1.
Chemistry
; 20(22): 6608-12, 2014 May 26.
Artigo
em Inglês
| MEDLINE
| ID: mdl-24737711
RESUMO
An unprecedented spontaneous reactivity between diazonium salts and diboronic acid has been unveiled, leading to a versatile arylboronic acid synthesis directly from (hetero)arylamines. This fast reaction (35â min overall) tolerates a wide range of functional groups and is carried out under very mild conditions. The radical nature of the reaction mechanism has been investigated.