Elaborating a systems methodology for cascading climate change impacts and implications.

New research is drawing attention to the potential for climate change to generate cascading impacts and implications across linked human-environment systems, requiring closer accounting of these interactions to anticipate the emergence of surprises and feedbacks. However, there is little practical guidance for those interested in characterising, identifying or assessing cascades, and few empirical examples. In this paper, we elaborate a systems-based methodology to identify and evaluate cascading climate change impacts and implications. We illustrate its application using the case of a participatory process with urban infrastructure managers, facing the legacy effects of damaging earthquakes and the prospect of future climate change. The results show the proposed approach and visualisation of cascades as causal diagrams provides a robust and flexible analytical framework. The use of systems thinking, visual aids, interactive discussion and expert elicitation generated valuable information about potential cascades, their interactions across domains of interest, and the implications for management. The process can provide a basis for further empirical application and advance methodological and conceptual development. Specifically, the systems methodology:•Identifies interdependencies and interconnections which may serve as transmission pathways for climate-related impacts;•Enhanced stakeholders' understanding of multiple causes and effects of climate change; and•Produced a useful visual aid for stakeholders to explore cascading impacts and implications, and opportunities for intervention.

Effects of Zn2+ and Ga3+ doping on the quantum yield of cluster-derived InP quantum dots.

As the commercial display market grows, the demand for low-toxicity, highly emissive, and size-tunable semiconducting nanoparticles has increased. Indium phosphide quantum dots represent a promising solution to these challenges; unfortunately, they typically suffer from low inherent emissivity resulting from charge carrier trapping. Strategies to improve the emissive characteristics of indium phosphide often involve zinc incorporation into or onto the core itself and the fabrication of core/shell heterostructures. InP clusters are high fidelity platforms for studying processes such as cation exchange and surface doping with exogenous ions since these clusters are used as single-source precursors for quantum dot synthesis. Here, we examined the incorporation of zinc and gallium ions in InP clusters and the use of the resultant doped clusters as single-source precursors to emissive heterostructured nanoparticles. Zinc ions were observed to readily react with InP clusters, resulting in partial cation exchange, whereas gallium resisted cluster incorporation. Zinc-doped clusters effectively converted to emissive nanoparticles, with quantum yields strongly correlated with zinc content. On the other hand, gallium-doped clusters failed to demonstrate improvements in quantum dot emission. These results indicate stark differences in the mechanisms associated with aliovalent and isovalent doping and provide insight into the use of doped clusters to make emissive quantum dots.