Safety evaluation of freeway interchange merging areas based on driver workload theory.

Prior safety evaluations of interchange merging areas have mostly focused on traffic conflicts and operating speeds, without considering how these factors can influence the driver workload. Researches regarding the level of driver workload have largely concentrated on urban roads, tunnel sections, and basic freeway segments, without considering the impact of merging traffic flows on safety. Therefore, this study has investigated how merging vehicles can impact through-driver workload and safety. Three independent field experiments were conducted on freeways, involving 18 drivers and 17 interchanges. The results showed that the vehicles merging onto freeway impact driver workload and driving performance, generating potential risk that cannot be ignored. Merging into the mainline traffic flow increases the through-driver workload to a higher level or even exceeds the safety threshold, despite there being better geometrical conditions of interchanges than those of basic freeway segments. When the volume of merging vehicles exceeds 564 pcu/h or the traffic saturation is above 0.485, driver workload rises above the safety thresholds and the driving risk is elevated, which potentially would lead to crashes. This study offers insights for more effective segment division of operating speed prediction, and dynamic risk management with regard to interchange safety.

Thallium transformation and partitioning during Pb-Zn smelting and environmental implications.

Thallium (Tl) is a toxic and non-essential heavy metal. Raw Pb-Zn ores and solid smelting wastes from a large Pb-Zn smelting plant - a typical thallium (Tl) pollution source in South China, were investigated in terms of Tl distribution and fractionation. A modified IRMM (Institute for Reference Materials and Measurement, Europe) sequential extraction scheme was applied on the samples, in order to uncover the geochemical behavior and transformation of Tl during Pb-Zn smelting and to assess the potential environmental risk of Tl arising from this plant. Results showed that the Pb-Zn ore materials were relatively enriched with Tl (15.1-87.7 mg kg(-1)), while even higher accumulation existed in the electrostatic dust (3280-4050 mg kg(-1)) and acidic waste (13,300 mg kg(-1)). A comparison of Tl concentration and fraction distribution in different samples clearly demonstrated the significant role of the ore roasting in Tl transformation and mobilization, probably as a result of alteration/decomposition of related minerals followed by Tl release and subsequent deposition/co-precipitation on fine surface particles of the electrostatic dust and acidic waste. While only 10-30% of total Tl amounts was associated with the exchangeable/acid-extractable fraction of the Pb-Zn ore materials, up to 90% of total Tl was found in this fraction of the electrostatic dust and acidic waste. Taking into account the mobility and bioavailability of this fraction, these waste forms may pose significant environmental risk.