Rheological evolution of straw-cattle manure (SCM) treated by dry anaerobic digestion in batch and in continuous pilot reactors.

Knowledge of rheological evolution of biomass during dry anaerobic digestion (D-AD) is important in the engineering design, modeling, and operation of D-AD reactors. In this work, two methods of rheological analysis, the slump test and the shear-box, were used to measure the evolution of the yield stress, cohesion and friction angle of the straw-cattle manure (SCM) during the D-AD. Firstly, four 60 L batch leach-bed reactors (LBR) were started in parallel and stopped at different stages of the D-AD process on days 0, 10, 21 and 31. Secondly, a 500 L and 2 m length plug flow reactor (PFR) was operated with 40 days of solid retention time and samples were recovered at different positions. The solid degradation during D-AD process was monitored by analysis of the degradation of volatile solids, the fiber content and the Flash BMP. Similar degradation patterns of SCM and rheological evolution were observed in both reactors type. VS content decreased of 10.7% and 10.2% in 30 days in PFR and LBR respectively. VS degradation in both cases was well explained by hemicellulose and cellulose consuming in D-AD process. Considering the rheological analysis, the results showed that D-AD induced a reduction of the yield stress of 28.1 and 24.2% in 30 days in PFR and LBR respectively. Moreover, a similar evolution of cohesion and friction angle value for samples from both reactors was observed. This study demonstrates the close relationship between the state of degradation of the solid biomass and its rheological properties.

Comparison of the mesophilic and thermophilic anaerobic digestion of spent cow bedding in leach-bed reactors.

Anaerobic digestion of spent cow bedding in batch leach-bed reactors (LBRs) was compared in mesophilic and thermophilic conditions for the first time. Results show that the use of thermophilic conditions enhanced only the degradation kinetics of easily-degradable matter during the first days of the digestion, whereas similar methane yields (80% of the Biomethane Potential) were reached after 42days at both temperatures. Therefore, the anaerobic digestion in LBRs of spent cow bedding, a substrate rich in slowly-degradable compounds, was not improved in term of methane production considering the overall digestion time. Moreover, the high initial biogas production rate in thermophilic reactors was found to significantly reduce the energetic performance of the cogeneration unit at industrial scale, leading to a 5.9% decrease in the annual electricity production when compared to a mesophilic one.

Recovering biomethane and nutrients from anaerobic digestion of water hyacinth (Eichhornia crassipes) and its co-digestion with fruit and vegetable waste.

The potential to recover bioenergy from anaerobic digestion of water hyacinth (WH) and from its co-digestion with fruit and vegetable waste (FVW) was investigated. Initially, biogas and methane production were studied using the biochemical methane potential (BMP) test at 2 g volatile solids (VS) L(-1) of substrate concentration, both in the digestion of WH alone and in its co-digestion with FVW (WH-FVW ratio of 70:30). Subsequently, the biogas production was optimized in terms of total solids (TS) concentration, testing 4 and 6% of TS. The BMP test showed a biogas yield of 0.114 m(3) biogas kg(-1) VSadded for WH alone. On the other hand, the biogas potential from the WH-FVW co-digestion was 0.141 m(3) biogas kg(-1) VSadded, showing an increase of 23% compared to that of WH alone. Maximum biogas production of 0.230 m(3) biogas kg(-1) VSadded was obtained at 4% of TS in the co-digestion of WH-FVW. Using semi-continuously stirred tank reactors, 1.3 m(3) biogas yield kg(-1) VSadded was produced using an organic loading rate of 2 kg VS m(-3) d(-1) and hydraulic retention time of 15 days. It was also found that a WH-FVW ratio of 80:20 improved the process in terms of pH stability. Additionally, it was found that nitrogen can be recovered in the liquid effluent with a potential for use as a liquid fertilizer.