles at a higher rate than that at which distilled water does. The rising bubble generates wake-like flow in the fluid while modifying the flow structure inside the droplet; hence, the number of circulating structures increases from two to four in droplet fluid. The dust particles picked up by flow currents are redistributed over the entire carbonated water droplet, while mitigated dust particles remain in the lower region of the distilled water droplet. Bubbles formed inside the carbonated water droplet improve dust lifting and rate of dust mitigation from the surface.

Carbonated water droplets on a dusty hydrophobic surface.

Dust mitigation from surfaces remains essential, particularly for the efficient operation of energy harnessing devices. Although various dust removal methods have been introduced, the self-cleaning method is favorable because of the cost-effective cleaning process. Dust mitigation from surfaces by water droplets, mimicking nature, is fruitful because it involves low-cost operations. The dust removal rate from surfaces by rolling water droplets can be increased by creating bubbles inside the rolling droplets through which dust pinning on surfaces can be lowered and the droplet liquid infusion on dust surfaces can be enhanced. This study provides insight into bubble formation and dust mitigation in carbonated and distilled water droplets located on hydrophobic surfaces by examining bubble formation and dust distribution inside the water droplets. The behavior of bubbles inside the carbonated water droplet and emanating from the hydrophobic surface was recorded and analyzed by incorporating high-speed camera data. The influence of environmental dust particles on bubble formation was also assessed. Bubble velocity was formulated analytically and the findings are compared with those of the experimental values. Findings revealed that the bubble formation inside the carbonated droplet fluid had a significant effect on the transition of dust particles from the hydrophobic surface towards the droplet fluid. The volume concentration of dust particles in the carbonated water droplet was almost 1.5 to 2.5 times larger than that of the distilled water droplet. The dissolution of alkaline and alkaline earth metal compounds in the carbonated droplet fluid acted like nucleation centers for bubble formation; hence, the number of bubbles formed on the dusty hydrophobic surface was greater than that of the clean hydrophobic surface. Some bubbles attached at the dust particle surface contributed to dust mobility in the droplet fluid, which occurred particularly in the droplet bottom region. This enhanced the velocity of the dust particles transiting from the dusty hydrophobic surface to the droplet fluid interior by almost 1.5 times in the early period.

Droplet fluid infusion into a dust layer in relation to self-cleaning.

Wettability of a droplet liquid on a dusty hydrophobic plate is considered and the fluid infusion into the dust layer is studied pertinent to dust removal from the hydrophobic surfaces via rolling/sliding droplets. Influence of droplet hydrostatic pressure on the fluid infusion into dust layer is also investigated towards exploring the dust removal mechanisms. Environmental dust characteristics are evaluated and their interface with the droplet fluid is assessed. Sets of experiments are carried out to examine: (i) droplet fluid infusion into the dust layer, (ii) droplet fluid cloaking of dust, and (iii) evaluate the weight gain of the dust particles during cloaking. The findings reveal that droplet fluid (water) spreads onto the dusty surface and infuses on the dust particles. Cloaking velocity decays sharply with time and the weight gain of the dust particles is about 17% of the original dust weight after cloaking. The dust particles have a large area of nano-size open-pores-sites on the surface; however, capillary diffusion through these sites is limited with shallow depths and the weight gain of a dust particle via capillary diffusion is about 1% of the particle weight. The maximum infusion depth of the droplet fluid in the dust layer is about 74 µm, which is slightly less than the dust layer thickness on the surface. The rolling droplet picks up all the dust from the 150 µm thick dust layer on the surface.

Dust removal from a hydrophobic surface by rolling fizzy water droplets.

Here, environmental dust cleaning from an inclined hydrophobic surface by rolling liquid droplets has been studied and the influence of fluid droplets on the dust removal rate has been examined. The distilled and carbonated water droplets at different volumes were incorporated and the inclination angle of the dusty hydrophobic surface on the droplet motion was explored in the experiments. We demonstrated that the carbonated water droplet had higher translational velocity than the distilled water droplet on the dusty hydrophobic surface. The bubbles formed around the droplet surface acted as gas cushions at the interface between the solid surface and the fluid droplet while lowering the friction and pinning forces and enhancing the droplet translational velocity on the surface. Collected environmental dust has various components, some of which can dissolve in water while creating resorption/nucleation centers for bubble formation in the carbonated water droplet. The interaction between the bubbles and the dust particles at the liquid-solid interface enhanced the rate of dust particle movement into carbonated water. For a small-volume droplet (20 µL) at a low surface inclination angle (δ = 1°), the rolling motion of the distilled and carbonated water droplets ceased on the hydrophobic surface at early periods.

Stretchable Hydrophobic Surfaces and Self-Cleaning Applications.

Hydrophobizing of stretchable elastomer surfaces is considered and the reversible behavior of the resulting surface wetting state is examined after stretching and relaxing the hydrophobized samples. The environmental dust are analyzed in terms of elemental constitutes and size, and the dust pinning on the hydrophobized surface is measured. The dust removal mechanisms, by the water droplets on the hydrophobized surface, are investigated. We demonstrated that deposition of functionalized nano-size silica units on the elastomer surface gives rise to hydrophobicity with 135° ± 3° contact angle and low hysteresis of 3° ± 1°. Stretching hydrophobized elastomer surface by 50% (length) reduces the contact angle to 122° ± 3° and enhances the hysteresis to 6° ± 1°. However, relaxing the stretched sample causes exchanging surface wetting state reversibly. Water droplet rolling and sliding can clean the dusty hydrophobized surface almost 95% (mass ratio of the dust particles removed). Droplet puddling causes striations like structures along the droplet path and close examination of the few residues of the dust reveals that the droplet takes away considerably large amount of dust from surface.

Environmental Dust Particles Repelling from A Hydrophobic Surface under Electrostatic Influence.

Environmental dust particles repelling from a hydrophobic surface under the electrostatic influence are considered and the dynamics of the dust particles are analyzed incorporating the high speed camera. The velocity of the repelled dust particles are formulated using the force balance incorporating the forces associated with the electrostatic repulsion, particle adhesion, particle drag, and the inflight particles interaction under the charge influence. The functionalized silica particles are deposited on the glass surface towards achieving a hydrophobic wetting state on the surface. An electronic circuitry is designed and built while generating the electrostatic effect, in the pulse form, on the dust particles located on the surface of the hydrophobic plate. Findings revealed that functionalized silica particles deposited surface results in hydrophobic wetting state with contact angle in the order of 158° ± 2° and contact angle hysteresis of 2° ± 1°. The electrostatic impulsive force generated on the plate surface enables to repel most of the sizes of the dust particles; however, some of the small dust particles remain as the residues on the surface after the electrostatic influence. The dust particle velocity predicted from the analytical formulation agrees with that obtained from the high speed camera data. The pinning force of the small size particles (0.6 µm≤), due to adhesion on the surface, is found to be larger than the average size particles (∼1.2 µm), which in turn, suppresses these particles repelling from the surface under the electrostatic influence. The residues of the dust particles on the as received glass surface after dust repelling are more than those residues on the hydrophobic surface. This behavior is associated with the dust particles adhesion on the surface. Consequently, hydrophobic wetting state on the plate surface improves the dust particle repelling from the surface.

Self-cleaning of a hydrophobic surface by a rolling water droplet.

A water droplet behavior on a hydrophobic surface is examined relevant to the dust particles removal from the surface. Surface crystallization of polycarbonate is realized in acetone bath and the resulting surface is coated by the functionalized nano-size silica particles towards reducing contact angle hysteresis. This arrangement provides droplet rolling/sliding on the hydrophobic surface. Droplet translational velocity is formulated and predictions are compared with those resulted from the high speed recorded data. Influence of surface inclination angle on droplet dynamics is investigated and the dust removal mechanism on the inclined surface is analyzed. It is found that predictions of droplet translational velocity agree well with those obtained from the experiment. Droplet rolling dominates over sliding on the inclined surface and droplet sliding velocity remains almost 10% of the droplet translational velocity. The main mechanism for the dust particles removal is associated with the droplet fluid cloaking of the dust particles during its transition on the hydrophobic surface. Droplet acceleration, due to increased surface inclination angle, has effect on the rate of dust particles removal from the surface, which is more apparent for large droplet volumes. Increasing droplet acceleration improves the coverage area of the clean surface.

Correction: Water droplet on inclined dusty hydrophobic surface: influence of droplet volume on environmental dust particles removal.

[This corrects the article DOI: 10.1039/C8RA10092F.].

Water Droplet Dynamics on a Hydrophobic Surface in Relation to the Self-Cleaning of Environmental Dust.

The dynamic motion of a water droplet on an inclined hydrophobic surface is analyzed with and without environmental dust particles on the surface. Solution crystallization of a polycarbonate surface is carried out to generate a hydrophobic surface with hierarchical texture composed of micro/nanosize spheroids and fibrils. Functionalized nanosize silica particles are deposited on the textured surface to reduce contact angle hysteresis. Environmental dust particles are collected and characterized using analytical tools prior to the experiments. The droplet motion on the hydrophobic surface is assessed using high-speed camera data, and then, the motion characteristics are compared with the corresponding analytical results. The influence of dust particles on the water droplet motion and the amount of dust particles picked up from the hydrophobic surface by the moving droplet is evaluated experimentally. A 40 µL droplet was observed to roll on the hydrophobic surface with and without dust particles, and the droplet slip velocity was lower than the rotational velocity. The rolling droplet removes almost all dust particles from the surface, and the mechanism for the removal of dust particles from the surface was determined to be water cloaking of the dust particles.

Environmental dust effects on aluminum surfaces in humid air ambient.

Environmental dusts settle on surfaces and influence the performance of concentrated solar energy harvesting devices, such as aluminum troughs. The characteristics of environmental dust and the effects of mud formed from the dust particles as a result of water condensing in humid air conditions on an aluminum wafer surface are examined. The dissolution of alkaline and alkaline earth compounds in water condensate form a chemically active mud liquid with pH 8.2. Due to gravity, the mud liquid settles at the interface of the mud and the aluminum surface while forming locally scattered patches of liquid films. Once the mud liquid dries, adhesion work to remove the dry mud increases significantly. The mud liquid gives rise to the formation of pinholes and local pit sites on the aluminum surface. Morphological changes due to pit sites and residues of the dry mud on the aluminum surface lower the surface reflection after the removal of the dry mud from the surface. The characteristics of the aluminum surface can address the dust/mud-related limitations of reflective surfaces and may have implications for the reductions in the efficiencies of solar concentrated power systems.

Chemo-Mechanical Characteristics of Mud Formed from Environmental Dust Particles in Humid Ambient Air.

Mud formed from environmental dust particles in humid ambient air significantly influences the performance of solar harvesting devices. This study examines the characterization of environmental dust particles and the chemo-mechanics of dry mud formed from dust particles. Analytical tools, including scanning electron microscopy, atomic force microscopy, energy dispersive spectroscopy, particle sizing, and X-ray diffraction, are used to characterize dry mud and dust particles. A micro/nano tribometer is used to measure the tangential force and friction coefficient while tensile tests are carried out to assess the binding forces of dry mud pellets. After dry mud is removed, mud residuals on the glass surface are examined and the optical transmittance of the glass is measured. Dust particles include alkaline compounds, which dissolve in water condensate and form a mud solution with high pH (pH = 7.5). The mud solution forms a thin liquid film at the interface of dust particles and surface. Crystals form as the mud solution dries, thus, increasing the adhesion work required to remove dry mud from the surface. Optical transmittance of the glass is reduced after dry mud is removed due to the dry mud residue on the surface.