RESUMO
Dextrinization of starch using extrusion processing is crucial to the quality of direct expanded products. To determine the extent of dextrinization, flour samples were extracted from a twin-screw extruder that had been brought to a sudden stop and molecular weights were determined by intrinsic viscosity. The screw profile and moisture feed content had the most significant impact on molecular weight reduction, reducing intrinsic viscosity from 1.75 to 0.70dL/g at the most. The breakdown, as shown by a reduction in intrinsic viscosity, had a strong negative correlation (r=-0.96) with specific mechanical energy. However, the extruder die did not have a measurable impact on the molecular weight reduction of waxy flour. Size exclusion chromatography confirmed intrinsic viscosity measurements were associated with reduction of the size of amylopectin molecules to approximately 1/10 the original molecular weight while native gliadin was nearly eliminated from the waxy flour following the extrusion treatments.