Synthesis, Structural, Optical, and Electrical Characterization of Biochitosan/Na0.5Bi0.5TiO3 Composite Thin-Film Materials.

The purpose of this research work was to synthesis bioderived nanocomposite films by incorporating Na0.5Bi0.5TiO3 (NBTO) nanoparticles into a chitosan matrix. The NBTO nanoparticles were synthesized using a traditional solid-state technique. Then, through a solution-casting approach, flexible composite films were fabricated using chitosan polymer. The study presents a range of compelling findings. For structural and morphological insights, scanning electron microscopy (SEM) reveals a fascinating morphology where NBTO nanoparticles are uniformly dispersed and interlocked with other particles, forming interconnected grains with significant interspaces within the chitosan matrix. For the optical properties, the spectral response within the 300-800 nm range is primarily governed by light scattering attributed to NBTO particles with diameter sizes ranging from 100 to 400 nm, as well as the distinctive bandgap exhibited by the NBTO phase. The investigation of dielectric properties demonstrates that composite films exhibit markedly higher dielectric values in comparison to pure chitosan films. It is noteworthy that an increase in the NBTO content results in a corresponding increase in dielectric values, enhancing the versatility of these materials. Local piezoelectric measurements utilizing piezoresponse force microscopy confirm the expected piezoelectric and ferroelectric behavior of NBTO particles when dispersed within the chitosan matrix. This research introduces a novel class of biocompatible nanocomposite materials, combining impressive structural attributes, enhanced dielectric properties, and piezoelectric capabilities. The outcomes of this study hold substantial promise for advanced applications in opto- and piezoelectric technologies, marking a significant advancement in biologically sourced materials with multifunctional properties.

Insights for the control of dried-fruit beetle Carpophilus hemipterus (Nitidulidae) using rosemary essential oil loaded in chitosan nanoparticles.

Natural insecticidal products, essentially essential oils and their bioactive compounds are available as an excellent alternative method to control insect pests as well as they are less toxic to human health. However, due to their volatile constituents, encapsulation could be considered as the most suitable solution for their practical application. Therefore, this study aims to explore the insecticidal toxicity of chitosan nanoparticles loaded with Rosmarinus officinalis essential oil against adults of Carpophilus hemipterus. Chitosan nanoparticles were prepared by ionic gelation method with an encapsulation efficiency 41.543.1% and loading capacity 5.24G0.28%. Results revealed that chitosan nanoparticles loaded rosemary oil exhibited interesting insecticidal toxicity towards C. hemipterus adults in stored dates with 50.73% mortality. Overall, this work pointed out that the innovative design method based on chitosan-nanoparticles loaded rosemary oil can be promoted in integrated pest management program for stored date pests.

Primary hydatid cyst of the small intestine masquerading as intestinal duplication in a child.

Hydatid disease or hydatidosis is a worldwide zoonosis disease caused by the tapeworm of Echinococcus granulosus and still widely endemic in Tunisia especially in rural areas where the sheep-dog cycle is dominant. It is an important public health problem in the pediatric age group causing significant morbidity and mortality. We report a case of primary hydatid cyst of the small intestine in a child and we want to highlight the difficulty that we meet in the diagnosis despite the contribution of imaging.