Tapioca-starch-based bionanocomposites with fructose and titanium dioxide for food packaging and fertilization applications.

Bionanocomposites offer a promising solution to the plastic waste crisis. Although tapioca starch shows potential as a bioplastic material, it is characterized by low mechanical properties, poor thermal stability, and high water absorption owing to its hydrophilic nature. To increase the flexibility of the material and reduce the transmission rate of oxygen and water vapor, additives such as fructose and titanium dioxide (TiO2) can be incorporated into the material. TiO2 nanoparticles are commonly utilized in agriculture to enhance nutrient release and promote plant growth. In this study, X-ray diffraction analysis revealed that TiO2 reduced crystal size while increasing the crystallinity of bionanocomposites. Fourier-transform infrared spectroscopy analysis revealed an absorption peak at 3397 cm-1, indicating hydrogen bonding between TiO2 and starch-OH groups, and a peak at 773 cm-1, indicating an increase in the intensity of Ti-O-Ti stretching vibrations with the incorporation of TiO2. Water absorption rate results confirmed that TiO2 addition enhanced bionanocomposite resistance to water vapor and moisture, evidenced by increased tensile strength from 0.11 to 0.49 MPa and Young's modulus from 2.48 to 5.26 MPa, as well as decreased elongation at break from 21.46 % to 2.36 % in bionanocomposites with TiO2. Furthermore, with TiO2 addition, the biodegradation rate of the bionanocomposites decreased, which is beneficial for enhancing plant nutrient content.

Keratin-based bioplastics extracted from chicken feathers: Effect of chitosan concentration on the structural, chemical bonding, and mechanical properties of bioplastics.

Keratin was synthesized by alkaline hydrolysis from chicken feathers and then continue by casting method for producing bioplastics with additional various amounts of chitosan as a filler, polyvinyl alcohol (PVA) and glycerol as a plasticizer. The main purpose is analysis the effect of chitosan on the structural properties using quantitative analysis of X-ray diffraction (XRD) spectra, chemical bonding by Fourier transforms infrared (FTIR) spectra, and mechanical properties by texture analyser to the keratin-based bioplastics. Biodegradation of bioplastics was analysed from the loss of weight by burying in the soil. It's found that, the additional of chitosan (0 %, 2 %, 5 %, and 8 %) increased the crystallinity of bioplastics by 11.83 %, 11.12 %, 18.99 %, and 17.03 %, respectively, but decreasing tensile strength and elasticity of bioplastics. Degradation of bioplastic keratin-based shows that the addition of chitosan can reduce the degradation time which is directly proportional to the loss of CO bonds. The highest degradation rate is 89.29 % in 49 days for keratin-based bioplastics with 8 % chitosan, indicated that high potential for future production.

High degradation bioplastics chitosan-based from scale waste of milkfish (Chanos chanos).

Bioplastic that is synthesized from natural materials such as chitosan is a renewable solution to reduce plastic waste in the environment because they are easily decomposed. In this study, chitosan (CS) was extracted from Milkfish scales waste to produce composite bioplastic CS/PVA/PEG to determine the effect of CS on the mechanical properties and degradation time. The average particle size of chitin is 8.5 µm and crystallinity of 57.18 % and for CS, the particle size is 3.5 µm and crystallinity of 64.94 %. The degree of deacetylation of CS is 84.1 % which met the quality standard of Indonesian national standard (SNI) Number: 7949:2013. The tensile strength of bioplastics for 0.5 g CS of 0.21 MPa increases to 0.24 MPa for 2 g CS in composite bioplastics CS/PVA/PEG. The biodegradation performance of bioplastic samples takes 72 h to completely decompose in soil for CS-based and in seawater for chitin-based, means that highly recommended to develop in future.

Treatment of Groundwater-Rich Organic Compounds Using Activated Carbon with Additional Germanium Dioxide (GeO2): Kinetics and Adsorption Studies of Methylene Blue and Congo Red.

Activated carbon/GeO2 composites were synthesized using the sol-gel method and then used as catalysts for the photodegradation of organic pollutants methylene blue (MB) and congo red (CR). The composites were characterized using an X-ray diffractometer and Fourier transform infrared spectroscopy to analyze the structure and chemical bonds of the composite materials, respectively. The ultraviolet-visible (UV-vis) absorption wavelength ranges of the composites toward the pollutants were 550-700 nm for MB and 450-550 for CR. The band gap energies of the composites were calculated, with the values found to be <4.5 eV. It was shown that the adsorption ability of the composites increased with the irradiation time of the pollutants. Furthermore, the adsorption kinetics data were found to be a good fit to a pseudo-first-order kinetics model.

Nickel Slag/Laterite Soil and Nickel Slag/Iron Sand Nanocomposites: Structural, Optical, and Electromagnetic Absorption Properties.

Efforts to produce microwave absorber materials that are inexpensive and environmentally friendly have become a means of greening the environment. The breakthrough can be focused on industrial waste and natural materials for functional purposes and how to enhance their performance. We successfully synthesized nickel slag/laterite soil (NS/LS) and nickel slag/iron sand (NS/IS) nanocomposites using a simple mechanical alloying technique, and the electromagnetic (EM) wave absorption capacities of the nanocomposites were measured using a vector network analyzer. The structural properties of the nanocomposites were analyzed by X-ray diffraction spectroscopy, where the results of the analysis showed that NS/IS has the largest crystallite size (15.69 nm) and the highest EM wave absorption performance. The optical properties of the nanocomposites were determined from their Fourier transform infrared spectra using the Kramers-Kronig relation. As determined through a quantitative analysis of the optical properties, the distance between the longitudinal and transversal optical phonon wavenumber positions (Δ(LO - TO) = 65 cm-1) is inversely proportional to the reflection loss. The surface morphologies of the nanocomposites were analyzed by scanning electron microscopy, and the particle diameters were observed by binary image and Gaussian distribution analyses. The nanocomposite surface exhibits a graded-like morphology, which indicates multiple reflections of the EM radiation, consequently reducing the EM interference. The best nanocomposite for an attenuated EM wave achieved a reflection loss of -39.14 dB at 5-8 GHz. A low penetration depth has implications for the electrical charge tuning of the storage and composite magnets. Finally, the EM absorption properties of NS/IS and NS/LS indicate a 2-mm-thick environmentally friendly nanocomposite for EM absorption.

Bibliometric analysis of chitosan research for wastewater treatment: a review.

Wastewater has negative impacts on the environment, such as destroying aquatic ecosystems and creating a shortage of clean water sources for consumption. In this paper, we provide a comprehensive bibliometric analysis of chitosan to better understand the evolution in degrading various pollutants as a wastewater treatment research limited only by photocatalyst system published in 2001-2021. The number of publications analyzed a total of 456 documents, which was conducted from the Scopus database. All data in this paper was visualized by using open-source software, VOSviewer and Tableau, to perform bibliometric analysis and scientific mapping. The reason for choosing chitosan is its ability to degrade various pollutants with high adsorption performance (from various sources: degradation Congo red 98.4%, methylene blue 99.36%, rhodamine B 95%, and Cd(II) 94%), non-toxicity, biodegradability, and abundantly available sources in nature. The analysis results show that the highest number of publications in 2016 was 66, and the highest number of citations was 2258. The network of keywords and innovations for wastewater treatment is USA and China as the most productive countries with many cooperative relations. This paper helps scholars understand the evolution of composite chitosan-based photocatalyst systems as research on wastewater treatment from a bibliometric point of view and inspires them to develop new efficient methods in synthesizing chitosan from fish by-products (waste) with high adsorption efficiency for various type of waste.

Bibliometric analysis of the use of calcium alginate for wound dressing applications: A review.

Wounds can cause many disorders and affect the quality of health, so it is necessary to develop wound dressings that have a role in accelerating the healing process. Wound dressings have evolved over time, and today there are many types of wound dressings that can suit the type of wound the patient has. This review discusses the development, types, and research directions of wound dressings from calcium alginate (CaAlg), using bibliometric analysis with time intervals from 1982 to 2021. It was found that, in the late 1990s, research related to this matter began to increase. United Kingdom, United States, China, Japan, and Italy are the five most influential countries. And from the results of the keyword analysis, it was found that, in addition to studying the general properties of wound dressings, currently there are many developments related to the structure of the material as well as the effect of adding drugs to wound dressings, so that the current study also displays various characterizations.

High efficiency self-cleaning of nanocomposites ZnO with additional chitosan for helping electron and hole transport.

ZnO/chitosan coated wool fabric has been applied as a self-cleaning which obtained through sol-gel method for various pH: 5, 7, and 9. The self-cleaning test was carried out by irradiating the cloth samples using UVA-UVB lamps up to 15 h with dye for the clothing stain. ZnO/chitosan composites were characterized using X-Ray Diffraction (XRD), Fourier Transform Infra-Red (FTIR), and UV-Visible spectroscopy. The diffraction spectra from chitosan for pH 9 is 19.56°. The vibration bond at the wavenumbers 422 cm-1- 621 cm-1 identified as ZnO bond and at the wavenumber 3495 cm-1 identified for stretching -OH and -NH2 from chitosan. Optical properties were analysed using the Kamers Kronig (KK) relation which was applied to the FTIR spectra and shows the highest distance between two optical photon vibration modes (∆ (LO-TO)) is 199 cm-1 was obtained when the pH 9. The pH 9 is the best self-cleaning performance for dye stain which completely lost after being exposed for 15 h irradiation. Samples pH 9 shows the best self-cleaning due to the smallest crystallite size and highest bandgap and (∆ (LO-TO)) indicated high potential for new self-cleaning material in future.

Composites cement/BaSO4/Fe3O4/CuO for improving X-ray absorption characteristics and structural properties.

Composite cement/BaSO4/Fe3O4/CuO with a thickness of 0.6 cm for various amounts of CuO: 2 wt%, 4 wt%, 6 wt%, and 8 wt% were successfully synthesized for the X-ray radiation shield. The bonding characteristics of composite and structural properties were determined using Fourier transform infrared spectra for the wavelength range of 4000-400 cm-1 and X-ray diffraction with the range of 2θ from 25° to 50°, respectively. The shielding ability was measured using a mobile X-ray with an energy of 55, 66, and 77 keV for determining the mass and linear attenuation coefficient, electronic and atomic cross-section. These shield characteristics best agreement with theoretical calculation from the XCOM database for energy < 77 keV with half value layer (HVL) < 0.3 cm. The best shielding in this study indicated by the lowest HVL and MFP is composite for CuO 8 wt%. The HVL and MFP shows better values compared to the previous reported using composite rubber-based, indicated high potentials composite in this study for design new and efficient radiology rooms as an alternative concrete, especially for X-ray radiation, in the future.

Enhanced Visible-Light Absorption of Fe2O3 Covered by Activated Carbon for Multifunctional Purposes: Tuning the Structural, Electronic, Optical, and Magnetic Properties.

Visible-light absorption is a critical factor for photocatalyst activity and absorption of electromagnetic (EM) interference application. The band gap of Fe2O3 is 2 eV, which can be increased by doping with a high-band-gap material such as carbon from activated carbon (AC) with a band gap of 4.5 eV for increased visible-light absorption. The porosity decreases from 88 to 81.6%, and the band gap increases from 2.14 to 2.64 eV by increasing the AC from 10 to 25%, respectively. The photocatalytic activity takes 120 min to produce a harmless product for 10-20% AC, but 25% AC shows 89.5% degradation in only 90 min and the potential to attenuate the EM wave up to 99% due to the RL being below -20 dB. The second- and third-cycle degradation achieved by the composite Fe2O3-AC having 25% AC is 88.2 and 86.5% in 90 min, respectively. The pore of the surface state of AC contains a trapped charge, and interaction occurs between the charge (electron/hole) and O2 or H2O to produce OH and superoxide (O2 -) radicals. These radicals move inside the molecule of the pollutant (methylene blue (MB)) to break up the bond, with the final products being H2O and CO2. The X-ray photoelectron (XPS) spectra show that oxygen plays a key role in the interatomic bonding with Fe, C, and MB atoms. The best absorption of EM interference is -21.43 dB, with degradation reaching 89.51% in only 90 min for 25% AC due to its higher band gap and anisotropy constant. Fe2O3-carbon is a multifunctional material for the green environment because of its electromagnetic interference absorption and photodegradation of wastewater.