Performance degradation and mitigation of high temperature polybenzimidazole-based polymer electrolyte membrane fuel cells.

To meet challenges associated with climate changes due to the continuous increase in global energy demand, implementation of hydrogen and fuel cell technologies, especially the polymer electrolyte membrane type, are recognized as potential solutions. The high temperature polymer electrolyte membrane fuel cell based on acid doped polybenzimidazoles has attracted enormous R&D attention due to the simplified construction and operation of the power system. In order to improve the reliability and lifetime of the technology, studies on material degradation and mitigation are essential. The present work is a comprehensive review of the current knowledge on degradation mechanisms of the fuel cell components including the acid loss, polymer oxidation and catalyst instability due to the metal dissolution and carbon support corrosion. The durability results are updated according to the categories of steady state and dynamic operations. Durability protocols, diagnostic techniques and mitigation strategies are also discussed.

Membrane Assemblies with Soft Protective Layers: Dense and Gel-Type Polybenzimidazole Membranes and Their Use in Vanadium Redox Flow Batteries.

Polybenzimidazole (PBI) membranes show excellent chemical stability and low vanadium crossover in vanadium redox flow batteries (VRFBs), but their high resistance is challenging. This work introduces a concept, membrane assemblies of a highly selective 2 µm thin PBI membrane between two 60 µm thick highly conductive PBI gel membranes, which act as soft protective layers against external mechanical forces and astray carbon fibers from the electrode. The soft layers are produced by casting phosphoric acid solutions of commercial PBI powder into membranes and exchanging the absorbed acid into sulfuric acid. A conductivity of 565 mS cm-1 is achieved. A stability test indicates that gel mPBI and dense PBI-OO have higher stability than dense mPBI and dense py-PBI, and gel/PBI-OO/gel is successfully tested for 1070 cycles (ca. 1000 h) at 100 mA cm-2 in the VRFB. The initial energy efficiency (EE) for the first 50 cycles is 90.5 ± 0.2%, and after a power outage stabilized at 86.3 ± 0.5% for the following 500 cycles. The initial EE is one of the highest published so far, and the materials cost for a membrane assembly is 12.35 U.S. dollars at a production volume of 5000 m2 , which makes these membranes very attractive for commercialization.

Correction: Duburg et al. Composite Polybenzimidazole Membrane with High Capacity Retention for Vanadium Redox Flow Batteries. Molecules 2021, 26, 1679.

The authors wish to make the following changes to their paper [...].

Composite Polybenzimidazole Membrane with High Capacity Retention for Vanadium Redox Flow Batteries.

Currently, energy storage technologies are becoming essential in the transition of replacing fossil fuels with more renewable electricity production means. Among storage technologies, redox flow batteries (RFBs) can represent a valid option due to their unique characteristic of decoupling energy storage from power output. To push RFBs further into the market, it is essential to include low-cost materials such as new generation membranes with low ohmic resistance, high transport selectivity, and long durability. This work proposes a composite membrane for vanadium RFBs and a method of preparation. The membrane was prepared starting from two polymers, meta-polybenzimidazole (6 µm) and porous polypropylene (30 µm), through a gluing approach by hot-pressing. In a vanadium RFB, the composite membrane exhibited a high energy efficiency (~84%) and discharge capacity (~90%) with a 99% capacity retention over 90 cycles at 120 mA·cm-2, exceeding commercial Nafion® NR212 (~82% efficiency, capacity drop from 90% to 40%) and Fumasep® FAP-450 (~76% efficiency, capacity drop from 80 to 65%).

The changing face of glucagon fibrillation: structural polymorphism and conformational imprinting.

We have established a time-resolved fluorescence assay to study fibrillation of the 29 residue peptide hormone glucagon under a variety of different conditions in a high-throughput format. Fibrils formed at pH 2.5 differ in fibrillation kinetics, morphology, thioflavin T staining and FTIR/CD spectra depending on salts, glucagon concentration and fibrillation temperature. Apparent fibrillar stability correlates with spectral and kinetic properties; generally, fibrils formed under conditions favourable for rapid fibrillation (ambient temperatures, high glucagon concentration or high salt concentration) appear less thermostable than those formed under more challenging conditions (high temperatures, low glucagon or low salt concentrations). Properties of preformed fibrils used for seeding are inherited in a prion-like manner. Thus, we conclude that the structure of fibrils formed by glucagon is not the result of the global energy minimization, but rather kinetically controlled by solvent conditions and seed-imprinting. Fibrillar polymorphism, which is being reported for an increasing number of proteins, probably reflects that fibrils have not been under evolutionary constraints to retain a single active conformation. Our results highlight the complexity of the fibrillation mechanism of glucagon, since even subtle changes in fibrillation conditions can alter the type of fibrils formed, or result in formation of mixtures of several types of fibrils.