Motility-induced coexistence of a hot liquid and a cold gas.

If two phases exist at the same time, such as a gas and a liquid, they have the same temperature. This fundamental law of equilibrium physics is known to apply even to many non-equilibrium systems. However, recently, there has been much attention in the finding that inertial self-propelled particles like Janus colloids in a plasma or microflyers could self-organize into a hot gas-like phase that coexists with a colder liquid-like phase. Here, we show that a kinetic temperature difference across coexisting phases can occur even in equilibrium systems when adding generic (overdamped) self-propelled particles. In particular, we consider mixtures of overdamped active and inertial passive Brownian particles and show that when they phase separate into a dense and a dilute phase, both phases have different kinetic temperatures. Surprisingly, we find that the dense phase (liquid) cannot only be colder but also hotter than the dilute phase (gas). This effect hinges on correlated motions where active particles collectively push and heat up passive ones primarily within the dense phase. Our results answer the fundamental question if a non-equilibrium gas can be colder than a coexisting liquid and create a route to equip matter with self-organized domains of different kinetic temperatures.

Writing Into Water.

Writing is an ancient communication technique dating back at least 30 000 years. While even sophisticated contemporary writing techniques hinge on solid surfaces for engraving or the deposition of ink, writing within a liquid medium requires a fundamentally different approach. The study here demonstrates the writing of lines, letters, and complex patterns in water by assembling lines of colloidal particles. Unlike established techniques for underwater writing on solid substrates, these lines are fully reconfigurable and do not require any fixation onto the substrate. Exploiting gravity, an ion-exchange bead (pen) is rolled across a layer of sedimented colloidal particles (ink). The pen evokes a hydrodynamic flow collecting ink-particles into a durable, high-contrast line along its trajectory. Deliberate substrate-tilting sequences facilitate pen-steering and thus drawing and writing. The experiments are complemented with a minimal model that quantitatively predicts the observed parameter dependence for writing in fluids and highlights the generic character of writing by line-assembly. Overall, the approach opens a versatile route for writing, drawing, and patterning fluids-even at the micro-scale.

Detecting Isotachophoresis Zones Hidden in Noise Using Signal Processing.

Lowering the limit of detection in chemical or biochemical analysis is key to extending the application scope of sensing schemes. Usually, this is related to an increased instrumentation effort, which in turn precludes many commercial applications. We demonstrate that the signal-to-noise ratio of isotachophoresis-based microfluidic sensing schemes can be substantially increased merely by postprocessing of recorded signals. This becomes possible by exploiting knowledge about the physics of the underlying measurement process. The implementation of our method is based on microfluidic isotachophoresis and fluorescence detection, for which we take advantage of the physics of electrophoretic sample transport and the structure of noise in the imaging process. We demonstrate that by processing only 200 images, the detectable concentration, compared to the detection from a single image, is already lowered by 2 orders of magnitude without any additional instrumentation effort. Furthermore, we show that the signal-to-noise ratio is proportional to the square root of the number of fluorescence images, which leaves room for further lowering of the detection limit. In the future, our results could be relevant for various applications where the detection of minute sample amounts plays a role.

Active Refrigerators Powered by Inertia.

We present the operational principle for a refrigerator that uses inertial effects in active Brownian particles to locally reduce their (kinetic) temperature by 2 orders of magnitude below the environmental temperature. This principle exploits the peculiar but so-far unknown shape of the phase diagram of inertial active Brownian particles to initiate motility-induced phase separation in the targeted cooling regime only. Remarkably, active refrigerators operate without requiring isolating walls opening the route toward using them to systematically absorb and trap, e.g., toxic substances from the environment.

Structural and Dynamical Properties of Liquids in Confinements: A Review of Molecular Dynamics Simulation Studies.

Molecular dynamics (MD) simulations are a powerful tool for detailed studies of altered properties of liquids in confinement, in particular, of changed structures and dynamics. They allow, on one hand, for perfect control and systematic variation of the geometries and interactions inherent in confinement situations and, on the other hand, for type-selective and position-resolved analyses of a huge variety of structural and dynamical parameters. Here, we review MD simulation studies on various types of liquids and confinements. The main focus is confined aqueous systems, but also ionic liquids and polymer and silica melts are discussed. Results for confinements featuring different interactions, sizes, shapes, and rigidity will be presented. Special attention will be given to situations in which the confined liquid and the confining matrix consist of the same type of particles and, hence, disparate liquid-matrix interactions are absent. Findings for the magnitude and the range of wall effects on molecular positions and orientations and on molecular dynamics, including vibrational motion and structural relaxation, are reviewed. Moreover, their dependence on the parameters of the confinement and their relevance to theoretical approaches to the glass transition are addressed.