Simultaneous Methylene Blue Adsorption and pH Neutralization of Contaminated Water by Rice Husk Ash.

In this study, the potential of rice husk ash (RHA) to act as an adsorbent for treating dye-containing wastewater was demonstrated. The RHA used in this study contained 91.7% silica, which was composed of crystalline (cristobalite and tridymite) and amorphous phases. The mechanochemical treatment of RHA led to an increase in its specific surface area from 6.2 to 14.6 m2/g in 15 min and dramatically improved its methylene blue (MB) adsorption ability. Langmuir adsorption isotherms revealed that the maximum adsorption capacity of the treated RHA was 8.59 mg/g, which is 2.45 times higher than that of raw RHA. pH-dependent adsorption studies on the RHA revealed that MB was adsorbed on the deprotonated Q3 silanol through electrostatic interactions. Moreover, the RHA adsorbent showed pH buffering at a pH value of approximately 7; thus, the pH of the solution could be neutralized simultaneously with the adsorptive removal of MB.

Synthesis of metaettringite from blast furnace slag and evaluation of its boron adsorption ability.

Blast furnace slag (BFS) is generated as a by-product in the ironmaking process, and hence, the development of a recycling system for BFS waste is important. In this study, the calcium component of BFS obtained from a steel company in Japan was successfully used as raw material of the synthesis of metaettringite. Metaettringite has been recently considered for as an adsorbent for boron, which is toxic to humans and animals. The BFS used was amorphous, and mainly consisted of CaO, SiO2, Al2O3, and MgO; in particular, it contained 42.82 mass % CaO. The X-ray diffraction pattern and Fourier transform infrared spectrum of the synthesized sample indicated the formation of metaettringite. Field-emission scanning electron microscopy observations revealed its needle-like morphology. The synthesized metaettringite adsorbed 1.189 mg-B/g-adsorbent in 240 min, which was approximately 25 times greater than that achieved using the parent BFS. The metaettringite can reduce the boron concentration to below the uniform effluent standard in industrial wastewater in Japan (16 mg/L).

Preparation and performance of arsenate (V) adsorbents derived from concrete wastes.

Solid adsorbent materials, prepared from waste cement powder and concrete sludge were assessed for removal of arsenic in the form of arsenic (As(V)) from water. All the materials exhibited arsenic removal capacity when added to distilled water containing 10-700 mg/L arsenic. The arsenic removal isotherms were expressed by the Langmuir type equations, and the highest removal capacity was observed for the adsorbent prepared from concrete sludge with heat treatment at 105°C, the maximum removal capacity being 175 mg-As(V)/g. Based on changes in arsenic and calcium ion concentrations, and solution pH, the removal mechanism for arsenic was considered to involve the precipitation of calcium arsenate, Ca3(AsO4)2. The enhanced removal of arsenic for the adsorbent prepared from concrete sludge with heat treatment was thought to reflect ion exchange by ettringite. The prepared adsorbents, derived from waste cement and concrete using simple procedures, may offer a cost effective approach for arsenic removal and clean-up of contaminated waters, especially in developing countries.