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Macromol Biosci ; 5(11): 1094-100, 2005 Nov 04.
Artigo em Inglês | MEDLINE | ID: mdl-16245274

RESUMO

Solid-state structures and enzymatic degradability have been investigated for cocrystallized blends between poly(3-hydroxybutyrate-co-3-hydroxyvalerate) [PHBV] and poly(3-hydroxybutyrate-co-3-hydroxypropionate) [PHBP]. From wide-angle X-ray diffraction patterns, small-angle X-ray scattering data, and the comparison of the enzymatic degradability of these blends, the solid-state structures of PHBV/PHBP blend samples, in which the PHBV component has higher isothermal crystal growth rate (G) value than the PHBP one, might be similar to those of the component PHBVs; while those of the PHBP/PHBV blend samples, in which PHBP component has higher G value, were similar to the component PHBPs. Normalized one-dimensional correlation functions gamma(x) of PHBV/PHBP binary blends crystallized at 90 degrees C.


Assuntos
Hidrolases de Éster Carboxílico/química , Hidroxibutiratos/química , Poliésteres/química , Ralstonia pickettii/enzimologia , Biodegradação Ambiental , Cristalização , Estrutura Molecular , Espalhamento de Radiação , Temperatura , Difração de Raios X
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