RESUMO
This paper focuses on the formation of high-density, low-defect monolayers of triphosphasumanene trisulfides, which are newly synthesized electronic and geometric Janus-type molecules, in a flat-on conformation. Although the molecules stack easily because of the developed π-conjugated plane, their application as a metal coating in a flat-on conformation via an interfacial molecular film enables the work function to be tuned. Surface pressure-area isotherms of the triphosphasumanene trisulfides show a two-dimensional phase transition at the air/water interface. Atomic force microscopy observations of the transferred monolayer and in- and out-of-plane X-ray diffraction patterns of the corresponding multilayers reveal that this phase transition occurs from the flat-on to the end-on conformation. The X-ray diffraction patterns obtained in the two directions completely reversed before and after the phase transition, indicating that the molecular arrangement that is generated by layers of molecular films and resultant molecular stacking is similar. The flat-on conformation of the molecules was evident from the out-of-plane X-ray diffraction and polarized infrared spectroscopy results, which indicate that a large, low-defect monomolecular film is obtained using a toluene solution with a small diffusion coefficient. The spectroscopic results reveal triphosphasumanene trisulfide aggregation in the organized molecular film, suggesting high-density molecular packing.
