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1.
Phys Rev Lett ; 91(6): 067601, 2003 Aug 08.
Artigo em Inglês | MEDLINE | ID: mdl-12935108

RESUMO

We report an enhancement of proton NMR signals by a factor of 10(6) by cross polarization with hyperpolarized liquid 129Xe in an ultralow magnetic field of 1 microT. The NMR signals from cyclopentane, acetone, and methanol are detected using a commercial high-T(c) SQUID magnetometer with a signal-to-noise ratio of up to 1000 from a single 90 degrees tipping pulse. This technique allows a wide range of low-field NMR measurements and is promising for the detection of intermolecular scalar spin-spin couplings. Scalar intermolecular couplings can produce a shift of the average NMR frequency in a hyperpolarized sample even in the presence of rapid chemical exchange.

3.
Proc Natl Acad Sci U S A ; 96(8): 4730-4, 1999 Apr 13.
Artigo em Inglês | MEDLINE | ID: mdl-10200330

RESUMO

This paper examines the relationship between various treatment parameters within a latent variable model when the effects of treatment depend on the recipient's observed and unobserved characteristics. We show how this relationship can be used to identify the treatment parameters when they are identified and to bound the parameters when they are not identified.


Assuntos
Modelos Estatísticos , Variações Dependentes do Observador , Resultado do Tratamento , Humanos , Modelos Econômicos , Modelos Psicológicos
4.
Proc Natl Acad Sci U S A ; 93(23): 13416-20, 1996 Nov 12.
Artigo em Inglês | MEDLINE | ID: mdl-8917606

RESUMO

This paper decomposes the conventional measure of selection bias in observational studies into three components. The first two components are due to differences in the distributions of characteristics between participant and nonparticipant (comparison) group members: the first arises from differences in the supports, and the second from differences in densities over the region of common support. The third component arises from selection bias precisely defined. Using data from a recent social experiment, we find that the component due to selection bias, precisely defined, is smaller than the first two components. However, selection bias still represents a substantial fraction of the experimental impact estimate. The empirical performance of matching methods of program evaluation is also examined. We find that matching based on the propensity score eliminates some but not all of the measured selection bias, with the remaining bias still a substantial fraction of the estimated impact. We find that the support of the distribution of propensity scores for the comparison group is typically only a small portion of the support for the participant group. For values outside the common support, it is impossible to reliably estimate the effect of program participation using matching methods. If the impact of participation depends on the propensity score, as we find in our data, the failure of the common support condition severely limits matching compared with random assignment as an evaluation estimator.


Assuntos
Viés , Modelos Estatísticos , Seleção de Pacientes , Seleção de Pessoal , Humanos , Probabilidade , Análise de Regressão , Reprodutibilidade dos Testes
5.
Stat Methods Med Res ; 3(3): 279-99, 1994.
Artigo em Inglês | MEDLINE | ID: mdl-7820296

RESUMO

This paper considers models for unobservables in duration models. It demonstrates how cross-section and time-series variation in regressors facilitates identification of single-spell, competing risks and multiple spell duration models. We also demonstrate the limited value of traditional identification studies by considering a case in which a model is identified in the conventional sense but cannot be consistently estimated.


Assuntos
Modelos Econométricos , Medição de Risco , Algoritmos , Simulação por Computador , Modelos de Riscos Proporcionais , Fatores de Tempo
6.
Res Popul Econ ; 7: 3-91, 1991.
Artigo em Inglês | MEDLINE | ID: mdl-12317032

RESUMO

"This paper estimates semiparametric reduced-form neoclassical models of life-cycle fertility in Sweden. Rising female wages delay times to all conceptions and reduce total conceptions. These results are robust across a variety of empirical specifications. We find a particular neoclassical model that predicts fertility attained at different ages as well as the aggregate time series of birth rates. A model that excludes wages and incomes predicts fertility attained at different ages but fails to predict the aggregate time series, and is dominated by the neoclassical model in terms of non-nested test criteria. Cohort drift found in estimated parameters is consistent with the expansion of pronatal social programs. The estimated neoclassical model produces strong short-run responses of birth rates to wages and incomes of the sort that have been found in the time series literature on fertility while generating the relatively weak long-run responses to economic variables found in the cross-sectional literature on completed fertility."


Assuntos
Fatores Etários , Coeficiente de Natalidade , Estudos de Coortes , Economia , Política de Planejamento Familiar , Fertilidade , Renda , Modelos Econômicos , Modelos Teóricos , Salários e Benefícios , Demografia , Países Desenvolvidos , Europa (Continente) , População , Características da População , Dinâmica Populacional , Política Pública , Pesquisa , Países Escandinavos e Nórdicos , Fatores Socioeconômicos , Suécia
7.
Econometrica ; 58(6): 1,411-41, 1990 Nov.
Artigo em Inglês | MEDLINE | ID: mdl-12343324

RESUMO

"This paper estimates semiparametric reduced-form neoclassical models of life-cycle fertility in Sweden.... The estimated model integrates aspects of life cycle fertility that have previously been studied in isolation of each other: completed fertility, childlessness, interbirth intervals, and the time series of annual birth rates. The main objective of this paper is to determine which aspects of life cycle fertility, if any, are sensitive to male income and female wages."


Assuntos
Intervalo entre Nascimentos , Coeficiente de Natalidade , Economia , Fertilidade , Renda , Estágios do Ciclo de Vida , Modelos Teóricos , Paridade , Salários e Benefícios , Comportamento Sexual , Demografia , Países Desenvolvidos , Europa (Continente) , Família , Características da Família , Serviços de Planejamento Familiar , População , Dinâmica Populacional , Pesquisa , Países Escandinavos e Nórdicos , Fatores Socioeconômicos , Suécia
8.
J Am Stat Assoc ; 85(410): 283-94, 1990 Jun.
Artigo em Inglês | MEDLINE | ID: mdl-12155385

RESUMO

"This article tests assumptions invoked in the demographic literature to estimate the population distribution of fecundability from data on waiting times to first conception. In continuous time, the key assumption is that waiting times are realizations from a mixture of exponentials distribution. In discrete time, the key assumption is that waiting times are realizations from a mixture of geometrics distribution. The [U.S.] Hutterite data analyzed by Sheps (1965) are consistent with this assumption. Various models, however, have one representation in mixture of exponentials form. A fundamental identification problem plagues the conventional estimation procedure. Our analysis calls into question the conventional practice of checking model specification by using goodness-of-fit tests. The practical importance of the identification problem in duration models is demonstrated."


Assuntos
Coeficiente de Natalidade , Estudos de Avaliação como Assunto , Fertilidade , Modelos Teóricos , Crescimento Demográfico , Fatores de Tempo , América , Demografia , Países Desenvolvidos , América do Norte , População , Dinâmica Populacional , Reprodução , Pesquisa , Estados Unidos
9.
J Popul Econ ; 3(4): 235-75, 1990.
Artigo em Inglês | MEDLINE | ID: mdl-12283653

RESUMO

"This paper considers the formulation, estimation and interpretation of microdynamic models of fertility. Our model explains parity choices, sterility, childlessness, interbirth intervals and initiation of pregnancy within a unified framework. We develop a general methodology for estimating the determinants of transition times to births of different orders. Our procedure incorporates time-varying explanatory variables and unobservables. We present conditions that justify conventional formulae relating hazards to survivor functions when time-varying variables enter hazards. We also consider the validity of widely-used piecemeal estimation strategies that focus on one birth at a time. We consider methods for selecting a best model among a class of non-nested models. Two criteria are set forth and used to evaluate the determinants of third births in Sweden."


Assuntos
Ordem de Nascimento , Coeficiente de Natalidade , Estudos de Avaliação como Assunto , Fertilidade , Comportamento Sexual , Estatística como Assunto , Demografia , Países Desenvolvidos , Europa (Continente) , Características da Família , Relações Familiares , População , Dinâmica Populacional , Pesquisa , Países Escandinavos e Nórdicos , Suécia
10.
J Am Stat Assoc ; 84(408): 958-65, 1989 Dec.
Artigo em Inglês | MEDLINE | ID: mdl-12155384

RESUMO

"This article demonstrates the value of microdata for understanding the effect of wages on life cycle fertility dynamics. Conventional estimates of neoclassical economic fertility models obtained from linear aggregate time series regressions are widely criticized for being nonrobust when adjusted for serial correlation. Moreover, the forecasting power of these aggregative neoclassical models has been shown to be inferior when compared with conventional time series models that assign no role to wages. This article demonstrates that, when neoclassical models of fertility are estimated on microdata using methods that incorporate key demographic restrictions and when they are properly aggregated, they have considerable forecasting power." Data are from the 1981 Swedish Fertility Survey.


Assuntos
Coeficiente de Natalidade , Fertilidade , Previsões , Renda , Modelos Teóricos , Fatores de Tempo , Demografia , Países Desenvolvidos , Economia , Europa (Continente) , População , Dinâmica Populacional , Pesquisa , Países Escandinavos e Nórdicos , Fatores Socioeconômicos , Estatística como Assunto , Suécia
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