1.
Org Lett
; 16(24): 6278-81, 2014 Dec 19.
Artigo
em Inglês
| MEDLINE
| ID: mdl-25467856
RESUMO
In the presence of FeCl(n)-(bisphosphine) or FeCl(n)-(2-iminomethylpyridine) (n = 2 or 3), 2-substituted oxetanes reacted with Grignard reagents undergoing reductive magnesiation at the 2-position to afford substituted 3-oxidopropylmagnesium compounds, which are useful nucleophiles in reactions with a variety of electrophiles.