1.
Chem Commun (Camb)
; 56(37): 4994-4997, 2020 May 07.
Artigo
em Inglês
| MEDLINE
| ID: mdl-32239066
RESUMO
Aerobic oxidation of (tmeda)Fe(CH2tBu)2 in toluene or THF solution leads to the self-assembly of a magic-sized all-ferrous oxide cluster containing the Fe9O6 subunit and bearing organometallic and diamine ligands. Mössbauer studies of the cluster are consistent with an all-ferrous assignment and magnetometry reveals complex intracluster and intercluster magnetic interactions.
