Quantum oscillations in an optically-illuminated two-dimensional electron system at the LaAlO3/SrTiO3interface.

We have investigated the illumination effect on the magnetotransport properties of a two-dimensional electron system at the LaAlO3/SrTiO3interface. The illumination significantly reduces the zero-field sheet resistance, eliminates the Kondo effect at low-temperature, and switches the negative magnetoresistance into the positive one. A large increase in the density of high-mobility carriers after illumination leads to quantum oscillations in the magnetoresistance originating from the Landau quantization. The carrier density (∼2 × 1012 cm-2) and effective mass (∼1.7me) estimated from the oscillations suggest that the high-mobility electrons occupy thedxz/yzsubbands of Ti:t2gorbital extending deep within the conducting sheet of SrTiO3. Our results demonstrate that the illumination which induces additional carriers at the interface can pave the way to control the Kondo-like scattering and study the quantum transport in the complex oxide heterostructures.

Gate-tuned anomalous Hall effect driven by Rashba splitting in intermixed LaAlO3/GdTiO3/SrTiO3.

The Anomalous Hall Effect (AHE) is an important quantity in determining the properties and understanding the behaviour of the two-dimensional electron system forming at the interface of SrTiO3-based oxide heterostructures. The occurrence of AHE is often interpreted as a signature of ferromagnetism, but it is becoming more and more clear that also paramagnets may contribute to AHE. We studied the influence of magnetic ions by measuring intermixed LaAlO3/GdTiO3/SrTiO3 at temperatures below 10 K. We find that, as function of gate voltage, the system undergoes a Lifshitz transition while at the same time an onset of AHE is observed. However, we do not observe clear signs of ferromagnetism. We argue the AHE to be due to the change in Rashba spin-orbit coupling at the Lifshitz transition and conclude that also paramagnetic moments which are easily polarizable at low temperatures and high magnetic fields lead to the presence of AHE, which needs to be taken into account when extracting carrier densities and mobilities.

Gate-Tunable Band Structure of the LaAlO_{3}-SrTiO_{3} Interface.

The two-dimensional electron system at the interface between LaAlO_{3} and SrTiO_{3} has several unique properties that can be tuned by an externally applied gate voltage. In this work, we show that this gate tunability extends to the effective band structure of the system. We combine a magnetotransport study on top-gated Hall bars with self-consistent Schrödinger-Poisson calculations and observe a Lifshitz transition at a density of 2.9×10^{13}cm^{-2}. Above the transition, the carrier density of one of the conducting bands decreases with increasing gate voltage. This surprising decrease is accurately reproduced in the calculations if electronic correlations are included. These results provide a clear, intuitive picture of the physics governing the electronic structure at complex-oxide interfaces.

Analysing magnetism using scanning SQUID microscopy.

Scanning superconducting quantum interference device microscopy (SSM) is a scanning probe technique that images local magnetic flux, which allows for mapping of magnetic fields with high field and spatial accuracy. Many studies involving SSM have been published in the last few decades, using SSM to make qualitative statements about magnetism. However, quantitative analysis using SSM has received less attention. In this work, we discuss several aspects of interpreting SSM images and methods to improve quantitative analysis. First, we analyse the spatial resolution and how it depends on several factors. Second, we discuss the analysis of SSM scans and the information obtained from the SSM data. Using simulations, we show how signals evolve as a function of changing scan height, SQUID loop size, magnetization strength, and orientation. We also investigated 2-dimensional autocorrelation analysis to extract information about the size, shape, and symmetry of magnetic features. Finally, we provide an outlook on possible future applications and improvements.

MAGNETISM. Imaging and control of ferromagnetism in LaMnO3/SrTiO3 heterostructures.

Oxide heterostructures often exhibit unusual physical properties that are absent in the constituent bulk materials. Here, we report an atomically sharp transition to a ferromagnetic phase when polar antiferromagnetic LaMnO3 (001) films are grown on SrTiO3 substrates. For a thickness of six unit cells or more, the LaMnO3 film abruptly becomes ferromagnetic over its entire area, which is visualized by scanning superconducting quantum interference device microscopy. The transition is explained in terms of electronic reconstruction originating from the polar nature of the LaMnO3 (001) films. Our results demonstrate that functionalities can be engineered in oxide films that are only a few atomic layers thick.

Anisotropic two-dimensional electron gas at the LaAlO3/SrTiO3 (110) interface.

The observation of a high-mobility two-dimensional electron gas between two insulating complex oxides, especially LaAlO3/SrTiO3, has enhanced the potential of oxides for electronics. The occurrence of this conductivity is believed to be driven by polarization discontinuity, leading to an electronic reconstruction. In this scenario, the crystal orientation has an important role and no conductivity would be expected, for example, for the interface between LaAlO3 and (110)-oriented SrTiO3, which should not have a polarization discontinuity. Here we report the observation of unexpected conductivity at the LaAlO3/SrTiO3 interface prepared on (110)-oriented SrTiO3, with a LaAlO3-layer thickness-dependent metal-insulator transition. Density functional theory calculation reveals that electronic reconstruction, and thus conductivity, is still possible at this (110) interface by considering the energetically favourable (110) interface structure, that is, buckled TiO2/LaO, in which the polarization discontinuity is still present. The conductivity was further found to be strongly anisotropic along the different crystallographic directions with potential for anisotropic superconductivity and magnetism, leading to possible new physics and applications.

Cationic-vacancy-induced room-temperature ferromagnetism in transparent, conducting anatase Ti1-xTaxO2 (x~0.05) thin films.

We report room-temperature ferromagnetism (FM) in highly conducting, transparent anatase Ti(1-x)Ta(x)O(2) (x∼0.05) thin films grown by pulsed laser deposition on LaAlO(3) substrates. Rutherford backscattering spectrometry (RBS), X-ray diffraction, proton-induced X-ray emission, X-ray absorption spectroscopy (XAS) and time-of-flight secondary-ion mass spectrometry indicated negligible magnetic contaminants in the films. The presence of FM with concomitant large carrier densities was determined by a combination of superconducting quantum interference device magnetometry, electrical transport measurements, soft X-ray magnetic circular dichroism (SXMCD), XAS and optical magnetic circular dichroism, and was supported by first-principles calculations. SXMCD and XAS measurements revealed a 90 per cent contribution to FM from the Ti ions, and a 10 per cent contribution from the O ions. RBS/channelling measurements show complete Ta substitution in the Ti sites, though carrier activation was only 50 per cent at 5 per cent Ta concentration, implying compensation by cationic defects. The role of the Ti vacancy (V(Ti)) and Ti(3+) was studied via XAS and X-ray photoemission spectroscopy, respectively. It was found that, in films with strong FM, the V(Ti) signal was strong while the Ti(3+) signal was absent. We propose (in the absence of any obvious exchange mechanisms) that the localized magnetic moments, V(Ti) sites, are ferromagnetically ordered by itinerant carriers. Cationic-defect-induced magnetism is an alternative route to FM in wide-band-gap semiconducting oxides without any magnetic elements.

Josephson supercurrent through a topological insulator surface state.

The long-sought yet elusive Majorana fermion is predicted to arise from a combination of a superconductor and a topological insulator. An essential step in the hunt for this emergent particle is the unequivocal observation of supercurrent in a topological phase. Here, direct evidence for Josephson supercurrents in superconductor (Nb)-topological insulator (Bi(2)Te(3))-superconductor electron-beam fabricated junctions is provided by the observation of clear Shapiro steps under microwave irradiation, and a Fraunhofer-type dependence of the critical current on magnetic field. Shubnikov-de Haas oscillations in magnetic fields up to 30 T reveal a topologically non-trivial two-dimensional surface state. This surface state is attributed to mediate the ballistic Josephson current despite the fact that the normal state transport is dominated by diffusive bulk conductivity. The lateral Nb-Bi(2)Te(3)-Nb junctions hence provide prospects for the realization of devices supporting Majorana fermions.

Conductance anisotropy and linear magnetoresistance in La(2 - x)Sr(x)CuO4 thin films.

We have performed a detailed study of conductance anisotropy and magnetoresistance (MR) of La(2 - x)Sr(x)CuO(4) (LSCO) thin films (0.10 < x < 0.25). These two observables are promising for the detection of stripes. Subtle features of the conductance anisotropy are revealed by measuring the transverse resistance R(xy) in zero magnetic field. It is demonstrated that the sign of R(xy) depends on the orientation of the LSCO Hall bar with respect to the terrace structure of the substrate. Unit-cell-high substrate step edges must therefore be a dominant nucleation source for antiphase boundaries during film growth. We show that the measurement of R(xy) is sensitive enough to detect the cubic-tetragonal phase transition of the SrTiO(3)(100) (STO) substrate at 105 K. The MR of LSCO thin films shows for 0.10 < x < 0.25 a non-monotonic temperature dependence, resulting from the onset of a linear term in the MR above 90 K. We show that the linear MR scales with the Hall resistivity as [Formula: see text], with the constant of proportionality independent of temperature. Such scaling suggests that the linear MR originates from current distortions induced by structural or electronic inhomogeneities. The possible role of stripes for both the MR and the conductance anisotropy is discussed throughout the paper.

Electronic phase separation at the LaAlO3/SrTiO3 interface.

There are many electronic and magnetic properties exhibited by complex oxides. Electronic phase separation (EPS) is one of those, the presence of which can be linked to exotic behaviours, such as colossal magnetoresistance, metal-insulator transition and high-temperature superconductivity. A variety of new and unusual electronic phases at the interfaces between complex oxides, in particular between two non-magnetic insulators LaAlO(3) and SrTiO(3), have stimulated the oxide community. However, no EPS has been observed in this system despite a theoretical prediction. Here, we report an EPS state at the LaAlO(3)/SrTiO(3) interface, where the interface charges are separated into regions of a quasi-two-dimensional electron gas, a ferromagnetic phase, which persists above room temperature, and a (superconductor like) diamagnetic/paramagnetic phase below 60 K. The EPS is due to the selective occupancy (in the form of 2D-nanoscopic metallic droplets) of interface sub-bands of the nearly degenerate Ti orbital in the SrTiO(3). The observation of this EPS demonstrates the electronic and magnetic phenomena that can emerge at the interface between complex oxides mediated by the Ti orbital.

Parallel electron-hole bilayer conductivity from electronic interface reconstruction.

The perovskite SrTiO3-LaAlO3 structure has advanced to a model system to investigate the rich electronic phenomena arising at polar oxide interfaces. Using first principles calculations and transport measurements we demonstrate that an additional SrTiO3 capping layer prevents atomic reconstruction at the LaAlO3 surface and triggers the electronic reconstruction at a significantly lower LaAlO3 film thickness than for the uncapped systems. Combined theoretical and experimental evidence (from magnetotransport and ultraviolet photoelectron spectroscopy) suggests two spatially separated sheets with electron and hole carriers, that are as close as 1 nm.

Interplay between static and dynamic properties of semifluxons in YBa2Cu3O(7-delta) 0-pi Josephson junctions.

We have investigated the static and dynamic properties of long YBa2Cu3O(7-delta) 0-pi Josephson junctions and compared them with those of conventional 0 junctions. Scanning SQUID microscope imaging has revealed the presence of a semifluxon at the phase discontinuity point in 0-pi Josephson junctions. Zero field steps have been detected in the current-voltage characteristics of all junctions. Comparison with simulation allows us to attribute these steps to fluxons traveling in the junction for conventional 0 junctions and to fluxon-semifluxon interactions in the case of 0-pi Josephson junctions.

High-T(c) superconducting thin films with composition control on a sub-unit cell level; the effect of the polar nature of the cuprates.

Inspired by the work of Ohtomo and Hwang in 2004, we shed new light on thin films of layered cuprate high-T(c) superconductors (HTS). In principle all HTS materials consist of charged perovskite-like layers which in thin films can lead to polar discontinuities at the interfaces of different materials. The resulting charge redistribution has to occur but we expect it to be far more complex than in the LaAlO(3)/SrTiO(3) system since copper can be multivalent. This makes it hard to predict what will happen in terms of transport or even magnetic properties compared to the 'simple' insulator LaAlO(3). Nevertheless, we point out that the picture of systems of charged layers is important and necessary to fully understand heterostructures of these complex materials.

Magnetic effects at the interface between non-magnetic oxides.

The electronic reconstruction at the interface between two insulating oxides can give rise to a highly conductive interface. Here we show how, in analogy to this remarkable interface-induced conductivity, magnetism can be induced at the interface between the otherwise non-magnetic insulating perovskites SrTiO3 and LaAlO3. A large negative magnetoresistance of the interface is found, together with a logarithmic temperature dependence of the sheet resistance. At low temperatures, the sheet resistance reveals magnetic hysteresis. Magnetic ordering is a key issue in solid-state science and its underlying mechanisms are still the subject of intense research. In particular, the interplay between localized magnetic moments and the spin of itinerant conduction electrons in a solid gives rise to intriguing many-body effects such as Ruderman-Kittel-Kasuya-Yosida interactions, the Kondo effect and carrier-induced ferromagnetism in diluted magnetic semiconductors. The conducting oxide interface now provides a versatile system to induce and manipulate magnetic moments in otherwise non-magnetic materials.

Flip-flopping fractional flux quanta.

The d-wave pairing symmetry in high-critical temperature superconductors makes it possible to realize superconducting rings with built-in pi phase shifts. Such rings have a twofold degenerate ground state that is characterized by the spontaneous generation of fractional magnetic flux quanta with either up or down polarity. We have incorporated pi phase-biased superconducting rings in a logic circuit, a flip-flop, in which the fractional flux polarity is controllably toggled by applying single flux quantum pulses at the input channel. The integration of p rings into conventional rapid single flux quantum logic as natural two-state devices should alleviate the need for bias current lines, improve device symmetry, and enhance the operation margins.

Phase-sensitive order parameter symmetry test experiments utilizing Nd(2-x)Ce(x)CuO(4-y)/Nb zigzag junctions.

Phase-sensitive order parameter symmetry test experiments are presented on the electron-doped high-T(c) cuprate Nd(2-x)Ce(x)CuO(4-y). These experiments have been conducted using zigzag-shaped thin film Josephson structures, in which the Nd(2-x)Ce(x)CuO(4-y) is connected to the low-T(c) superconductor Nb via an Au barrier layer. For the optimally doped as well as for the overdoped Nd(2-x)Ce(x)CuO(4-y), a clear predominant d(x2-y2)-wave behavior is observed at T=4.2 K. Both compounds were also investigated at T=1.6 K, presenting no indications for a change to a predominant s-wave symmetry with decreasing temperature.

Admixtures to d-wave gap symmetry in untwinned YBa2Cu3O7 superconducting films measured by angle-resolved electron tunneling.

We report on an ab anisotropy of Jc parallel b/Jc parallel a approximately/= 1.8 IcRn parallelb/IcRn parallel a approximately/= 1.2 and in ramp-edge junctions between untwinned YBa2Cu3O7 and s-wave Nb. For these junctions, the angle theta with the YBa2Cu3O7 crystal b axis is varied as a single parameter. The RnA(theta) dependence presents twofold symmetry. The minima in IcRn at theta approximately/= 50 degrees suggest a real s-wave subdominant component and negligible d(xy)-wave or imaginary s-wave admixtures. The IcRn(theta) dependence is well fitted by 83% dx2-y2-, 15% isotropic s-, and 2% anisotropic s-wave order parameter symmetry, consistent with deltab/deltaa approximately/= 1.5.

Observation of splintered Josephson vortices at grain boundaries in YBa(2)Cu(3)O(7-delta).

We have directly observed well-separated Josephson vortex splinters with unquantized magnetic flux at asymmetric 45 degrees grain boundaries in YBa(2)Cu(3)O(7-delta) films by imaging magnetic flux with scanning SQUID microscopy. The existence of these splinter vortices has been predicted and is well described by a model based on dx(2)(-y(2)) pairing symmetry and facetting of the grain boundary on a length scale shorter than the Josephson penetration depth.

d-wave induced zero-field resonances in dc pi-superconducting quantum interference devices.

A dc pi SQUID consists of a superconducting ring interrupted by two Josephson junctions, one of which carries in equilibrium a pi phase difference, caused, for example, by the d-wave pairing symmetry of the high- T(c) cuprates. If this phase shift is maintained in the voltage state, anomalous resonance currents are expected in the SQUIDs transport characteristics. Here we report the observation of such resonances for high- T(c) dc pi SQUIDs, providing evidence for the influence of the d-wave symmetry on the voltage state of a Josephson junction for frequencies of several tens of GHz.